[1]胡佳斌*,白 旺.doi: 10.3969/j.issn.1001-3849.2025.09.014PVD技术在聚合物产品表面装饰镀层中的应用研究[J].电镀与精饰,2025,(09):97-105.
　Hu Jiabin*,Bai Wang.Research on the application of PVD technology in decorative coatings on polymer products[J].Plating & Finishing,2025,(09):97-105.
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doi: 10.3969/j.issn.1001-3849.2025.09.014PVD技术在聚合物产品表面装饰镀层中的应用研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年09
页码:
97-105
栏目:
出版日期:
2025-09-30

文章信息/Info

Title:
Research on the application of PVD technology in decorative coatings on polymer products
作者:
胡佳斌*; 白 旺
(华北科技学院 艺术设计学院,河北 廊坊 065201)
Author(s):
Hu Jiabin*;  Bai Wang
(School of Art and Design, North China Institute of Science and Technology, Langfang 065201, China)
关键词:
物理气相沉积; 聚合物; 金属化; 表面精饰; 装饰镀层
Keywords:
physical vapor deposition;  polymers;  metallization;  surface finishing;  decorative coatings
分类号:
TB43
文献标志码:
A
摘要:
聚合物材料在日用消费品中应用广泛，为满足装饰性需求，采用物理气相沉积(PVD)技术对其进行表面金属化是一种兼具环保与较高性价比的方式。然而，聚合物表面PVD镀层存在结合力差、色彩调控困难等问题。本文综述了PVD技术在聚合物表面装饰镀层中的研究进展，重点探讨了增强镀层结合力的方法及镀层色彩、质感的调控策略。磁控溅射及其改进工艺是聚合物表面镀层制备的常用方法；通过对基材进行表面活化、表面粗化、中间层制备等方式，可显著提高镀层结合力；调整靶材金属、沉积气氛及工艺参数，可制备不同色彩与质感的镀层。然而，镀层色彩形成机理、特定颜色与装饰效果的制备工艺仍有待深入研究。本综述为聚合物产品表面装饰的理论研究与工程实践提供了参考。
Abstract:
Polymer materials are widely used in daily consumer products. To meet decorative demands, metallizing their surfaces using physical vapor deposition (PVD) technology is an environmentally friendly and cost-effective method. However, PVD coatings on polymer surfaces often face issues such as poor adhesion and difficulty in color control. This paper focuses on the application of PVD technology in decorative coatings on polymer surfaces, reviewing methods to enhance coating adhesion and strategies to improve decorative effects such as color and texture. It has been found that magnetron sputtering and its improved processes are commonly used methods for preparing polymer surface coatings. Coating adhesion can be significantly improved through techniques such as surface activation, surface roughening, and the use of intermediate layers. Adjusting the target metal, controlling the deposition atmosphere, and optimizing process conditions, different colors and textures of coatings can be prepared. However, the mechanisms of color formation and the preparation processes for specific decorative effects still require further study. This review provides a reference for both theoretical research and engineering practice in the surface decoration of polymer products

参考文献/References:

