[1]廖 丹,张文展,胡佳幸,等.doi: 10.3969/j.issn.1001-3849.2026.02.002基于二维材料的析氢电催化剂研究进展[J].电镀与精饰,2026,(02):19-26.
　LIAO Dan,ZHANG Wenzhan,HU Jiaxing,et al.Research progress on hydrogen evolution electrocatalysts based on two-dimensional materials[J].Plating & Finishing,2026,(02):19-26.
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doi: 10.3969/j.issn.1001-3849.2026.02.002基于二维材料的析氢电催化剂研究进展()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2026年02
页码:
19-26
栏目:
出版日期:
2026-02-28

文章信息/Info

Title:
Research progress on hydrogen evolution electrocatalysts based on two-dimensional materials
作者:
廖 丹; 张文展; 胡佳幸; 周冬兰; 邱小林
(南昌理工学院 石墨烯与先进材料实验室,江西 南昌 330044)
Author(s):
LIAO Dan;  ZHANG Wenzhan;  HU Jiaxing;  ZHOU Donglan;  QIU Xiaolin
(Graphene and Advanced Materials Laboratory, Nanchang Institute of Technology, Nanchang 330044, China)
关键词:
二维材料; 电催化析氢; 材料改性; 能源转换
Keywords:
two-dimensional materials;  electrocatalytic hydrogen evolution;  material modification;  energy conversion
分类号:
TQ116.2
文献标志码:
A
摘要:
面对全球性的能源短缺和环境污染问题，氢能以其高能量密度和零排放的特性，被认为是未来能源转型的关键能源之一。电催化析氢反应(HER)作为一种高效氢气制备方法，引起科研人员的广泛关注。在众多电催化材料中，二维材料因其卓越的电子传输特性和可调控的化学活性，展现出高效电催化析氢的潜力。综合评述了二维材料在电催化析氢领域的最新研究动态，详细分析了缺陷调控、异质结构构建、相转变及氢键调节等策略提升二维材料析氢性能的有效方法。本文还探讨了当前二维材料在电催化析氢中存在的挑战，并对未来研究方向进行了展望。
Abstract:
Confronted with energy shortage and environmental pollution, hydrogen energy has emerged as a promising solution, celebrated for its high energy density and emission-free nature, and is widely concerned as pivotal in the transition to future energy systems. The electrocatalytic hydrogen evolution reaction (HER) stands out as an efficient pathway for hydrogen generation, garnering significant interest from the scientific community. Among various electrocatalytic materials, two-dimensional materials have demonstrated their potential in HER due to their superior electron transfer characteristics and adjustable chemical reactivity. This article offers an in-depth synthesis of the recent advancements in the application of two-dimensional materials for electrocatalytic hydrogen evolution, meticulously examining the effective approaches to enhance the HER performance of these materials. Strategies such as defect engineering, heterostructure assembly, phase transformation, and hydrogen bonding modulation are discussed in detail. Additionally, the paper delves into the current challenges associated with the use of two-dimensional materials in HER and outlines prospective research directions for the future. The aim is to lay a scientific foundation and guide material selection for the development of highly efficient and cost-effective hydrogen production methods.

参考文献/References:

