[1]吴宜骏,王 翀,王 城,等.doi: 10.3969/j.issn.1001-3849.2026.06.001不溶性析氧阳极在电镀中的应用及研究进展[J].电镀与精饰,2026,(06):1-14.
 WANG Shouxu,LI Jiujuan,ZHOU Guoyun,et al.Application and progress of insoluble oxygen evolution anode in electroplating WU Yijun1, WANG Chong1, WANG Cheng2, XU Guoxing3, HONG Yan1,[J].Plating & Finishing,2026,(06):1-14.
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doi: 10.3969/j.issn.1001-3849.2026.06.001不溶性析氧阳极在电镀中的应用及研究进展()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2026年06
页码:
1-14
栏目:
出版日期:
2026-06-30

文章信息/Info

Title:
Application and progress of insoluble oxygen evolution anode in electroplating WU Yijun1, WANG Chong1, WANG Cheng2, XU Guoxing3, HONG Yan1,
作者:
吴宜骏1王 翀1王 城2徐国兴3洪 延1王守绪1李玖娟1周国云1何 为12
(1. 电子科技大学 材料与能源学院,四川 成都 61 1731;2. 西昌学院 理学院,四川 西昌 615000 ;3. 广东硕成科技股份有限公司,广东 韶关 51 2721)
Author(s):
WANG Shouxu1 LI Jiujuan1 ZHOU Guoyun1 HE Wei12
(1. School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China; 2. School of Science, Xichang University, Xichang 615000, China; 3. Guangdong Shuocheng Technology Co., Ltd., Shaoguan 512 721, China)
关键词:
Ti基底电化学析氧反应电化学催化剂复合材料
Keywords:
Ti substrate oxygen evolution reaction electrochemical catalysts composite materials
分类号:
TQ153.2;TG178
文献标志码:
A
摘要:
电镀生产使用金属钛(Ti)基底的不溶性析氧阳极,电镀质量稳定、副产物少,在电子电镀等领域具有显著优势。若进一步降低成本和能耗,将为电镀行业带来深远变革。本文首先阐述了不溶性析氧阳极的主要技术指标及其评价方法,随后从对电化学析氧机制的理论研究中总结出提高此类阳极性能的两大关键研究方向:催化剂涂层的配方设计以及涂层与钛基底的固着技术。析氧阳极催化剂的研究经历了从贵金属(如Ru、Ir等)向贱金属化合物、贱金属合金、非金属化合物以及碳材料等多样化廉价催化剂的扩展。新型催化剂不仅能够降低成本,还能提高催化性能和稳定性。在涂层制备技术方面,介绍了电镀、热分解、溶胶凝胶、磁控溅射等先进纳米和薄膜制备技术,使得涂层与钛基底的结合更加牢固,提高了涂层的稳定性和使用寿命。不溶性析氧阳极在铜、铬、锌电镀以及复杂废水处理中的应用日益成熟,未来,不溶性析氧阳极的研究与发展将继续聚焦于优化催化剂性能、提升涂层稳定性以及探索更多创新应用领域。
Abstract:
In the field of electroplating, insoluble oxygen evolution anodes based on titanium (Ti) have been widely applied in various industries, including electronic plating, due to their stability in electroplating performance and minimal byproduct generation. If the cost and energy consumption of these anodes can be further reduced, this technology has the potential to bring transformative advancements to the electroplating industry. The article begins by detailing the key technical indicators and evaluation methods of insoluble oxygen evolution anodes, laying a theoretical foundation for further in-depth research. Building on this, it summarizes the theoretical studies on the mechanisms of electrochemical oxygen evolution and identifies two critical research directions for improving anode performance: the formulation of catalytic coatings and the efficient bonding techniques between the coating and the titanium substrate. In terms of catalytic coatings, the development of oxygen evolution catalysts has progressed from noble metals (e.g., Ru, Ir) to more cost-effective alternatives, including base metal compounds, base metal alloys, non-metal compounds, and carbon-based materials. These novel catalysts not only reduce costs but also enhance catalytic performance and stability. Concurrently, advancements in coating preparation technologies-such as electroplating, thermal decomposition, sol-gel techniques, and magnetron sputtering-have been widely adopted. These technologies enable stronger adhesion between the coating and the titanium substrate, thereby improving the stability and lifespan of the coatings. The application of DSA in copper, chromium, and zinc electroplating, as well as in complex wastewater treatment, has become increasingly mature, looking ahead, as industrial demand for efficiency, environmental sustainability, and resource conservation continues to grow, the research and development of dimensionally stable anodes (DSA) will remain focused on optimizing catalytic performance, enhancing coating stability, and exploring innovative application areas.

