[1]李安心,朱增伟.doi: 10.3969/j.issn.1001-3849.2026.04.010超声作用下铁镍合金电化学性能研究[J].电镀与精饰,2026,(04):64-69.
　LI AnxinZHU Zengwei.Study on electrochemical properties of Fe-Ni alloys under ultrasonic[J].Plating & Finishing,2026,(04):64-69.
点击复制

doi: 10.3969/j.issn.1001-3849.2026.04.010超声作用下铁镍合金电化学性能研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2026年04
页码:
64-69
栏目:
出版日期:
2026-04-30

文章信息/Info

Title:
Study on electrochemical properties of Fe-Ni alloys under ultrasonic
作者:
李安心1; 朱增伟2
(1. 安徽职业技术大学 智能制造学院,安徽 合肥 230011 ;2. 南京航空航天大学 机电学院,江苏 南京 210016)
Author(s):
LI Anxin1ZHU Zengwei2
(1. College of Intelligent Manufacturing, Anhui University of Applied Technology, Hefei 230011, China; 2. College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics &Astronautics, Nanjing 210016, China)
关键词:
超声; 铁镍合金; 电沉积; 线性伏安扫描
Keywords:
ultrasonic;  Fe-Ni alloy;  electrodeposition;  linear scanning voltammetry
分类号:
TQ317
文献标志码:
A
摘要:
为制备出高性能的铁镍合金，本研究将超声场引入铁镍合金电铸工艺过程中。从微观电化学角度研究了超声对铁镍合金电沉积过程的影响。利用计时电流法研究了超声场中铁镍的形核和生长。结果表明，铁镍合金在不锈钢表面的电沉积符合电荷转移控制下瞬间形核三维生长的机理。在不同的超声功率下进行线性伏安扫描测试，以研究铁镍合金在超声场中电沉积的电化学机理。结果表明，铁镍沉积过程会由静态下的扩散控制转变成为超声作用下的电化学控制；超声电沉积铁镍合金的优化参数为超声功率80～100 W、电流密度≤10 mA/cm2。本研究为超声电铸制备铁镍合金的方法奠定了理论基础。
Abstract:
To prepare Fe-Ni alloy with high performance, the ultrasonic field was introduced into the electroforming process of Fe-Ni alloys. The influence of ultrasound on the electrodeposition of Fe-Ni alloy was systematically investigated from a micro-electrochemical perspective. The nucleation and growth behavior of Fe-Ni were studied using chronoamperometry under an ultrasonic field. The results show that the electrodeposition of iron-nickel alloys on the stainless-steel surface follows the mechanism of instantaneous nucleation and three-dimensional growth governed by charge transfer control. Linear scanning voltammetry was conducted under different ultrasonic powers to investigate the electrochemical mechanism of electrodeposition of Fe-Ni alloys in an ultrasonic field. The results indicate that the iron-nickel deposition process is transformed from diffusion control under static conditions to electrochemical control under ultrasonic irradiation. The optimum parameters for Fe-Ni electrodeposition under ultrasonic conditions are ultrasonic power between 80 ～100 W and current density ≤ 10 mA/cm 2. This research establishes a theoretical foundation for the ultrasonic electroforming method in Fe-Ni alloy preparation

参考文献/References:

[1].MCCREA J L, PALUMBO G, HIBBARD G D, et al. Properties and applications for electrodeposited nanocrystalline Fe-Ni alloy[J]. Reviews on Advanced Materialsence, 2003, 5: 252-258.
[2].KIM S H, CHOI S G, CHOI W K, et al. Pulse electrochemical machining on Invar alloy: optical microscopic/SEM and non-contact 3D measurement study of surface analyses[J]. Applied Surface Science, 2014, 314(24): 822-831.
[3].NAKAMURA Y T. Low Thermal expansion and fine-pitch metal masks fabricated via invar Fe-Ni alloy electroforming for large fine-pitch OLED displays[J]. SID International Symposium: Digest of Technology Papers, 2017, 48(1): 527-530.
[4].BALACHANDRAN R, YOW H K, ONG B H, et al. Effects of ultrasonic field in pulse electrodeposition of NiFe foil on Cu substrate[J]. Journal of Alloys and Compounds, 2009, 481: 336-339.
[5].HONMA H. Plating technology for electronics packaging[J]. Electrochimica Acta, 2001, 47(1-2): 75-84.
[6].CHANG W S, WEI Y, GUO J M, et al. Thermal stability of NiFe alloy foils continuously electrodeposited in a fluorborate bath[J]. Open Journal of Metal, 2012, 2(1): 18-23.
[7].NAGAYAMA T, YAMAMOTO T, NAKAMURA T. Thermal expansions and mechanical properties of electrodeposited Fe-Ni alloys in the invar composition range[J]. Electrochimica Acta, 2016, 205: 178-187.
[8].WAKABAYASHI H, SATO N, SONE M, et al. Nano-grain structure of nickel films prepared by emulsion plating using dense carbon dioxide[J]. Surface & Coatings Technology, 2005, 190(2-3): 200-205.
[9].YOSHIDA H, SONE M, MIZUSHIMA A, et al. Application of emulsion of dense carbon dioxide in electroplating solution with nonionic surfactants for nickel electroplating[J]. Surface and Coatings Technology, 2003, 173(2-3): 285-292.
[10].FRICOTEAUX P, ROUSSE C. Influence of substrate, pH and magnetic field onto composition and current efficiency of electrodeposited Ni-Fe alloys[J]. Journal of Electroanalytical Chemistry, 2008, 612(1): 9-14.
[11].WEN Y, ZHONG Y, REN Z, et al. Microstructure analysis of NiFe films electrodeposited in the parallel magnetic field[J]. Rare Metal Materials and Engineering, 2006, 35(8): 325-330.
[12].KIM H, MURPHY M C, PODLAHAA E J. Electrodeposition of high aspect ratio super invar microstructures[J]. Journal of the Electrochemical Society, 2012, 159(9): 549-554.
[13].TORABINEJAD V, ALIOFKHAZRAEI M, ASSAREH S, et al. Electrodeposition of Ni-Fe alloys, composites, and nano coatings-A review[J]. Journal of Alloys and Compounds, 2017, 691: 841-859.
[14].SONG C, DU L, JIA X. Reducing the residual stress in micro electroforming layer by megasonic agitation [J]. Ultrasonics Sonochemistry, 2018, 49: 233-240.
[15].GONG T, BAI X J, XIANG X Z, et al. Microstructure of ultrasonic-electrodepositing nano-silver coatings, Advanced Materials Research[J]. 2009, 79: 413-416.
[16].刘仁志. 实用电铸技术[M]. 北京: 化学工业出版社, 2006: 149-152.
[17].卢琳, 刘天成, 李鹏, 等. 电沉积因瓦合金镀层成分的影响因素[J]. 工程科学学报, 2008, 30(8): 903-907.
[18].SU C W, HE F J, JU H, et al. Electrodeposition of Ni, Fe and Ni-Fe alloys on a 316 stainless steel surface in a fluorborate bath[J]. Electrochimica Acta, 2009, 54(26): 6257-6263.
[19].FEI D, ZHANG C F, HU X G. Effects of ultrasound on lithium metal rechargeable battery characteristics at high charging rate[J]. Electrochemistry Communications, 2005, 7: 552-556.
[20].ZHONG Z, DU L Q, TAO Y S, et al. Enhancing the adhesion strength of micro electroforming layer by ultrasonic agitation method and the application[J]. Ultrasonics Sonochemistry, 2016, 33: 10-17.
[21].NATH P, SAHU D K, MALLIK A. Physicochemical and corrosion properties of sono-electrodeposited Cu-Ni thin films[J]. Surface and Coatings Technology, 2016, 307: 772-780.
[22].黄先杰. 玻碳电极表面因瓦合金的电化学成核机理[J]. 电化学, 2017, 23(1): 3429-3431.
[23].苏长伟. 铁镍合金箔的电化学制备及其结构性能研究[D]. 长沙: 湖南大学, 2011.
[24].HUANG X Q, CHEN Y, ZHOU J Q, et al. Electrochemical nucleation and growth of Sn onto double reduction steel substrate from a stannous fluoborate acid bath[J]. Journal of Electroanalytical Chemistry, 2013, 709: 83-92.

更新日期/Last Update: 2026-04-15