[1]刘石双,刘 璇,聂强胜,等.doi: 10.3969/j.issn.1001-3849.2026.04.007汽车用锌铝镁镀层钢板组织及耐蚀性研究[J].电镀与精饰,2026,(04):45-51.
 ZHOU Jiming,WU Guangyu,LI Xiaojun.Research on composition and corrosion resistance of zinc aluminum magnesium coating on steel plate for automobiles LIU Shishuang1, LIU Xuan2, NIE Qiangsheng1, HAN Long1, PAN Ming1, LI Runchang1,[J].Plating & Finishing,2026,(04):45-51.
点击复制

doi: 10.3969/j.issn.1001-3849.2026.04.007汽车用锌铝镁镀层钢板组织及耐蚀性研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2026年04
页码:
45-51
栏目:
出版日期:
2026-04-30

文章信息/Info

Title:
Research on composition and corrosion resistance of zinc aluminum magnesium coating on steel plate for automobiles LIU Shishuang1, LIU Xuan2, NIE Qiangsheng1, HAN Long1, PAN Ming1, LI Runchang1,
作者:
刘石双1刘 璇2聂强胜1韩 龙1潘 明1李润昌1周纪名1吴广宇1李晓军1
(1. 首钢京唐钢铁联合有限责任公司 制造部,河北 唐山 063200 ;2. 首钢京唐钢铁联合有限责任公司 冷轧作业部,河北 唐山 063200)
Author(s):
ZHOU Jiming1 WU Guangyu1 LI Xiaojun1
(1. Manufacturing Division, Shougang Jingtang United Iron and Steel Co., Ltd., Tangshan 063200, China; 2. Cold Rolling Department, Shougang Jingtang United Iron and Steel Co., Ltd., Tangshan 063200, China)
关键词:
锌铝镁轻量化镀层厚度耐蚀性
Keywords:
zinc aluminum magnesium lightweight coating thickness corrosion resistance
分类号:
TQ341 TG335.22
文献标志码:
A
摘要:
锌铝镁镀层具有出色的耐蚀性、良好的成形性和轻量化潜力等优势,在汽车领域具有广泛的应用前景,符合新一代绿色、低碳、降本的制造要求。本文通过SEM、辉光放电光谱仪(GDS)、XRD、盐雾实验(SST)箱等设备对比研究了不同镀层厚度(35、50和90 g/m2)的镀层组织及中性盐雾(Neutral Salt Spray,NSS)和循环盐雾(Circulating Salt Spray,CSS)环境下的腐蚀行为。结果表明:锌铝镁镀层组织相同,均由富Zn相、Zn/MgZn2二元共晶相和Zn/Al/MgZn2三元共晶相组成;锌铝镁镀层的厚度对耐腐蚀性有显著影响,镀层的耐腐蚀性随镀层厚度的增加而提升。随着镀层厚度的增加,镀层表面的主要腐蚀产物是Zn5(OH)8Cl2?H2O,这有利于减缓镀层的腐蚀。
Abstract:
Zinc aluminum magnesium (ZM) coating has advantages such as excellent corrosion resistance, well formability, and lightweight potential, making it widely applicable in the automotive industry and meeting the requirements of the new generation of green, low-carbon, and cost-effective manufacturing. The microstructure of coatings with different coating thicknesses (35, 50 and 90 g/m2) and the corrosion behavior under neutral salt spray (NSS) and cyclic salt spray (CSS) environments were analyzed by using SEM, glow discharge spectrometer (GDS), XRD, salt spray test (SST) chamber and other equipment. The results show that the microstructure of the coatings with different thicknesses exhibit identical, which is composed of Zn-rich phase, Zn/MgZn2 binary eutectic phase and Zn/Al/MgZn 2 ternary eutectic phase. The thickness of ZM coating has a significant impact on corrosion resistance, that the corrosion resistance of the coating increases with increasing of coating thickness. As the thickness of the coating increases, the main corrosion product on the coating surface is Zn5(OH)8Cl2?H2O, beneficial for slowing down the corrosion behavior

参考文献/References:

