[1]李 呐,倪自飞,余育军,等.doi: 10.3969/j.issn.1001-3849.2026.04.012电镀钐工艺对铜基钢丝性能影响[J].电镀与精饰,2026,(04):76-82.
　LI Na,NI Zifei,YU Yujun,et al.Influence of electroplating samarium process on the properties of copper-based steel wires[J].Plating & Finishing,2026,(04):76-82.
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doi: 10.3969/j.issn.1001-3849.2026.04.012电镀钐工艺对铜基钢丝性能影响()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2026年04
页码:
76-82
栏目:
出版日期:
2026-04-30

文章信息/Info

Title:
Influence of electroplating samarium process on the properties of copper-based steel wires
作者:
李 呐1; 2; 倪自飞1; 2; 余育军1; 华 欣1; 2; 魏于博1; 2; 王创造1; 2; 刘湘慧1
(1. 江苏兴达钢帘线股份有限公司,江苏 泰州 225721 ;2. 江苏省结构与功能金属复合材料重点实验室;江苏 泰州 225721)
Author(s):
LI Na1; 2;  NI Zifei1; 2;  YU Yujun1;  HUA Xin1; 2;  WEI Yubo1; 2;  WANG Chuangzao1; 2;  LIU Xianghui1
(1. Jiangsu Xingda Steel Tyre Cord Co., Ltd., Taizhou 225721, China; 2. Jiangsu Key Laboratory for Structural and Functional Metal Materials Composites, Taizhou 225721, China)
关键词:
铜锌钢丝; 电镀钐; 盐酸体系; 耐蚀性
Keywords:
copper-zinc steel wire;  samarium electroplating;  hydrochloric acid system;  corrosion resistance
分类号:
TQ153.1
文献标志码:
A
摘要:
铜基钢丝与橡胶结合后的使用寿命与钢丝自身的耐蚀性相关。因此为提高铜基钢丝耐蚀性，本文分别考察硫酸和盐酸体系镀液在铜基钢丝上电沉积钐的性能。研究表明，硫酸体系镀液在电镀过程中对镀液pH的变化较为敏感，镀液稳定性欠佳，而盐酸体系镀液在铜基钢丝上电镀金属钐，可以明显观察到铜基钢丝表面沉积的金属钐层，镀液稳定性较好。故以盐酸体系镀液将少量钐引入铜锌镀层，并与现有铜锌钢丝进行各项性能比较，结果如下：钐加入使铜锌镀层的耐蚀性提高，填补了铜锌镀层的孔隙，使得镀层更为致密，并使溶铁量相对黄铜钢丝明显减少，再次证明了镀层致密性的提高，同时钐加入未改变铜锌钢丝物相组成，对钢丝进一步形变无影响。
Abstract:
The service life of copper-based steel wires after bonding with rubber was closely related to their corrosion resistance. Therefore, electrodeposition performance of metal Sm on copper-based steel wires was investigated in sulfuric acid and hydrochloric acid plating systems respectively, to improve the corrosion resistance. It was found that the sulfuric acid plating system exhibited sensitivity to the pH fluctuations of the plating solution during the electroplating process, resulting in poor stability of the plating solution. In contrast, during electroplating metal Sm on copper-based steel wires in the hydrochloric acid plating system, a Sm layer deposites on the surface of the copper-based steel wires could be clearly observed, with stable plating solution. Therefore, a small amount of Sm was introduced into the copper-zinc coating using the hydrochloric acid plating system, and compared with various properties of the existing copper-zinc steel wires. The results show that the addition of Sm improves the corrosion resistance of the copper-zinc coating, by filling the pores of the copper-zinc coating with compact structure. The amount of dissolved iron is significantly reduced compared with brass steel wires, further confirming the improved coating density. Meanwhile, the addition of Sm does not change the phase composition of copper-zinc steel wires and had no effect on the further deformation.

