[1]陆 昆*,赵立军.doi: 10.3969/j.issn.1001-3849.2025.12.014TiO2基光催化材料的制备、改性和应用研究进展[J].电镀与精饰,2025,(12):107-116.
　Lu Kun*,Zhao Lijun.Research progress on preparation, modification and application of TiO2-based photocatalytic materials[J].Plating & Finishing,2025,(12):107-116.
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doi: 10.3969/j.issn.1001-3849.2025.12.014TiO2基光催化材料的制备、改性和应用研究进展()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年12
页码:
107-116
栏目:
出版日期:
2025-12-31

文章信息/Info

Title:
Research progress on preparation, modification and application of TiO2-based photocatalytic materials
作者:
陆 昆1*; 赵立军2
(1. 滁州城市职业学院 生物医药学院,安徽 滁州 239000 ;2. 江苏科技大学 材料科学与工程学院,江苏 镇江 212003)
Author(s):
Lu Kun1*;  Zhao Lijun2
(1. School of Biomedicine, Chuzhou City Vocational College, Chuzhou 239000, China; 2. College of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China)
关键词:
二氧化钛; 光催化; 制备方法; 改性研究
Keywords:
TiO2;  photocatalysis;  preparation method;  modification research
分类号:
TG174.4；TQ153
文献标志码:
A
摘要:
TiO2基光催化材料在环境净化和生物医学领域展现出巨大潜力，但其本征宽带隙和高载流子复合率严重制约实际应用。从“结构调控-性能优化-应用拓展”的耦合机制视角，系统评述了该领域的最新进展。首先，深入剖析了水热合成法、溶胶-凝胶法、等离子喷涂法和磁控溅射等关键制备技术对TiO2材料微观结构的精确调控规律及其对光催化活性、稳定性和可加工性的决定性影响。其次，聚焦于通过离子掺杂、半导体复合及表面修饰等改性策略，系统阐释了电子结构、载流子动力学及表面特性的协同优化机制，揭示了性能增强的物理化学本质。最后，分析了TiO2基光催化功能材料的研究发展趋势，指出其在光催化增效机制、环境治理技术升级和生物医学前沿探索等领域的潜在应用。通过梳理现有成果，为设计高效、智能、多功能的下一代TiO2基光催化材料提供了理论支撑和创新思路，为其推广应用提供参考，旨在进一步推动光催化材料在材料科学的发展。
Abstract:
TiO2-based photocatalytic materials have shown great potential in the fields of environmental purification and biomedicine, but their intrinsic wide band gap and high carrier recombination rate seriously restrict their practical applications. The latest progress in this field was systematically reviewed from the perspective of the coupling mechanism of “structure regulation-performance optimization-application expansion”. Firstly, the precise regulation of the microstructure of TiO2 materials by key preparation techniques such as hydrothermal synthesis, sol-gel method, plasma spraying and magnetron sputtering and its decisive influence on photocatalytic activity, stability and processability were deeply analyzed. Secondly, focusing on the modification strategies such as ion doping, semiconductor compounding and surface modification, the synergistic optimization mechanism of electronic structure, carrier dynamics and surface properties was systematically explained, and the physical and chemical nature of performance enhancement was revealed. Finally, the research and development trends of TiO 2-based photocatalytic functional materials were analyzed, and their potential applications in the fields of photocatalytic synergistic mechanism, environmental governance technology upgrading and biomedical frontier exploration were pointed out. By combing the existing achievements, it provides theoretical support and innovative ideas for the design of efficient, intelligent and multi-functional next-generation TiO2-based photocatalytic materials, and provides a reference for its popularization and application, aiming to further promote the development of photocatalytic materials in materials science

参考文献/References:

[1].Zhou Z, Li B, Liu X, et al. Recent progress in photocatalytic antibacterial[J]. ACS Applied Bio Materials, 2021, 4(5): 3909-3936.
[2].丁良兵, 刘东光. TiO2/Al2O3复合陶瓷热控涂层制备与性能[J]. 电镀与精饰, 2019, 41(8): 25-28.
[3].Shah L A, Malik T, Siddiq M, et al. TiO2 nanotubes doped poly (vinylidene fluoride) polymer membranes (PVDF/ TNT) for efficient photocatalytic degradation of brilliant green dye[J]. Journal of Environmental Chemical Engineering, 2019, 7(5): 103291.