[1].SONG G M, VYSTAVEL T, VAN D P N, et al. Relation between microstructure and adhesion of hot dip galvanized zinc coatings on dual phase steel[J]. Acta Materialia, 2012, 60(6-7): 2973-2981.
[2].刘石双, 袁天祥, 刘延强, 等. 带钢热镀锌锌渣缺陷形成机理及控制措施[J]. 电镀与精饰, 2024, 46(9): 83-92.
[3].SALGUEIRO A M, ALLELY C, OGLE K, et al. Corrosion mechanisms of Zn (Mg, Al) coated steel in accelerated tests and natural exposure: 1. The role of electrolyte composition in the nature of corrosion products and relative corrosion rate[J]. Corrosion Science 2015, 90: 472-481.
[4].谢英秀, 金鑫焱, 王利. 热浸镀锌铝镁镀层开发及应用进展[J]. 钢铁研究学报, 2017, 29(3): 167-174.
[5].HE X, ZHOU X, SHANG T, et al. Influence mechanism of different elements and alloy phases on the corrosion resistance of Zn-Al-Mg coated steel in the atmospheric environment: a review[J]. Corrosion Communications, 2024, 13: 49-59.
[6].李海鹏, 孙邦兴, 李嘉烨. 双碳目标下绿色制氢技术的进展[J]. 电池, 2024, 54(2): 271-275.
[7].张继阳, 郑秀, 赵斌, 等. 电网级大规模储能的电池技术进展[J]. 电池, 2024, 54(5): 745-750.
[8].姚舜, 田耕, 马幸江, 等. 板带钢热浸镀锌铝镁技术的研究进展[J]. 钢铁研究学报, 2023, 35(12): 1451-1462.
[9].邹建国, 卢琳. 锌铝镁镀层中合金相与耐蚀性关系的研究进展[J]. 中国有色金属学报, 2022, 32(7): 1934-1944.
[10].SCHUERZ S, FLEISCHANDERL M, LUCKENEDER G H, et al. Corrosion behavior of Zn-Al-Mg coated steel sheet in sodium chloride-containing environment[J]. Corrosion Science, 2009, 51(10): 2355-2363.
[11].GU T Z, ZHANG P, GUO M X, et al. Corrosion behavior of zinc-aluminum-magnesium coated steel in simulated marine atmosphere[J]. International Journal of Electrochemical Science, 2022, 17: 22054.
[12].吕家舜, 李锋, 杨洪刚, 等. 热浸镀锌铝镁钢板镀层组织及腐蚀性能研究[J]. 材料工程, 2012, 40(10): 89-93.
[13].邵蓉, 黎敏, 刘永壮, 等. 镀层厚度对热纯锌板及热基锌铝镁板抗石击腐蚀性能的影响[J]. 腐蚀与防护, 2024, 45(3): 30-36.
[14].宋志岗, 王淑华, 梅淑文, 等. 拉伸应变对锌铝镁镀层裂纹及耐蚀性的影响[J]. 电镀与精饰, 2024, 46(3): 44-49.
[15].张鹏, 张杰, 梁爱国, 等. 冷却速度对锌铝镁镀层组织及耐蚀性能的影响[J]. 河北冶金, 2022(1): 30-33.
[16].王言峰, 马德刚, 李建英, 等. 加热制度对锌铝镁镀层结构及耐蚀性的影响[J]. 河北冶金, 2021(8): 28-30, 77.
[17].MA Z, DING C F, LU R, et al. Effect of Al and Sn on the microstructure, micro-hardness and corrosion properties of Zn-Al-Mg coatings[J]. Materials Today Communications, 2022, 33: 104892.
[18].蒋光锐, 郑学斌, 赵晓非, 等. 汽车车身用热浸镀锌铝镁镀层钢板[J]. 汽车工艺与材料, 2021(4): 12-22.
[19].张晨, 刘顺明, 王长成, 等. 不同厚度锌铝镁合金镀层的耐腐蚀性能[J]. 电镀与涂饰, 2024, 43(7): 92-100.
[20].黎敏, 郝玉林, 姚士聪, 等. 中性盐雾环境中典型汽车用钢的初期腐蚀行为[J]. 电镀与涂饰, 2019, 38(18): 1015-1021.
[21].CHAOUKI A, BEN A M, EL K, et al. Optimizing corrosion protection: performance comparison of Zn and Zn-Al-Mg alloys hot-dip galvanized coatings[J]. Journal of Alloys and Compounds, 2024, 1007: 176371.
[22].ZHENG L Y, CAO F H, LIU WJ, et al. Corrosion behavior of pure zinc and its alloy under thin electrolyte layer[J]. Acta Metallurgica Sinica, 2010, 23(6): 416-430.
[23].黎敏, 董妮妮, 潘明, 等. 典型汽车用镀锌板耐腐蚀性能研究[J]. 表面技术, 2023, 52(4): 295-303.
[24].庞晟, 何鑫, 商婷, 等. 热基锌铝镁镀层钢切边初始腐蚀机理和保护性能研究[J]. 材料保护, 2024, 57(6): 29-35.
[25].QIAO D G, WANG S L, NING P D, et al. Corrosion resistance of zinc-magnesium-aluminium alloy coated steel in marine atmospheric environments[J]. International Journal of Electrochemical Science, 2024, 19(8): 100705.

更新日期/Last Update: 2026-04-15