[1].ZHANG J, ZHANG Q, FENG X. Support and interface effects in water‐splitting electrocatalysts[J]. Advanced Materials, 2019, 31(31): 1808167.
[2].HOU J, WU Y, ZHANG B, et al. Rational design of nanoarray architectures for electrocatalytic water splitting[J]. Advanced Functional Materials, 2019, 29(20): 1808367.
[3].CARELLA A, FRANZINI M, FUSCO S, et al. Isoindigo dyes functionalized with terminal electron-withdrawing groups: Computational, optical and electrical characterization[J]. Dyes and Pigments, 2023, 208: 110866.
[4].TANG T, WANG Z, GUAN J. A review of defect engineering in two-dimensional materials for electrocatalytic hydrogen evolution reaction[J]. Chinese Journal of Catalysis, 2022, 43(3): 636-678.
[5].SALEEM S, SALMAN M, ALI S, et al. Electrocatalytic hydrogen evolution reaction on sulfur-deficient MoS 2 nanostructures[J]. International Journal of Hydrogen Energy, 2022, 47(12): 7713-7723.
[6].张春雁, 窦真兰, 徐桂芝, 等. PEM电解槽制氢多相传输及转化模型综述[J].电池, 2024, 54(4): 569-573.
[7].VENKATESHWARAN S, JOSLINE M J, KUMAR S M S. Fine-tuning interlayer spacing in MoS2 for enriching 1T phase via alkylated ammonium ions for electrocatalytic hydrogen evolution reaction[J]. International Journal of Hydrogen Energy, 2021, 46(12): 8377-8390.
[8].ZAHRA S A, RIZWAN S. MWCNT-modified MXene as cost-effective efficient bifunctional catalyst for overall water splitting[J]. RSC advances, 2022, 12(14): 8405-8413.
[9].XIE T, SONG G, WANG G, et al. Amorphous iron boride in situ grown on black phosphorus sheets: A promising electrocatalyst for OER[J]. Journal of Electronic Materials, 2022, 51(7): 3705-3713.
[10].PRABHU P, JOSE V, LEE J M. Design strategies for development of TMD-based heterostructures in electrochemical energy systems[J]. Matter, 2020, 2(3): 526-553.
[11].张传香, 陈亚玲, 巩云, 等. 二硫化钼/石墨烯复合材料的一步水热合成及电催化性能[J]. 材料工程, 2020, 48(5): 56-61.
[12].DONG L, GUO S, WANG Y, et al. Activating MoS2 basal planes for hydrogen evolution through direct CVD morphology control[J]. Journal of Materials Chemistry A, 2019, 7(48): 27603-27611.
[13].KUMAR T H V, YADAV S K, SUNDRAMOORTHY A K. Electrochemical synthesis of 2D layered materials and their potential application in pesticide detection[J]. Journal of Electrochemical Society, 2018, 165(16): B848.
[14].张溪桓, 王鹏杰, 王明安, 等. 一种新型尖晶石异质结构的催化剂及析氧反应的研究[J]. 电镀与精饰, 2024, 46(9): 10-18.
[15].WYSS K M, LUONG D X, TOUR J M. Large‐scale syntheses of 2D materials: flash joule heating and other methods[J]. Advanced Materials, 2022, 34(8): 2106970.
[16].DONG S, SONG Y, SU M, et al. Flash Joule heating induced highly defective graphene towards ultrahigh lithium ion storage[J]. Chemical Engineering Journal, 2024, 481: 147988.
[17].LIAO Y, ZHU R, ZHANG W, et al. Transient synthesis of carbon-supported high-entropy alloy sulfide nanoparticles via flash Joule heating for efficient electrocatalytic hydrogen evolution[J]. Nano Research, 2024, 17(4): 3379-3389.
[18].KOPPENS F H L, MUELLER T, AVOURIS P, et al. Photodetectors based on graphene, other two-dimensional materials and hybrid systems[J]. Nature Nanotechnology, 2014, 9(10): 780-793.
[19].ZHANG X, LI J, XIAO P, et al. Morphology-controlled electrocatalytic performance of two-dimensional VSe 2 nanoflakes for hydrogen evolution reactions[J]. ACS Applied Nano Materials, 2022, 5(2): 2087-2093.
[20].HU R, JIANG H, XIAN J, et al. Microwave-pulse sugar-blowing assisted synthesis of 2D transition metal carbides for sustainable hydrogen evolution[J]. Applied Catalysis B: Environmental, 2022, 317: 121728.