参考文献/References:

[1].李赟, 孟艳花. 电池储能系统和功率调节技术研究进展[J]. 电池, 2024, 54(6): 883-888.
[2].王海波, 林虹, 宋文龙, 等. 2024年上半年中国电池行业运行情况[J]. 电池, 2024, 54(4): 445-449.
[3].贝哲斯咨询. 全球及中国电镀行业需求与市场前景分析[R]. 贝哲斯咨询, 2023.
[4].LI S, LI E, AN X, et al. Transition metal-based catalysts for electrochemical water splitting at high current density: current status and perspectives[J]. Nanoscale, 2021, 13(30): 12788-12817.
[5].BEER H B. The invention and industrial development of metal anodes[J]. Journal of the Electrochemical Society, 2019, 127(8): 303C-307C.
[6].王立璇. DSA电极的应用研究进展[J]. 技术创新, 2016(11): 163-164.
[7].张兰馨, 王鸿辉, 张小蝶, 等. 改性DSA电极的研究进展[J]. 能源与环境, 2024(3): 114-116.
[8].GUENEAU D E MUSSY J P, MACPHERSON J V, Delplancke J L. Characterisation and behaviour of Ti/TiO 2/noble metal anodes[J]. Electrochimica Acta, 2003, 48(9): 1131-1141.
[9].王冰冰, 谢刚, 俞小花, 等. 析氧型贵金属涂层钛阳极的研究进展[J]. 有色金属科学与工程, 2021, 12(1): 1-7.
[10].张锦园, 张菁丽, 白忠波, 等. 电解铜箔用钛阳极涂层的研究现状[J]. 电镀与精饰, 2023, 45(12): 95-102.
[11].LIU S, TAN H, HUANG Y C, et al. Structurally-distorted RuIr-based nanoframes for long-duration oxygen evolution catalysis[J]. Advanced Materials, 2023, 35(42): e2305659.
[12].TRASATTI S. Electrocatalysis: understanding the success of DSA[J]. Electrochimica Acta, 2000, 45(15-16): 2377-2385.
[13].LI Y, SUN Y, QIN Y, et al. Recent advances on water‐splitting electrocatalysis mediated by noble‐metal‐based nanostructured materials[J]. Advanced Energy Materials, 2020, 10(11): 1903120.
[14].MEFFORD J T, AKBASHEV A R, Kang M, et al. Correlative operando microscopy of oxygen evolution electrocatalysts[J]. Nature, 2021, 593(7857): 67-73.
[15].LI J. Oxygen evolution reaction in energy conversion and storage: design strategies under and beyond the energy scaling relationship[J]. Nano-Micro Letters, 2022, 14(1): 112.
[16].GUO T, LI L, WANG Z. Recent development and future perspectives of amorphous transition metal‐based electrocatalysts for oxygen evolution reaction[J]. Advanced Energy Materials, 2022, 12(24): 2200827.
[17].MAN I C, SU H Y, CALLE‐VALLEJO F, et al. Universality in oxygen evolution electrocatalysis on oxide surfaces[J]. ChemCatChem, 2011, 3(7): 1159-1165.
[18].AN L, WEI C, LU M, et al. Recent development of oxygen evolution electrocatalysts in acidic environment[J]. Advanced Materials, 2021, 33(20): e2006328.
[19].ROSSMEISL J, QU Z W, ZHU H, et al. Electrolysis of water on oxide surfaces[J]. Journal of Electroanalytical Chemistry, 2007, 607(1-2): 83-89.
[20].SONG J, WEI C, HUANG Z F, et al. A review on fundamentals for designing oxygen evolution electrocatalysts[J]. Chemical Society Reviews, 2020, 49(7): 2196-2214.
[21].GRIMAUD A, DIAZ-MORALES O, HAN B, et al. Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution[J]. Nature Chemistry, 2017, 9(5): 457-465.
[22].RONG X, PAROLIN J, KOLPAK A M. A fundamental relationship between reaction mechanism and stability in metal oxide catalysts for oxygen evolution[J]. ACS Catalysis, 2016, 6(2): 1153-1158.
[23].YOO J S, RONG X, LIU Y, et al. Role of lattice oxygen participation in understanding trends in the oxygen evolution reaction on perovskites[J]. ACS Catalysis, 2018, 8(5): 4628-4636.