[4].翦奉林, 金凡亚, 冯军, 等. 微弧氧化TiO2涂层微结构对细胞黏附性能的影响[J]. 材料保护, 2023, 56(10): 123-129.
[5].Nawaz H, Umar M, Nawaz I, et al. Photodegradation of textile pollutants by nanocomposite membranes of polyvi-nylidene fluoride integrated with polyaniline-titanium dioxide nanotubes[J]. Chemical Engineering Journal, 2021, 419: 129542.
[6].雷思哲, 翟晓霞, 阮乐, 等. 工艺参数对Zn-TiO2复合镀层性能的影响[J]. 电镀与精饰, 2024, 46(11): 17-22.
[7].Wang Z Q, Hao Q Q, Mao X C, et al. Characterization of the excited state on methanol/TiO2(110) interface[J]. Chinese Journal of Chemical Physics, 2015, 28(2): 123-127.
[8].许秀婷, 吉连忠, 陈书文, 等. 聚苯胺-TiO2复合膜对316L不锈钢耐蚀性能的影响[J]. 电镀与精饰, 2023, 45(1): 28-32.
[9].胡皓, 高鑫, 贾冠冠, 等. Fe3+-TiO2/ACF复合材料的制备及其性能研究[J]. 化工新型材料, 2023, 51(8): 141-146.
[10].汪文华, 雷彩虹, 余媛, 等. 基于Zn2+与Mo6+共掺杂TiO2复合粒子的抗菌PVDF平板膜制备及其性能分析[J]. 浙江理工大学学报(自然科学版), 2022, 47(4): 524-532.
[11].Lu K, Sun M, Jiang Y H, et al. Insight into the structural and performance correlation of photocatalytic TiO2/Cu composite films prepared by magnetron sputtering method[J]. Catalysts, 2024, 14(9): 621-635.
[12].Sun R J, Chen Z L, Peng J T, et al. The effect mechanisms of pH, complexant and calcination temperature on the hydrophilicity of TiO2 films prepared by the sol-gel method[J]. Applied Surface Science, 2018, 462: 480-488.
[13].张杰, 邹君文, 刘学广, 等. 改性TiO2防污闪复合涂层的制备与研究[J]. 材料保护, 2024, 57(12): 114-121.
[14].Lin W H, Chen S N, Wang J X, et al. Study on structural, optical and hydrophilic properties of FTO/TiO2 tandem thin film prepared by aerosol-assisted chemical vapor deposi-tion method[J]. Surface and Coatings Technology, 2019, 358: 715-720.
[15].Guo F, Liu J M, Zhang W G, et al. Synthesis of Cu, N-doped TiO2 nanotube by a novel magnetron sputtering method and its photoelectric property[J]. Vacuum, 2019, 165: 223-231.
[16].Liu Y, Xu C, Feng Z D. Characteristics and anticorrosion performance of Fe-doped TiO2 films by liquid phase deposition method[J]. Applied Surface Science, 2014, 314: 392-399.
[17].王晓辉, 李新梅, 张景. 喷涂距离对Al2O3-TiO2涂层组织与干摩擦性能的影响[J]. 电镀与精饰, 2019, 41(11): 1-5.
[18].高凯, 李志宏, 单冬冬, 等. 溶胶凝胶涂覆制备金刚石/陶瓷复合材料及其物理性能特点[J]. 化工进展, 2011, 30(10): 2252-2257.
[19].崔烺, 王守勇, 尹飞, 等. 喷涂及激光熔覆制备难熔金属涂层的研究现状[J]. 材料保护, 2023, 56(5): 153-163.
[20].姚远. 微波水热法制备钴、钇和钴-钇掺杂TiO2光催化剂及其光催化活性[D]. 昆明: 云南师范大学, 2021.
[21].Nishiyama N, Ichioka K, Park D H, et al. Reactant-selective hydrogenation over composite silicalite-1 coated Pt/TiO2 particles[J]. Industrial & Engineering Chemistry Research, 2004, 435: 1211-1215.
[22].郭萍, 朱宪忠. 水热合成法制备TiO2膜层条件及质量研究[J]. 化工新型材料, 2016, 44(4): 214-216.
