LV Chunlei*,RUI Can,TENG Wei.Studies on Production of Copper Plate Electroplating for Continuous Casting Mould[J].Plating & Finishing,2022,(2):66-70.[doi:10.3969/j.issn.1001-3849.2022.02.014]
连铸结晶器铜板电镀生产研究
- Title:
- Studies on Production of Copper Plate Electroplating for Continuous Casting Mould
- 分类号:
- TQ153.1
- 文献标志码:
- A
- 摘要:
- 结晶器铜板作为连铸设备的关键备件,在使用过程中会出现热裂纹、磨损、腐蚀等问题,因此结晶器铜板需通过表面处理以提高其耐高温、耐磨损、耐腐蚀性能。本文结合其主要失效形式总结论述了连铸结晶器铜板近几年的电镀技术生产实践,主要包括电镀前处理技术、电镀非均一性镍硼合金和电镀镍基陶瓷复合镀技术生产实践。电解刻蚀前处理技术能有效提高铜板表面粗糙度并进一步提高镀层与基体的结合强度,镍硼合金生产实践表明通过控制合适的工艺能够制造出硬度梯度较大的镀层,复合镀生产实践表明能够在铜板表面制造出镍基复合镀层,但陶瓷颗粒的加入对电镀设备连续性有一定影响。
- Abstract:
- As a key spare part of continuous casting equipment , the mold copper plate will appear hot crack , wear , corrosion and other problems in the use process , so the mold copper plate needs surface treatment to improve its high temperature resistance , wear resistance and corrosion resistance. In this paper , the production practices of electroplating technology for copper plate of continuous casting mould in recent years were summarized and discussed combined with the main failure modes , including electroplating pretreatment technology , electroplating non-uniform Ni-B alloy and electroplating nickel-based ceramic composite plating technology. Electrolytic etching pretreatment technology could effectively improve the surface roughness of copper plate and further improved the bonding strength between the coatings and substrates. The production practice of Ni-B alloy showed that the coating with larger hardness gradient could be produced by controlling the appropriate process. The production practice of composite plating showed that nickel-based composite coatings could be produced on the surface of copper plate , but the addition of ceramic particles had a certain impact on the continuity of electroplating equipment.
参考文献/References:
[1] 吕春雷 , 夏鹏 , 高茜 , 等 . 连铸结晶器铜板表面镀层失效分析 [J]. 复旦学报 ( 自然科学版 ), 2016, (2): 205-210.
Lv C L, Xia P, Gao Q, et al. Failure analysis of the coating on continuous casting mold [J]. Journal of Fudan University (Natural Science), 2016, (2): 205-210 (in Chinese).
[2] 侯峰岩 , 吕春雷 . 连铸结晶器铜板表面处理关键技术的研究与应用 [J]. 表面技术 , 2012, (4): 63-65.
Hou F Y, Lv C L Research and application of key technologies of continuous casting mould surface treatment[J]. Surface Technology, 2012, (4): 63-65 (in Chinese).
[3] 侯峰岩 , 任乔华 , 高锦岩 . 连铸关键设备再制造技术及应用 [J]. 中国表面工程 , 2012, (4): 31-35.
Hou F Y, Ren Q H, Gao J Y. Remanufacturing technology in continuous casting core equipment and its application [J]. China Surface Engineering, 2012, (4): 31-35 (in Chinese).
[4] 刘健健 , 朱诚意 , 李光强 . 连铸结晶器铜板表面涂镀层应用研究进展 [J]. 材料导报 , 2019, (17): 2831-2838.
Liu J J, Zhu C Y, Li G Q. Application research progress of coatings on copper plate in continuous casting mould [J]. Materials Reports, 2019, (17): 2831-2838 (in Chinese).
[5] 赵涛 , 张庆莹 , 徐立 , 等 . 结晶器用铜板强化技术的研究进展 [J]. 工业加热 , 2014, (3): 26-29.
Zhao T, Zhang Q Y, Xu L, et al. Research progress on strengthen technology of the mould copper plate [J]. Industrial Heating, 2014, (3): 26-29 (in Chinese).
[6] 耿哲 , 刘阳 , 张宏杰 , 等 . 结晶器铜板 Ni-Co 电镀层的耐磨性 [J]. 中国表面工程 , 2013, (6): 93-99.
Geng Z, Liu Y, Zhang H J, et al. Wear resistance of Ni-Co electrodeposited coatings on copperplate of crystallizer [J]. China Surface Engineering, 2013, (6): 93-99 (in Chinese).
[7] 侯峰岩 , 路庆华 , 谭兴海 , 等 . Co-Ni 合金镀层组织结构及性能研究 [J]. 材料热处理学报 , 2007, (1): 123-126.
Hou F Y, Lu Q H, Tan X H, et al. Study on structure and properties of electrodeposited Co-Ni alloy deposits [J]. Transactions of Materials and Heat Treatment, 2007, (1): 123-126 (in Chinese).
[8] 白林 , 陈登福 , 刘鹏 , 等 . 结晶器铜板表面耐磨纳米复合镀层的制备及性能 [J]. 表面技术 , 2017, (7):7-12.
Bai L, Chen D F, Liu P, et al. Preparation of wear resistant nano composite coating on surface of copper crystallizer [J]. Surface Technology, 2017, (7): 7-12 (in Chinese).
[9] 郭鹤桐 , 张三元 . 复合电镀技术 [M]. 北京 : 化学工业出版社 , 2007.
[10] 吕春雷 , 侯峰岩 , 黄丽 . 结晶器铜板表面复合镀层的制备方法 [P]. 中国专利 : 201110285172.4, 2011-09-23.
相似文献/References:
[1]吕春雷*,芮灿.电镀技术在机械备件修复中的生产应用[J].电镀与精饰,2023,(4):106.[doi:10.3969/j.issn.1001-3849.2023.04.017]
Lyu Chunlei*,Rui Can.Application of electroplating technology in the repair of mechanical spare parts[J].Plating & Finishing,2023,(2):106.[doi:10.3969/j.issn.1001-3849.2023.04.017]
备注/Memo
收稿日期: 2021-02-28 修回日期: 2021-05-23 作者简介: 吕春雷( 1983 —),男,硕士,工程师,主要研究方向:冶金机械备件修复, email : 7408348@163.com