[24].KUZNETSOV D A, NAEEM M A, KUMAR P V, et al. Tailoring lattice oxygen binding in ruthenium pyrochlores to enhance oxygen evolution activity[J]. Journal of the American Chemical Society, 2020, 142(17): 7883-7888.
[25].WEN Y, CHEN P, WANG L, et al. Stabilizing highly active Ru sites by suppressing lattice oxygen participation in acidic water oxidation[J]. Journal of the American Chemical Society, 2021, 143(17): 6482-6490.
[26].BAO X, LIU C, ZHANG Y, et al. Preparation of insoluble Ti/IrO2/MoS2 anodes by electrodeposition and its application in electrolytic copper foil[J]. Journal of Applied Electrochemistry, 2024, 54(9): 2051-2061.
[27].COMNINELLIS C, VERCESI G. Characterization of DSA?-type oxygen evolving electrodes: choice of a coating[J]. Journal of Applied Electrochemistry, 1991, 21(4): 335-345.
[28].XIN Y. Graphene-modified IrO2-Ta2O5 coated titanium anodes for the application of impressed current cathodic protection[J]. International Journal of Electrochemical Science, 2021, 16(10): 211056.
[29].SALVERDA A, DONDAPATI J S, THIRUPPATHI A R, et al. Effect of reduced graphene oxide on the Ta2O5-IrO2 electrocatalyst for water splitting[J]. Journal of the Electrochemical Society, 2020, 167(14): 146506.
[30].XU H, YUAN J, HE G, et al. Current and future trends for spinel-type electrocatalysts in electrocatalytic oxygen evolution reaction[J]. Coordination Chemistry Reviews, 2023, 475: 214869.
[31].WANG Y, ZHU Y Q, XIE Z, et al. Efficient electrocatalytic oxidation of glycerol via promoted OH* generation over single-atom-bismuth-doped spinel Co3O4[J]. ACS Catalysis, 2022, 12(19): 12432-12443.
[32].TAO G, WANG Z, LIU X, et al. Enhanced acidic oxygen evolution reaction performance by anchoring iridium oxide nanoparticles on Co3O4[J]. ACS Applied Materials & Interfaces, 2025, 17(1): 1350-1360.
[33].GUO M, LIU Y, XIN Y, et al. Performance enhancement of Ti/IrO2-Ta2O5 anode through introduction of tantalum-titanium interlayer via double-glow plasma surface alloying technology[J]. Nanomaterials, 2024, 14(14): 1219.
[34].FAN Y, CHENG X. Porous IrO2-Ta2O5 coating modified with carbon nanotubes for oxygen evolution reaction[J]. Journal of the Electrochemical Society, 2016, 163(8): E209-E215.
[35].QIN J, LI J, LIU F, et al. Improving the electrochemical stability of TiMn2 middle-layer for oxygen evolution anode in sulfuric acid solution by high-temperature nitriding[J]. Advanced Sustainable Systems, 2024, 8(10): 2400061.
[36].FORTI J C, DE ANDRADE A R. Formaldehyde oxidation on a DSA-type electrode modified by Pt or PbO2 electrodeposition[J]. Journal of the Electrochemical Society, 2007, 154(1): E19.
[37].TAMILARASI B, JITHUL K P, PANDEY J. Non-noble metal-based electro-catalyst for the oxygen evolution reaction (OER): Towards an active & stable electro-catalyst for PEM water electrolysis[J]. International Journal of Hydrogen Energy, 2024, 58: 556-582.
[38].WU Z P, LU X F, ZANG S Q, et al. Non‐noble‐metal‐based electrocatalysts toward the oxygen evolution reaction[J]. Advanced Functional Materials, 2020, 30(15): 1910274.
[39].LI A, SUN Y, YAO T, et al. Earth-abundant transition-metal-based electrocatalysts for water electrolysis to produce renewable hydrogen[J]. Chemistry, 2018, 24(69): 18334-18355.
[40].LI L, CAO X, HUO J, et al. High valence metals engineering strategies of Fe/Co/Ni-based catalysts for boosted OER electrocatalysis[J]. Journal of Energy Chemistry, 2023, 76: 195-213.
[41].AL-NAGGAR A H, SHINDE N M, KIM J-S, et al. Water splitting performance of metal and non-metal-doped transition metal oxide electrocatalysts[J]. Coordination Chemistry Reviews, 2023, 474: 214864.
[42].ZHANG R, PAN L, GUO B, et al. Tracking the role of defect types in Co3O4 structural evolution and active motifs during oxygen evolution reaction[J]. Journal of the American Chemical Society, 2023, 145(4): 2271-2281.
