[1]王雅骁,杨建军*,韩雨生,等.doi: 10.3969/j.issn.1001-3849.2025.11.004电流体动力氧化还原3D打印制备金属铜线的成形规律研究[J].电镀与精饰,2025,(11):31-37.
　Wang Yaxiao,Yang Jianjun*,Han Yusheng,et al.Study on forming rules of electrohydrodynamic Redox 3D printing for metal copper wire[J].Plating & Finishing,2025,(11):31-37.
点击复制

doi: 10.3969/j.issn.1001-3849.2025.11.004电流体动力氧化还原3D打印制备金属铜线的成形规律研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年11
页码:
31-37
栏目:
出版日期:
2025-11-30

文章信息/Info

Title:
Study on forming rules of electrohydrodynamic Redox 3D printing for metal copper wire
作者:
王雅骁; 杨建军*; 韩雨生; 郑 莹
(青岛理工大学 机械与汽车工程学院,山东 青岛 266520)
Author(s):
Wang Yaxiao;  Yang Jianjun*;  Han Yusheng;  Zheng Ying
(School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, China)
关键词:
电流体动力学; 氧化还原; 金属结构; 3D打印
Keywords:
electrohydrodynamics;  redox;  metal structure;  3D printing
分类号:
TQ153.1+4
文献标志码:
A
摘要:
电流体动力学氧化还原打印(EHD-RP)能够直接在微纳米尺度下制造金属3D结构，并且无需后处理，但打印过程中对电压、打印速度等参数较敏感。针对此问题，以CuSO4溶液作为打印材料，借助多物理场仿真分析电压和打印高度对电流体动力喷射的影响规律，通过具体实验探究了电流体动力学氧化还原打印过程中打印电压、打印高度、气压和打印速度对沉积铜线直径的影响规律，并进行线栅和网栅样件的打印。对成品进行透光率测试，在可见光范围内电极有平缓的光谱透过率。本研究将为电流体动力学氧化还原3D打印技术的进一步发展提供理论支持。
Abstract:
Electrohydrodynamic Redox (Reduction-Oxidation) printing (EHD-RP) can directly manufacture metal 3D structures at micro and nano scale without post-processing, but the printing process is sensitive to parameters such as voltage and printing speed. To solve this problem, CuSO4 solution was used as printing material, and the influence law of voltage and printing height on electrohydrodynamic jet was analyzed by multi-physical field simulation. The influence law of printing voltage, printing height, air pressure and printing speed on deposited copper wire diameter during electrohydrodynamic Redox printing was explored through specific experiments, and wire grid and mesh grid samples were printed. The light transmittance test of the finished product shows that the electrode has gentle spectral transmittance in the visible range. It provides theoretical support for the further development of electrohydrodynamic Redox 3D printing technology.

参考文献/References:

[1].Braun T M, Schwartz D T.The emerging role of electrode -position in additive manufacturing[J]. Electrochemical So-ciety Interface, 2016, 25(1): 69-73.
[2].Hernandez P, Campos D, Socorro P, et al. Electroforming applied to manufacturingof microcomponents[J]. Procedia Engineering, 2015,132: 655-662.
[3].Kamaraj A, Lewis S, Sundaram M. Numerical studyof localized electrochemical deposition for micro electrochemical additive manufacturing[J]. Procedia CIRP, 2016, 42: 788-792.
[4].魏雷, 林鑫, 王猛, 等. 金属激光增材制造过程数值模拟[J]. 航空制造技术, 2017(13): 16-25.
[5].Ning D, Zhang A, Murtaza M, et al.Effect of surfactants on the electrodeposition of Cu-TiO2 composite coatings prepared by jet electrodeposition[J]. Journal of Alloys and Compounds, 2019, 777(10): 1245-1250.
[6].He G, Lu S, Xu W, et al. Stable superhydrophobic Zn/ZnO surfaces fabricated via electrodeposition on tin substrate for self-cleaning behavior and switchable wettability[J]. Jour-nal of Alloys and Compounds, 2018, 747(30):772-782.
[7].Qiao G, Jing T, Wang N, Gao Y, et al. High-speed jet electrodeposition and microstructure of nanocrystalline Ni-Co alloys[J]. Electrochimica Acta, 2005, 51(1): 85-92.
[8].Jiang W, Shen L, Qiu M, et al. Microhardness, wear, and corrosion resistance of Ni-SiC composite coating with magnetic-field-assisted jet electrodeposition[J]. Materials Research Express, 2018, 5: 096407.
[9].Cui W, Wang K, Xia F, et al.Simulation and characterization of Ni-doped SiCnanocoatings prepared by jet electrodepo-sition[J]. Ceramics International 2018, 44(5): 5500-5505.
[10].Park J U, Hardy M, Kang S, et al. High-resolution elec-trohydrodynamic jet printing[J]. Nature Materials. 2007(6): 782-789.
[11].Li A, Luo Q, Park SJ, et al. Synthesis and catalytic reactions of nanoparticles formed by electrospray ionization of coi-nage metals[J]. Angewandte Chemie-International Edition. 2014, 53(12): 3147-3150.
[12].Reiser A, Lukas K, Kathleen A, et al. Metals by micro-scale additive manufacturing: Comparison of microstructure and mechanical properties[J]. Advanced Functional Materials, 2020, 30(28): 1-20.
[13].Reiser A, Lindén M, Rohner P, et al. Multi-metal electrohydrodynamic redox 3D printing at the submicron scale[J]. Nature Communication, 2019(10):1853.
[14].Nikolaus P, Mirco N, Maxence M, et al. Micron-scale additive manufacturing of binary and ternary alloys by electrohydrodynamic redox 3D printing[J]. Materials & Design, 2023, 234:112364.
[15].Nydegger M, Pru?ka A, Galinski H, et al. Additive manufacturing of Zn with submicron resolution and its conversion into Zn/ZnO core-shell structures[J]. Nanoscale, 2022,14(46): 17418-17427.
[16].王莉, 韦诗嘉, 冯学明, 等. 一种基于电流体还原滴印的微电极结构制备装置及方法: 中国, 113737235 A[P]. 2021-12-03.
[17].Hirt L, Reiser A, Spolenak R, et al. Additive manufacturing of metal structures at the micrometer scale[J]. Advanced Materials. 2017, 29(17): 1604211.
[18].Mishra P, Shruti S, Mayank P, et al. Additive manufacturing (3D Printing): A review on the micro fabrication methods[J]. International Journal for Research in Applied Science & Engineering Technology. 2020(8): 956-975.
[19].Yazdi A A, Popma A, Wong W, et al. 3D printing: an emerging tool for novel microfluidics and lab-on-a-chip applications[J]. Microfluid Nanofluid, 2016, 20(3): 1-18.
[20].Jae-Hwang L, Jonathan P S, Edwin L T, et al.Micro-nanostructured mechanical metamaterials[J]. Advanced Materials, 2012, 24(36): 4782-4810.

更新日期/Last Update: 2025-11-20