[1]唐 敏,刘 军,李岳峰.doi: 10.3969/j.issn.1001-3849.2026.04.006园林建筑用镁合金的表面改性与疏水耐蚀性能研究[J].电镀与精饰,2026,(04):39-44.
 TANG Min,LIU Jun,LI Yuefeng.Research on surface modification and hydrophobic corrosion resistance of magnesium alloy for landscape architecture[J].Plating & Finishing,2026,(04):39-44.
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doi: 10.3969/j.issn.1001-3849.2026.04.006园林建筑用镁合金的表面改性与疏水耐蚀性能研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2026年04
页码:
39-44
栏目:
出版日期:
2026-04-30

文章信息/Info

Title:
Research on surface modification and hydrophobic corrosion resistance of magnesium alloy for landscape architecture
作者:
唐 敏1刘 军1李岳峰2
(1. 河南林业职业学院 园林园艺学院,河南 洛阳,471002;2. 河南科技大学 材料科学与工程学院,河南 洛阳 471000)
Author(s):
TANG Min1 LIU Jun1 LI Yuefeng2
(1. School of Landscape Architecture and Horticulture, Henan Forestry Vocational College, Luoyang 471002, China; 2. School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471000, China)
关键词:
园林建筑MB15镁合金表面膜层疏水性耐蚀性能
Keywords:
landscape architecture MB15 magnesium alloy surface layer hydrophobicity corrosion resistance
分类号:
TQ050 TG174.4
文献标志码:
A
摘要:
为提升园林建筑用镁合金的超疏水性和耐腐蚀性能,采用电化学辅助沉积法在MB15镁合金表面制备硅烷膜,研究了沉积时间和不同含量添加剂十六烷基三甲基溴化铵(CTAB)对镁合金表面硅烷膜形貌、厚度、疏水性和耐蚀性能的影响。结果表明,MB15镁合金表面硅烷膜试样的疏水角和耐腐蚀性能高于镁合金基体试样;随着沉积时间延长,MB15镁合金表面硅烷膜疏水角增大、耐蚀性增强,在沉积时间达到180 s及以上时的硅烷膜具有超疏水性。添加十六烷基溴化铵添加剂后MB15镁合金表面硅烷膜的厚度和耐蚀性有不同程度增加;随着沉积时间延长,表面硅烷膜厚度不断增加且添加十六烷基溴化铵添加剂可缩短具有超疏水性的电沉积时间。相同沉积时间下添加十六烷基溴化铵添加剂后MB15镁合金表面膜层的耐蚀性增强;MB15镁合金表面适宜沉积时间为180 s,此时膜层已完全覆盖镁合金基体,且具有超疏水性和良好耐蚀性。
Abstract:
In order to improve the superhydrophobicity and corrosion resistance of magnesium alloys used in garden architecture, silane films were prepared on MB15 magnesium alloy by electrochemical-assisted deposition. The effects of deposition time and different content of additive cetyltrimethylammonium bromide (CTAB) on the morphology, thickness, hydrophobicity and corrosion resistance of silane films were studied. The results show that the hydrophobicity angle and corrosion resistance of the surface silane film on MB15 magnesium alloy are higher than those of magnesium alloy substrate. Moreover, as the deposition time increases, the hydrophobicity angle and corrosion resistance of the silane film continue to increase. The silane film sample with a deposition time of 180 s or longer exhibite superhydrophobicity. After adding hexadecyl ammonium bromide additive, the thickness and corrosion resistance of the silane film increase to varying degrees, and the thickness continues to increase with the prolongation of deposition time. Moreover, the addition of hexadecyl ammonium bromide additive can shorten the superhydrophobic electrodeposition time. At the same deposition time, the corrosion resistance of the surface facial mask of MB15 magnesium alloy is enhanced by adding cetyl ammonium bromide additive. The optimal deposition time for MB15 magnesium alloy is 180 s, at which point the film layer completely covers the magnesium alloy substrate and exhibits superhydrophobicity and excellent corrosion resistance.