[43].YAN K L, QIN J F, LIN J H, et al. Probing the active sites of Co3O4 for the acidic oxygen evolution reaction by modulating the Co 2+/Co3+ ratio[J]. Journal of Materials Chemistry A, 2018, 6(14): 5678-5686.
[44].ZHAO W, XU F, YANG J, et al. Ce single-atom incorporation enhances the oxygen evolution reaction of Co3O4 in acid[J]. Inorganic Chemistry, 2024, 63(4): 1947-1953.
[45].LI Y, WU Z S, LU P, et al. High‐valence nickel single‐atom catalysts coordinated to oxygen sites for extraordinarily activating oxygen evolution reaction[J]. Advanced Science, 2020, 7(5): 1903089.
[46].FAN L, ZHANG B, TIMMER B J J, et al. Promoting the Fe(VI) active species generation by structural and electronic modulation of efficient iron oxide based water oxidation catalyst without Ni or Co[J]. Nano Energy, 2020, 72: 104656.
[47].BAI X, WANG L, NAN B, et al. Atomic manganese coordinated to nitrogen and sulfur for oxygen evolution[J]. Nano Research, 2022, 15(7): 6019-6025.
[48].GAO J, TAO H, LIU B. Progress of nonprecious-metal-based electrocatalysts for oxygen evolution in acidic media[J]. Advanced Materials, 2021, 33(31): e2003786.
[49].ZHANG Y, CHEN B, QIAO Y, et al. FeNi alloys incorporated N-doped carbon nanotubes as efficient bifunctional electrocatalyst with phase-dependent activity for oxygen and hydrogen evolution reactions[J]. Journal of Materials Science & Technology, 2024, 201: 157-165.
[50].CHEN C, SUN M, ZHANG F, et al. Adjacent Fe Site boosts electrocatalytic oxygen evolution at Co site in single-atom-catalyst through a dual-metal-site design[J]. Energy & Environmental Science, 2023, 16(4): 1685-1696.
[51].WANG J, KONG H, ZHANG J, et al. Carbon-based electrocatalysts for sustainable energy applications[J]. Progress in Materials Science, 2021, 116: 100717.
[52].CHEN S, DUAN J, JARONIEC M, et al. Nitrogen and oxygen dual-doped carbon hydrogel film as a substrate-free electrode for highly efficient oxygen evolution reaction[J]. Advanced Materials, 2014, 26(18): 2925-2930.
[53].LIU Y, ZHOU L, LIU S, et al. Fe, N-inducing interfacial electron redistribution in NiCo spinel on biomass-derived carbon for bi-functional oxygen conversion[J]. Angewandte Chemie International Edition in English, 2024, 63(16): e202319983.
[54].ZHANG H, MAIJENBURG A W, LI X, et al. Bifunctional heterostructured transition metal phosphides for efficient electrochemical water splitting[J]. Advanced Functional Materials, 2020, 30(34): 2003261.
[55].PENG L, SHAH S S A, WEI Z. Recent developments in metal phosphide and sulfide electrocatalysts for oxygen evolution reaction[J]. Chinese Journal of Catalysis, 2018, 39(10): 1575-1593.
[56].ANANTHARAJ S, NODA S. Nickel selenides as pre-catalysts for electrochemical oxygen evolution reaction: A review[J]. International Journal of Hydrogen Energy, 2020, 45(32): 15763-15784.
[57].NGUYEN T X, SU Y H, LIN C C, et al. Self‐reconstruction of sulfate‐containing high entropy sulfide for exceptionally high‐performance oxygen evolution reaction electrocatalyst[J]. Advanced Functional Materials, 2021, 31(48): 2106229.
[58].LIU M, LI J. Cobalt phosphide hollow polyhedron as efficient bifunctional electrocatalysts for the evolution reaction of hydrogen and oxygen[J]. ACS Applied Materials & Interfaces, 2016, 8(3): 2158-2165.
[59].MAKGAE M E, KLINK M J, CROUCH A M. Performance of sol-gel titanium mixed metal oxide electrodes for electro-catalytic oxidation of phenol[J]. Applied Catalysis B: Environmental, 2008, 84(3-4): 659-666.
[60].HAN Z, ZHU P, XU L, et al. Electrochemical properties of the IrO2-Ta2O5 coated anodes with Al/Ti and Cu/Ti layered composites substrates[J]. Journal of Alloys and Compounds, 2018, 769: 210-217.