[23].薛寒松, 顾铭, 曾强, 等. 微波水热合成法制备TiO2纳米管的晶型和形貌研究[J]. 化工新型材料, 2015, 43(11): 182-184.
[24].白晶, 赫丽杰, 徐晓辰, 等. 溶胶-凝胶法制备TiO2/硅藻土复合材料及其光催化性能[J]. 有色金属(冶炼部分), 2023(11): 106-112.
[25].Laghrib S, Gherdaoui E C, Belgherbi O, et al. Photocatalytic degradation of methylene blue using TiO 2 nanoparticles synthesized via the sol-gel method in acidic and neutral media[J]. Reaction Kinetics, Mechanisms and Catalysis, 2025, 138(3): 1-21.
[26].王哲昊, 吕绪明. 等离子喷涂技术在工程陶瓷涂层制备中的应用现状及展望[J]. 材料导报, 2024, 38(11): 52-61.
[27].崔赛楠, 范秀娟, 尹辉俊, 等. 悬浮液等离子喷涂高效制备TiO2涂层及其光催化性能[J]. 表面技术, 2024, 53(1): 209-219.
[28].胡林荣, 所彭帮, 龙金, 等. 大气等离子喷涂Al2O3-TiO2-Ni5Al复合涂层的性能及应用[J]. 电镀与精饰, 2025, 47(6): 28-34.
[29].周志强, 郝娇山, 宋文文, 等. 钛合金表面等离子喷涂Al2O3-40%TiO2陶瓷涂层的高温摩擦磨损性能[J].表面技术, 2023, 52(12): 351-359.
[30].王朝勇, 黄晓亚, 魏瑞朋, 等. 能量过滤磁控溅射技术制备Cu2O/TiO2复合薄膜及其光催化性能[J]. 表面技术, 2020, 49(6): 132-137.
[31].季震宇, 马迅, 刘平, 等. TiO2对磁控溅射Ti-TiO2纳米复合涂层抗菌性能的影响[J]. 有色金属材料与工程, 2023, 44(2): 75-84.
[32].Wongthawachnugool S, Limwichean S, Eiamchai P, et al. Enhanced hydrophilicity and optical properties of TiO2 slanted nanorod films fabricated by reactive gas-timing magnetron sputtering with oblique angle deposition technique[J]. Vacuum, 2025, 238: 114327.
[33].Sun L, Hu X, Yuan Z, et al. Photocatalytic properties of Ag-modifying N-TiO2 films prepared via magnetron sputtering[J]. Catalysts, 2025, 15(2): 164-175.
[34].Nikolova P M, Yousefi S, Handzhiyski Y, et al. One-step magneton sputtering of crystalline Cu-doped TiO2 coatings: characterization and antibacterial activity[J]. Applied Sciences, 2024, 14(20): 9578-9590.
[35].Li M J, Wang Z L, Jin W H, et al. Highly efficient visible-blind ultraviolet photodetector based on scalably produced titanium dioxide nanowire arrays[J]. Nano Letters, 2023, 23(13): 6059-6066.
[36].Hardin E B, Hoke T E, Armstrong B P, et al. Increased light harvesting in dye-sensitized solar cells with energy relay dyes[J]. Nature Photonics, 2009, 3(11): 667-674.
[37].Cong S R, Cai J H, Li X Y, et al. Direct z-scheme xylan-based carbon dots@TiO2-x nanocomposites for visible light driven photocatalytic of dye degradation and antibacterial[J]. Advanced Functional Materials, 2024, 34(32): 2401540.
[38].王鑫娈, 任璐, 倪嘉, 等. TiO2基自洁净玻璃的研究及应用进展[J]. 表面技术, 2025, 54(6): 19-35.
[39].荆倩, 曹晗, 刘方园, 等. 铁离子掺杂TiO2的制备及其光催化性能[J]. 材料研究学报, 2022, 36(11): 862-870.
[40].刘羽熙, 张鸣, 顾瑜, 等. 镍离子掺杂TiO2涂层的制备及亲水性研究[J]. 表面技术, 2021, 50(5): 127-132.
[41].Sharma S D, Singh D, Saini K K, et al. Sol-gel-derived super-hydrophilic nickel doped TiO2 film as active photo-catalyst[J]. Applied Catalysis A: General, 2006, 314(1): 40-46.