参考文献/References:

[1].夏先朝, 潘玥, 袁杏, 等. 镁合金表面腐蚀防护技术研究进展[J]. 表面技术, 2023, 52(5): 37-50.
[2].CAO J K, MA B J, XU C P, et al. Research progress on superhydrophobic surface corrosion prevention of magnesium alloys: a review[J]. Materials Today Communications, 2024, 411: 10962-110969.
[3].吴瑜, 李月樵, 洪伟, 等. 镁合金微弧氧化膜致密化技术研究进展[J]. 电镀与精饰, 2024, 46(11): 76-85.
[4].刘明杰, 刘宁华, 赖心翘, 等. 一种用于镁铝合金表面微弧氧化陶瓷膜的封闭剂及性能研究[J]. 电镀与精饰, 2025, 47(2): 106-110.
[5].HAN Y J, WANG X X, WEI P G, et al. Biodegradable magnesium alloy janus membrane with surface-selective osteoinduction and soft tissue healing properties in guided bone regeneration[J]. Acta biomaterialia, 2025, 195: 582-598.
[6].王世颖, 康丰, 吴敏娴, 等. AZ31镁合金基Cu-MOF-SA超疏水膜的制备及其耐腐蚀性能研究[J]. 材料保护, 2024, 57(1): 148-155.
[7].谢陈凯, 金建港, 张立军, 等. 复合硅烷膜及双层硅烷膜对Mg-Gd-Y稀土镁合金耐蚀性的影响[J]. 上海航天, 2025, 42(1): 102-109.
[8].赵志杰, 赵景茂. AZ91D镁合金表面双层硅烷膜的制备及其性能研究[J]. 北京化工大学学报, 2019, 46(4): 46-53.
[9].ZHOU P, SUN S Y, LIU X Y, et al. Brushing conversion coating on magnesium alloys: a promising dry-in-place phosphate conversion treatment with high corrosion resistance for coating repair on Mg alloys[J]. Corrosion Science, 2025, 246: 112750-112758.
[10].PENG C, CAO N N, QI Z H, et al. Preparation and corrosion performance of PPy/silane film on AZ31 magnesium alloy via one-step cyclic voltammetry[J]. Polymers, 2021, 13(18): 3148-3153.
[11].田梦真, 王勇, 李涛, 等. 电参数对AZ31B镁合金微弧氧化膜能耗及耐蚀性的影响[J].中国腐蚀与防护学报, 2024, 44(4): 1064-1072.
[12].张雨露, 祁星, 姜波, 等. 硝酸铈添加剂对AZ91D镁合金微弧氧化膜组织与性能的影响[J]. 电镀与精饰, 2024, 46(8): 18-24.
[13].WANG Y, GU Z P, YUAN N Y, et al. Fabrication of anti-corrosion dual-component silane film on AZ31 Mg alloy surface by self-assembly method[J]. JOM, 2020, 72(2): 730-737.
[14].孙丽娟, 王潇, 李长青. 建筑用6061铝合金的表面改性与耐蚀耐磨性能研究[J]. 电镀与精饰, 2025, 47(2): 61-66.
[15].孙天逸, 管骏武, 张伊凡, 等. ZK60镁合金表面MAO-LDH疏水膜层的一步水热法制备及其耐蚀性能[J]. 材料热处理学报, 2024, 45(6): 121-129.
[16].CHEN L, DU S Y, QU X Y, et al. Improved protective properties of Mg alloy AZ31 using bis-[triethoxysilylpropyl] tetrasulfide silane films modified with nano TiO 2 by electrochemically assisted deposition[J]. Colloids and surfaces. B, Biointerfaces, 2024, 240: 113972-113979.
[17].孙伟清, 陈微, 王玮琪. 镁合金建筑模板的表面化学镀与耐蚀性能[J]. 电镀与精饰, 2024, 46(10): 34-41.
[18].郭超瑜, 宋铭龙, 朱永鹏, 等. EW75镁合金镧掺杂硫酸盐稀土转化膜的防护性能研究[J]. 现代交通与冶金材料, 2024, 4(3): 77-82.
[19].WANG Y, YIN M H, TANG A G, et al. Effect of chain length on the anticorrosion property of bis[3-(triethoxysilyl) propyl]tetrasulfide/trimethoxysilane dual-component silane film on the AZ31B Mg alloy surface[J]. Surface and Interface Analysis, 2021, 53(12): 1059-1068.
[20].YANG K K, KUANG Y L, XU B Q, et al. Simultaneously regulating electrochemical corrosion behavior and wettability of magnesium-neodymium alloy by self-layered chemical conversion coating[J]. Materials, 2024, 17(12): 2815-2822.

更新日期/Last Update: 2026-04-15