[1].Melentiev R, Yudhanto A, Tao R, et al. Metallization of polymers and composites: State-of-the-art approaches[J]. Materials & Design, 2022, 221: 110958.
[2].Wang S, Ma C, Walsh F C. Alternative tribological coatings to electrodeposited hard chromium: a critical review[J]. Transactions of the IMF, 2020, 98(4): 173-185.
[3].Vorobyova M, Biffoli F, Giurlani W, et al. PVD for decorative applications: a review[J]. Materials, 2023, 16(14): 4919.
[4].Olivera S, Muralidhara H B, Venkatesh K, et al. Plating on acrylonitrile-butadiene-styrene (ABS) plastic: a review[J]. Journal of Materials Science, 2016, 51(8): 3657-3674.
[5].Kumar V, Dwivedi S K. Toxicity potential of electroplating wastewater and its bioremediation approaches: a review[J]. Environmental Technology Reviews, 2021, 10(1): 238-254.
[6].Kamar M T, Elattar H, Mahmoud A S, et al. A critical review of state-of-the-art technologies for electroplating wastewater treatment[J]. International Journal of Environmental Analytical Chemistry, 2024, 104(16): 4143-4176.
[7].Protsenko V S. Kinetics and mechanism of electrochemical reactions occurring during the chromium electrodeposition from electrolytes based on Cr(III) compounds: a literature review[J]. Reactions, 2023, 4(3): 398-419.
[8].Arenas M A, Conde A, Garcia I, et al. PVD hard coatings on ceramic tiles for aesthetic applications: surface characterisation and corrosion properties[J]. Ceramics International, 2022, 48(15): 21794-21802.
[9].Pinheiro X L, Oliveira K, Santos J, et al. The combination of electrodeposited chromium (III) and PVD as an industrial viable solution for the replacement of electrodeposited chromium (VI)[J]. Process Safety and Environmental Protection, 2024, 182: 727-739.
[10].李晓刚, 黎子辉, 叶俊文. 基于文献数据可视化的真空镀膜技术研究与应用分析[J]. 真空科学与技术学报, 2022, 42(11): 863-875.
[11].刘帮毅, 孙力, 苏英霞, 等. 物理气相沉积用于汽车外饰件的可行性分析[J]. 电镀与涂饰, 2022, 41(14): 1038-1042.
[12].赵卫民, 王淼, 朱燕峰. 固态电池石榴石电解质与锂金属界面改善的综述[J]. 电池, 2024, 54(4): 574-577.
[13].何亮, 王祥宇, 田浩生, 等. 多种方法制备SiO2薄膜及其性能研究[J]. 材料导报, 2024, 38 (S1): 46-49.
[14].付保英. 磁控溅射CrSiN涂层及其摩擦磨损性能研究[J]. 电镀与精饰, 2022, 44(7): 36-41.
[15].Marchiori G, Gambardella A, Berni M, et al. Impact of surface functionalization by nanostructured silver thin films on thermoplastic central venous catheters: mechanical, microscopical and thermal analyses[J]. Coatings, 2020, 10(11): 1034.
[16].Zhang D, Zuo X, Wang Z, et al. Comparative study on protective properties of CrN coatings on the ABS substrate by DCMS and HiPIMS techniques[J]. Surface and Coatings Technology, 2020, 394: 125890.
[17].Hein? J-P, Fietzke F. High-rate deposition of thick aluminum coatings on plastic parts for electromagnetic shielding[J]. Surface and Coatings Technology, 2020, 385: 125134.
[18].Ferreira A A, Silva F J G, Pinto A G, et al. Characterization of thin chromium coatings produced by PVD sputtering for optical applications[J]. Coatings, 2021, 11(2): 215.
[19].Carneiro E, Parreira N M G, Vuchkov T, et al. Cr-based sputtered decorative coatings for automotive industry[J]. Materials, 2021, 14(19): 5527.
[20].Baptista A, Pinto G, Silva F J G, et al. Wear characterization of chromium PVD coatings on polymeric substrate for automotive optical components[J]. Coatings, 2021, 11(5): 555.
[21].Polanec B, Zupanic F, Boncina T, et al. Experimental investigation of the wear behaviour of coated polymer gears[J]. Polymers, 2021, 13: 203588.
[22].张亚东, 黄海波, 黄飞洪, 等. ABS基材表面功能装饰CrCu涂层制备及性能研究[J]. 真空科学与技术学报, 2022, 42(5): 371-378.
[23].Boncina T, Polanec B, Zupanic F, et al. Wear behaviour of multilayer Al-PVD-coated polymer gears[J]. Polymers, 2022, 14: 214751.
[24].Romani A, Tralli P, Levi M, et al. Metallization of recycled glass fiber-reinforced polymers processed by UV-assisted 3D printing[J]. Materials, 2022, 15: 186242.
[25].Toroslu A G, Tekiner Z, Mert F. Characterization of physical vapor deposited coating on acrylonitrile-butadiene-styrene and polycarbonate substrates[J]. Materialwissenschaft Und Werkstofftechnik, 2022, 53(8): 867-875.
[26].Joanna Kacprzyńska-Go?acka, Monika ?o?yńska, Wioletta Barszcz, et al. Microfiltration membranes modified with zinc by plasma treatment[J]. Membranes, 2023, 13(4): 387.