[61].HERRADA R A, ACOSTA-SANTOYO G, SEP?LVEDA-GUZM?N S, et al. IrO2-Ta2O5|Ti electrodes prepared by electrodeposition from different Ir:Ta ratios for the degradation of polycyclic aromatic hydrocarbons[J]. Electrochimica Acta, 2018, 263: 353-361.
[62].YAN Z, MENG H. Effect of different shapes of the titanium based IrO2-Ta2O5 coatings anode on electrochemical properties[J]. Rare Metal Materials and Engineering, 2012, 41(5): 772-775.
[63].HUANG C A, YANG S W, LAI P L. Effect of precursor baking on the electrochemical properties of IrO2-Ta2O5/Ti anodes[J]. Surface and Coatings Technology, 2018, 350: 896-903.
[64].HERRADA R A, MEDEL A, MANRIQUEZ F, et al. Preparation of IrO2-Ta2O5|Ti electrodes by immersion, painting and electrophoretic deposition for the electrochemical removal of hydrocarbons from water[J]. Journal of Hazardous Materials, 2016, 319: 102-110.
[65].XU L, XIN Y, WANG J. A comparative study on IrO2-Ta2O5 coated titanium electrodes prepared with different methods[J]. Electrochimica Acta, 2009, 54(6): 1820-1825.
[66].FATTAH-ALHOSSEINI A, ELMKHAH H, ANSARI G, et al. A comparison of electrochemical behavior of coated nanostructured Ta on Ti substrate with pure uncoated Ta in Ringer’s physiological solution[J]. Journal of Alloys and Compounds, 2018, 739: 918-925.
[67].ZHANG B, YANG F, LIU X, et al. Phosphorus doped nickel-molybdenum aerogel for efficient overall water splitting[J]. Applied Catalysis B: Environmental, 2021, 298: 120494.
[68].LENG J, WANG Z, WANG J, et al. Advances in nanostructures fabricated via spray pyrolysis and their applications in energy storage and conversion[J]. Chemical Society Reviews, 2019, 48(11): 3015-3072.
[69].CHEN S, HUANG H, JIANG P, et al. Mn-doped RuO2 nanocrystals as highly active electrocatalysts for enhanced oxygen evolution in acidic media[J]. ACS Catalysis, 2019, 10(2): 1152-1160.
[70].SUN P, QIAO Z, DONG X. Designing 3D transition metal cation-doped mRuOx asdurable acidic oxygen evolution electrocatalysts for PEM water electrolyzers[J]. Journal of the American Chemical Society, 2024, 146(22): 15515-15524.
[71].韩宁宁, 许壮, 何广利. 泡沫镍原位生长普鲁士蓝类似物构筑镍铁双金属氧化物催化剂的氧析出反应性能研究[J]. 低碳化学与化工, 2024, 49(5): 105-111.
[72].金荣涛. DSA在电解铜箔生产中的应用[J]. 有色冶炼, 1998(5): 27-28.
[73].MSINDO Z S, SIBANDA V, POTGIETER J H. Electrochemical and physical characterization of lead-based anodes in comparison to Ti-(70%) IrO2/(30%) Ta2O5 dimensionally stable anodes for use in copper electrowinning[J]. Journal of Applied Electrochemistry, 2009, 40(3): 691-699.
[74].SON S H, PARK S C, LEE M S. Enhancement of life time of the dimensionally stable anode for copper electroplating applications[J]. Archives of Metallurgy and Materials, 2017, 62(2): 1019-1022.
[75].宋琴, 武俊伟, 张辉, 等. 钛基DSA阳极在电镀铬工艺中的应用研究[J]. 中国腐蚀与防护学报, 2013, 33(6): 507-514.
[76].ZHANG W, HOULACHI G, HASKOURI S, et al. Study on electrochemical performance of dimensionally stable anodes during zinc electrowinning[J]. Archives of Metallurgy and Materials, 2023, 68: 1457-1466.
[77].ABDALRHMAN A S, GAMAL EL-DIN M. Degradation of organics in real oil sands process water by electro-oxidation using graphite and dimensionally stable anodes[J]. Chemical Engineering Journal, 2020, 389: 124406.
[78].JIN X, LIU M, LI S, et al. Novel use of the electrocatalytic oxidation process with Fe-DSA dual anode configuration for leachate treatment: significance of in situ ferrate generation[J]. Journal of Cleaner Production, 2024, 457: 142490.

备注/Memo

备注/Memo:
关键词:Ti基底;电化学析氧反应;电化学催化剂;复合材料
更新日期/Last Update: 2026-06-12