[42].Dong P M, Yang F F, Cheng X C, et al. Plasmon enhanced photocatalytic and antimicrobial activities of Ag-TiO2 nanocomposites under visible light irradiation prepared by DBD cold plasma treatment[J]. Materials science & engineering, 2019, 96: 197-204.
[43].何雪薇, 周晟戎, 李光照, 等. 稀土镨、钆离子掺杂改性纳米TiO2的制备及光催化研究[J]. 功能材料, 2025, 56 (5): 5135-5142.
[44].Chen J, Zhang Y, Li Y, et al. N-doped TiO2 with stable surface Ti 3+ for visible light photocatalytic hydrogen production[J]. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2025, 47(1): 11946-11956.
[45].Fu W G, Zhang L, Wu W L, et al. S-doped TiO2 nanotubes decorated whisker mullite-based hollow fiber membrane with anti-fouling and photocatalytic self-cleaning properties for high-efficient separation of emulsified oily wastewater[J]. Separation and Purification Technology, 2025, 373: 133615.
[46].Xu W Y, Yang M H, Du M H, et al. Deep remediation of oil spill based on the photocatalytic degradation of solar light-driven floating C-doped TiO2/sepiolite composites[J]. Journal of Industrial and Engineering Chemistry, 2025, 145: 610-619.
[47].张家琪, 林雪玲, 田文虎, 等. 应变对Si掺杂A-TiO2光学性质影响的第一性原理研究[J]. 人工晶体学报, 2025, 54(4): 617-628.
[48].李大玉, 张徐, 李嘉伟, 等. Si掺杂对溶液等离子喷涂TiO2涂层结构及光催化性能的影响[J]. 表面技术, 2018, 47(5): 220-226.
[49].彭富昌, 李然, 刘翘楚, 等. 纳米TiO2光催化剂的改性及其在VOCs治理中的应用研究进展[J]. 化工新型材料, 2022, 50(7): 283-288.
[50].Long Z, Li Q, Wei T, et al. Historical development and prospects of photocatalysts for pollutant removal in water[J]. Journal of Hazardous Materials, 2020, 395: 122599.
[51].杜欢, 邹渝, 赵忠. MnO2、ZnO复合半导体改性TiO2的光催化氧化VOCs的性能研究[J]. 化工管理, 2019(13): 117-119.
[52].王浩, 赵硕涵, 王秋龙, 等. CeO2-CuO/TiO2催化剂的制备及其在微波下降解苯乙烯的性能研究[J]. 陶瓷学报, 2025, 46(3): 499-505.
[53].Liu W, Liu D Y, Zhang Z Y, et al. Synthesis of core-shell nanostructured SiO2/TiO2 photocatalysts via atomic layer deposition in a fluidized bed with central tube[J]. Particuology, 2024, 91: 19-28.
[54].Xie J L, Hong W, Meng M W, et al. Synthesis and photocatalytic activity of cerium-modified CdS-TiO2 pho -tocatalyst for the formaldehyde degradation at room temperature[J]. Zeitschrift Für Anorganische Und Allgemeine Chemie, 2018, 644(23): 1570-1575.
[55].Stefan M, Leostean C, Pana O, et al. Interface tailoring of SnO2-TiO2 photocatalysts modified with anionic/cationic surfactants[J]. Journal of Materials Science, 2020, 55(21): 3279-3298.
[56].贾斌中, 杨夏渊, 李羿龙, 等. TiO2纳米粒子表面修饰对变压器油冲击击穿性能的影响[J]. 绝缘材料, 2024, 57(3): 23-28.
[57].Zhang R G, Gong K W, Du F Y, et al. Highly efficient thiomolybdate [Mo2S12]2- nanocluster cocatalyst decorated on TiO2 to boost photocatalytic hydrogen evolution[J]. International Journal of Hydrogen Energy, 2022, 47(45): 19570-19579.
[58].王瑛琦, 常嘉怡, 李敏, 等. 金属原子表面修饰TiO2光电催化CO2与NO2–共还原合成尿素[J]. 化学学报, 2025, 83(3): 247-255.
[59].Cao Y D, Di Y, Wang M L, et al. Pt-substituted polyoxometalate modification on the surface of low-cost TiO2 with highly efficient H2 evolution performance[J]. Dalton transactions, 2020, 49(7): 2176-2183.

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更新日期/Last Update: 2025-12-18