[21].FAN M, TIAN H, WU Z, et al. Microwave Shock synthesis of porous 2D non-layered transition metal carbides for efficient hydrogen evolution[J]. SusMat, 2025, 5(2): e252.
[22].YANG S, ZHANG P, NIA A S, et al. Emerging 2D materials produced via electrochemistry[J]. Advanced Materials, 2020, 32(10): 1907857.
[23].张美霞, 吴王平, 王芹芹. 电沉积铱镍薄膜电催化剂及其析氢性能[J]. 电镀与精饰, 2024, 46(12): 136-144.
[24].SI J, CHEN H, LEI C, et al. Electrochemical exfoliation of ultrathin ternary molybdenum sulfoselenide nanosheets to boost the energy-efficient hydrogen evolution reaction[J]. Nanoscale, 2019, 11(35): 16200-16207.
[25].CHEN H, SI J, LYU S, et al. Highly effective electrochemical exfoliation of ultrathin tantalum disulfide nanosheets for energy-efficient hydrogen evolution electrocatalysis[J]. ACS Applied Materials & Interfaces, 2020, 12(22): 24675-24682.
[26].JIN L, WANG K, YANG L, et al. Engineering two-dimensional nanocatalysts for boosting water splitting[J]. International Journal of Hydrogen Energy, 2024, 51: 865-883.
[27].LI G, ZHANG D, QIAO Q, et al. All the catalytic active sites of MoS2 for hydrogen evolution[J]. Journal of American Chemical Society, 2016, 138(51): 16632-16638.
[28].LI Z, YUE Y, PENG J, et al. Phase engineering two-dimensional nanostructures for electrocatalytic hydrogen evolution reaction[J]. Chinese Chemical Letters, 2023, 34(1): 107119.
[29].FAN Z, LUO Z, HUANG X, et al. Synthesis of 4H/fcc noble multimetallic nanoribbons for electrocatalytic hydrogen evolution reaction[J]. Journal of American Chemical Society, 2016, 138(4): 1414-1419.
[30].ZHAO J W, WANG H Y, FENG L, et al. Crystal-phase engineering in heterogeneous catalysis[J]. Chemical Reviews, 2023, 124(1): 164-209.
[31].WANG K, YU K, XU S, et al. Synergizing lattice strain and electron transfer in TMSs@ 1 T-MoS2 in-plane heterostructures for efficient hydrogen evolution reaction[J]. Applied Catalysis B: Environmental, 2023, 328: 122445.
[32].WANG X, ZHOU W, WANG Y, et al. MoO2/Mo heterostructures for hydrogen evolution reaction and ammonia sensing in self-powered mode[J]. Nano Energy, 2023, 109: 108253.
[33].Dahl P J, Malvankar N S. The Jekyll-and-Hyde electron transfer chemistry of hydrogen bonds[J]. Nature Chemistry, 2024, 16: 1746-1747.
[34].GU Y, WU A, JIAO Y, et al. Two‐dimensional porous molybdenum phosphide/nitride heterojunction nanosheets for pH‐universal hydrogen evolution reaction[J]. Angewandte Chemie International Edition, 2021, 60(12): 6673-6681.
[35].WANG F, XIE L, SUN N, et al. Deformable catalytic material derived from mechanical flexibility for hydrogen evolution reaction[J]. Nano-Micro Letters, 2024, 16(1): 32.
[36].ZHANG T, YE Q, HAN Z, et al. Biaxial strain induced OH engineer for accelerating alkaline hydrogen evolution[J]. Nature Communications, 2024, 15(1): 6508.
[37].VALLINAYAGAM M, KARTHIKEYAN J, POSSELT M, et al. Metalloid-doping in SMoSe Janus layers: first- principles study on efficient catalysts for the hydrogen evolution reaction[J]. Journal of Materials Chemistry A, 2024, 12(13): 7742-7753.
[38].ZHANG Y, LIU X, WANG W. Theoretical calculation assisted by machine learning accelerate optimal electrocatalyst finding for hydrogen evolution reaction[J]. ChemElectroChem, 2024, 11(13): e202400084.

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备注/Memo

备注/Memo:
关键词：二维材料；电催化析氢；材料改性；能源转换
更新日期/Last Update: 2026-02-09