[27].Ponte F, Sharma P, Figueiredo N M, et al. Decorative chromium coatings on polycarbonate substrate for the automotive industry[J]. Materials, 2023, 16(6): 2315.
[28].Sharma P, Ponte F, Lima M J, et al. Plasma etching of polycarbonate surfaces for improved adhesion of Cr coatings[J]. Applied Surface Science, 2023, 637: 157903.
[29].Alfath S A, Ponte F, Sharma P, et al. PVD decorative coatings on polycarbonate and polyamide substrates for the automotive industry[J]. Surfaces and Interfaces, 2024, 52: 104887.
[30].Fumagalli N, Sanchez J C D H, Bianchi C L, et al. Metallization of polypropylene substrates through surface functionalization and physical vapor deposition of chromium coatings[J]. Surface & Coatings Technology, 2024, 484: 130880.
[31].Zhang C, Bai Y P, Liu W W. The approaches for promoting PP adhesion based on the surface modification[J]. Journal of Adhesion Science and Technology, 2014, 28(5): 454-465.
[32].Arias N, Jaramillo F. Highly reflective aluminum films on polycarbonate substrates by physical vapor deposition[J]. Applied Surface Science, 2019, 505: 144596.
[33].Liu J, He L, Wang L, et al. Significant enhancement of the adhesion between metal films and polymer substrates by UV-ozone surface modification in nanoscale[J]. ACS Applied Materials & Interfaces, 2016, 8(44): 30576-30582.
[34].李林蔚. 聚合物表面化学改性与金属化的界面结合性能研究[D]. 广州: 华南理工大学, 2023.
[35].李志杰, 裴淏, 甘全全,等. 双极板表面润湿性能的研究进展[J]. 电池, 2024, 54(3): 402-407.
[36].Seo J S, Jeon H T, Han T H. Peeling mechanism of interlocked interface between etched acrylonitrile-butadiene-styrene and electroplated metal layer[J]. Surfaces and interfaces, 2021, 26: 101337.
[37].Lambaré C, Tessier P Y, Poncin-Epaillard F, et al. Plasma functionalization and etching for enhancing metal adhesion onto polymeric substrates[J]. Rsc Advances, 2015, 5(77): 62348-62357.
[38].Wang E, Wang S, Wang F, et al. Adhesion improvement of sputtered Cu films on flexible polymer substrates through the design of metal interlayers[J]. Physica Scripta, 2024, 99(7): 075926.
[39].Bulut Y, Sochor B, Reck K A, et al. Investigating gold deposition with high-power impulse magnetron sputtering and direct-current magnetron sputtering on polystyrene, poly-4-vinylpyridine, and polystyrene sulfonic acid[J]. Langmuir, 2024, 40(43): 22591-22601.
[40].曹一鸣, 潘俊锋, 黄沛. 磁控溅射工艺对金属镀膜塑料结合力影响的研究[J]. 机电工程技术, 2017, 46(7): 13-15.
[41].Paulo P, Rodrigues M S, Neto M A, et al. Properties of CrN thin films deposited in plasma activated ABS by reactive magnetron sputtering[J]. Surface & Coatings Technology, 2018, 349: 858-866.
[42].Chodun R, Skowronski L, Okrasa S, et al. Optical TiO2 layers deposited on polymer substrates by the Gas Injection Magnetron Sputtering technique[J]. Applied Surface Science, 2019, 466: 12-18.
[43].Liu J S, He L F, Xu Z, et al. Defect generation mechanism in magnetron sputtered metal films on PMMA substrates[J]. Journal of Materials Science-Materials in Electronics, 2019, 30(16): 14847-14854.
[44].Cuppo F L S, García-Valenzuela A, Olivares J A. Influence of surface roughness on the diffuse to near-normal viewing reflectance factor of coatings and its consequences on color measurements[J]. Color Research and Application, 2013, 38(3): 177-187.
[45].孔晶, 费玉清, 陈正件, 等. 磁控溅射TiN/Au-Cu复合薄膜的性能及其变色机理研究[J]. 电镀与涂饰, 2021, 40(23): 1781-1785.
[46].Mousavi S E, Naghshehkesh N, Amirnejad M, et al. Corrosion performance and tribological behavior of diamond-like carbon based coating applied on Ni-Al-bronze alloy[J]. Transactions of Nonferrous Metals Society of China, 2021, 31(2): 499-511.
[47].田文燕, 胡洪瑞, 刘富亮,等. 干法制备LiCoO2电极的电化学性能[J]. 电池, 2024, 54(5): 677-681.
[48].Martinho R P, Andrade M F C, Silva F J G, et al. Micro-abrasion wear behaviour of TiAlCrSiN nanostructured coatings[J]. Wear, 2009, 267(5): 1160-1165.
[49].Cai Z T, Chen Y K, Chen X Y, et al. Water vapor permeation in alumina films on polymer substrates[J]. Physica Status Solidi B-Basic Solid State Physics, 2024, 261(4): 2300454.

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更新日期/Last Update: 2025-09-11