[1]赵会峰,刘广财,余德兴,等.镀膜参数对浮法玻璃热反射合金膜性能的影响[J].电镀与精饰,2022,(4):51-55.[doi:10.3969/j.issn.1001-3849.2022.04.011]
　ZHAO Huifeng,LIU Guangcai,YU Dexing,et al.Effects of Coating Parameters on Properties of Float Glass Heat-Reflective Alloy Films[J].Plating & Finishing,2022,(4):51-55.[doi:10.3969/j.issn.1001-3849.2022.04.011]
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镀膜参数对浮法玻璃热反射合金膜性能的影响()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2022年4
页码:
51-55
栏目:
出版日期:
2022-04-15

文章信息/Info

Title:
Effects of Coating Parameters on Properties of Float Glass Heat-Reflective Alloy Films
作者:
赵会峰1; 刘广财1; 余德兴2; 王琦1; 姜宏1 3*
（1.海南海控特玻科技有限公司，海南 澄迈 571924； 2.海南中航特玻材料有限公司，特种玻璃国家重点实验室，海南 澄迈 571924； 3.海南大学 材料科学与工程学院，海南 海口 570228）
Author(s):
ZHAO Huifeng1;  LIU Guangcai1;  YU Dexing2;  WANG Qi1;  JIANG Hong1 3*
( 1.AVIC ( Hainan ) Special Glass Technology Co. Ltd. Chengmai 571924 China 2.AVIC ( Hainan ) Special Glass Materials Co. Ltd. State Key Laboratory of Special Glass Chengmai 571924 China 3.School of Materials Science and Engineering Hainan University Haikou 570228 China )
关键词:
在线镀膜; 热反射合金膜; 气体流量; 耐酸性
Keywords:
online coating ; heat-reflective alloy film; ??as flow rate; ??cid resistance
分类号:
TB43
DOI:
10.3969/j.issn.1001-3849.2022.04.011
文献标志码:
A
摘要:
通过改变气体流量、镀膜温度、锡槽保护气用量，研究浮法玻璃在线镀膜参数对热反射合金膜的影响。采用扫描电子显微镜和能谱仪分析膜层的表面形貌、厚度和化学组成，采用分光光度计分析镀膜玻璃的光学性能和颜色指标，并配制 5 mol/L 的 H 2 SO 4 溶液测试薄膜的耐酸性能。结果表明，随着气体流量增大，镀膜层厚度增大，膜层颗粒度基本不变，镀膜玻璃透过率、太阳光遮阳系数和玻璃亮度均降低，膜层耐酸性增强。降低镀膜温度，晶粒结合变得疏松，膜层耐酸性降低。关闭锡槽保护气体 H 2 ，膜层颗粒、厚度减小，玻璃亮度、遮阳系数和膜层耐酸性均有提高。由此可知，任一参数发生变化时，均影响镀膜材料的反应速率， Cr 2 O 3 、 Fe 2 O 3 、 CoO 等金属氧化物及元素比例改变可影响玻璃的颜色和耐酸性。
Abstract:
： The effect of the float glass online coating parameters on the heat-reflective alloy film was studied by changing the gas flow ， coating temperature ， and the amount of shielding gas in the tin bath. The surface morphology ， thickness and chemical composition of the film were tested using scanning electron microscope （ SEM ） and energy spectrometer （ EDS ）， the optical properties and color indexes of the coated glass were analyzed by spectrophotometer. In addition ， the acid resistance of the film was tested by preparation of 5 mol/L H 2 SO 4 solution. The results showed that with the increase of gas flow ， the thickness of the coating layer increased ， the particle size of the coating layer was basically unchanged ， the transmittance of the coating glass ， the solar shading coefficient and the glass brightness were all reduced ， and the acid resistance of the coating layer is enhanced. When the coating temperature is reduced ， the grain binding became loose and the film resistance decreased. Turn off the protection gas H 2 for tin tank ， the particles and thickness of the film were reduced ， and the brightness of the glass ， the shading coefficient and the acid resistance of the film were improved. It can be seen that the reaction rate of coating material was affected when any parameter changed. The change in the ratio of metal oxides such as Cr 2 O 3 ， Fe 2 O 3 ， CoO and the elements could affect the color and acid resistance of the glass.

参考文献/References:



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备注/Memo

备注/Memo:
收稿日期： 2020-04-17 修回日期： 2021-04-30 第一 作者： 赵会峰（ 1966- ），女，研究员级高工，主要从事特种玻璃研究。 email ： greenapple146@sina.com * 通信作者： 姜宏（ 1961- ），男，博士，教授， email ： jhong63908889@sina.com 基金项目： 海南省重点研发计划项目（ ZDYF2021GXJS027 ）；海南省重大科技计划项目（ ZDKJ2021049 ）
更新日期/Last Update: 2022-04-20