[1]谷英花*,任航星,毕康璐,等.doi: 10.3969/j.issn.1001-3849.2025.09.013铱基析氧催化剂在质子交换膜水电解领域的研究进展[J].电镀与精饰,2025,(09):90-96.
　Gu Yinghua*,Ren Hangxing,Bi Kanglu,et al.Research progress of iridium-based oxygen evolution catalyst for water electrolysis with proton exchange membrane[J].Plating & Finishing,2025,(09):90-96.
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doi: 10.3969/j.issn.1001-3849.2025.09.013铱基析氧催化剂在质子交换膜水电解领域的研究进展()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年09
页码:
90-96
栏目:
出版日期:
2025-09-30

文章信息/Info

Title:
Research progress of iridium-based oxygen evolution catalyst for water electrolysis with proton exchange membrane
作者:
谷英花*; 任航星; 毕康璐; 曹 轩; 李亚辉; 袁先明
(中船(邯郸)
Author(s):
Gu Yinghua*;  Ren Hangxing;  Bi Kanglu;  Cao Xuan;  Li Yahui;  Yuan Xianming
(Peric Hydrogen Technologies Co., Ltd., Handan 056010, China)
关键词:
PEM水电解; 析氧反应; 铱基催化剂
Keywords:
PEM water electrolysis;  oxygen evolution reaction;  iridium-based catalyst
分类号:
TQ153.2
文献标志码:
A
摘要:
质子交换膜(PEM)水电解技术在可再生能源电催化制氢的背景下倍受关注，其具有电流密度大、氢气纯度高和响应速度快等优点，是制氢领域极具发展前景的电解水技术之一。阳极的析氧反应(OER)动力学缓慢，对器件的整体效率有重要影响。因此，在酸性介质中为高效的PEM水电解开发高性能的OER催化剂仍然是一个挑战。目前，铱(Ir)基催化剂是酸性介质中最有希望用于PEM水电解的OER催化剂。本文综述了Ir基阳极OER催化剂的研究进展，重点讨论了通过纳米结构设计、合金化策略以及载体优化等手段提升催化性能的研究。展望了开发可行的阳极OER催化剂用于PEM水电解制氢技术的未来方向，包括通过密度泛函理论指导材料设计并结合可控合成方法制备具有特定结构特征的Ir基催化剂，发展原位表征技术以揭示催化剂动态演变规律和真实活性位点，开发规模化制备工艺以满足工业应用需求。
Abstract:
Proton exchange membrane (PEM) electrolysis technology is gaining increasing attention in the context of renewable energy-driven electrocatalytic hydrogen production, boasting advantages such as high current density, high hydrogen purity, and fast response speed, making it one of the most promising electrolysis water technologies in the hydrogen production field. The oxygen evolution reaction (OER) on the anode is slow, which has a significant impact on the overall efficiency of the device. At present, iridium (Ir)-based catalysts are the most promising OER catalysts for PEM electrolysis in acidic media. This article reviews the research progress of Ir-based anode OER catalysts, with a focus on the studies that aim to enhance catalytic performance through means such as nanostructure design, alloying strategies, and carrier optimization. The future directions for developing feasible anode OER catalysts for PEM water electrolysis hydrogen production technology were envisioned, including using density functional theory to guide material design and combining with controllable synthesis methods to prepare Ir-based catalysts with specific structural characteristics, developing in-situ characterization techniques to reveal the dynamic evolution rules and real active sites of the catalysts, and developing large-scale production processes to meet the requirements of industrial applications

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更新日期/Last Update: 2025-09-11