参考文献/References:

[1].GIRIDHAR J, VAN O W J. Study of Zn-Ni and Zn-Co alloy coatings electrodeposited on steel strips II: corrosion, dezincification and sulfidation of the alloy coatings[J]. Surface and Coatings Technology, 1992(53): 35-47.
[2].张正伟, 刘晓芳, 魏胜, 等. 4＋3×0.35 ST三相合金镀层钢丝帘线在全钢载重子午线轮胎带束层中的应用[J]. 轮胎工业, 2021, 41(9): 565-567.
[3].BUYTAERT G, LUO Y W. Study of Cu-Zn-Co ternary alloy-coated steel cord in cobalt-free skim compound[J]. Journal of Adhesion Science and Technology, 2014, 28(16): 1545-1555.
[4].TAO Y, WINDSLOW R, STEVENS C A, et al. Development of a novel fatigue test method for cord-rubber composites[J]. Polymer Testing, 2018, 71: 238-247.
[5].马海俊, 王宝星, 刘磊. 不同镀层钢丝帘线粘合力在相应粘合体系中的测试、表征和分析[J]. 轮胎工业, 2018, 38(2): 117-120.
[6].BUYTAERT G, WANG B X, LUO Y W. Superior adhesion of rubber and steel cord coated with Cu-Zn-Co ternary alloy[J]. Rubber World, 2015, 252(6): 20-24, 32.
[7].JEON G S, KANG U I, JEONG S W, et al. Adhesion between rubber compounds and ternary-alloy-coated steel cords. Part II: effects of sulfur and cobalt salt in rubber compounds[J]. Journal of Adhesion Science and Technology, 2005, 19(15): 1325-1348.
[8].廉成波, 马岩, 李京民, 等. 硫黄用量对橡胶/尼龙帘线动态粘合性能的影响[J]. 青岛科技大学学报, 2016, 37(5): 539-544.
[9].李利, 肖培光, 刘潇冬. 热老化和湿气老化对橡胶/钢丝帘线粘合性能的影响[J]. 特种橡胶制品, 2016, 37(5): 22-26.
[10].JEON G S. Adhesion between rubber compounds and ternary-alloy-coated steel cords, part I: effect of cobalt plating amount in ternary-alloy-coated steel cords[J]. Journal of Adhesion Science and Technology, 2005, 19(6): 445-465.
[11].李利, 刘潇冬, 肖培光, 等. 疲劳加载因素对橡胶钢丝复合体粘合性能的影响[J]. 功能材料, 2016, 47(12): 12206-12211.
[12].VANOOIJ W J, HARAKUNI P B, BUYTAERT G. Adhesion of steel tire cord to rubber[J]. Rubber Chemistry and Technology, 2009, 82(3): 315-339.
[13].田廓. 适用于轮胎帘线的新型NiZn/ZnCo镀层钢丝[J]. 湘钢译丛, 1993(4): 24-32.
[14].雍占福. 新型ZnMn镀层钢丝帘线[J]. 橡胶科技市场, 2006(20): 13-14.
[15].黄清安, 王银平, 吴俊. 稀土金属和合金电沉积的研究现状[J]. 材料保护, 2000, 33(1): 51-53.
[16].成旦红. 稀土元素在金属电沉积中的应用[J]. 电镀与涂饰, 1995, 14(1): 40-47.
[17].朱明华, 李立青. 稀土添加剂在金属电沉积中的应用研究进展[J]. 电镀与涂饰, 2006, 25(6): 46-48, 53.
[18].RUIZ E J, ORTEGA B R, GODLNEZ L A, et al. Mechanism of the electrochemical deposition of samarium-based coatings[J]. Electrochimica Acta, 2006(52): 914-920.
[19].王玲玲, 唐黎明, 彭军, 等. 水溶液中电沉积稀土合金的研究现状[J]. 材料保护, 2004, 37(6): 30-33.
[20].徐仰涛, 裴亮, 杨斌, 等. Ce2(SO4)3对铜电沉积层晶粒细化的作用研究[J]. 中国稀土学报, 2023, 41(5): 956-965.
[21].龚晓钟, 汤皎宁, 张晓萃. 单一稀土镧在不同基底上的电沉积及其性能的研究[J]. 广州化学, 2008, 33(3): 1-7, 22.
[22].彭军, 王玲玲, 唐黎明, 等. 水溶液中电沉积非晶态稀土合金的研究进展[J]. 稀有金属, 2004, 28(1): 252-256.

更新日期/Last Update: 2026-04-15