PDF下载 分享
[1]成张佳宁,黄坤坤.建筑铝合金表面制备耐久性超疏水阳极氧化膜[J].电镀与精饰,2022,(6):16-20.[doi:10.3969/j.issn.1001-3849.2022.06.004]
　CHENG Zhangjianing,HUANG Kunkun.Preparation of Durable Super-Hydrophobic Anodic Oxide Film on Aluminum Alloy for Construction[J].Plating & Finishing,2022,(6):16-20.[doi:10.3969/j.issn.1001-3849.2022.06.004]
点击复制

建筑铝合金表面制备耐久性超疏水阳极氧化膜

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG] 卷: 期数: 2022年6 页码: 16-20 栏目: 出版日期: 2022-06-15
Title:
Preparation of Durable Super-Hydrophobic Anodic Oxide Film on Aluminum Alloy for Construction
作者:
成张佳宁1; 2; 黄坤坤2
（1.同济大学 土木工程学院，上海 200092； 2.南通居者安建筑科学研究院有限公司，江苏 南通 226019）
Author(s):
CHENG Zhangjianing1; 2;  HUANG Kunkun2
( 1.College of Civil Engineering Tongji University，??hanghai 200092 China 2.Nantong Juzhean Architectural Research Institute Co. Ltd，??antong 226019 China )
关键词:
阳极氧化膜; 封孔处理; 表面修饰; 超疏水状态; 耐久性
Keywords:
anodic oxide film;  ?ealing treatment;  ?urface modification; super-hydrophobic;  state durable
分类号:
TQ153.6
DOI:
10.3969/j.issn.1001-3849.2022.06.004
文献标志码:
A
摘要:
采用阳极氧化工艺，并结合封孔处理和低表面能修饰，在建筑行业常用的 6463 铝合金表面制备出耐久性超疏水阳极氧化膜。表征了试样形貌、成分和表面接触角，并通过模拟实验测试了耐蚀性和耐久性。结果表明：经过阳极氧化、封孔处理和表面修饰后在铝合金试样表面形成微纳米分级结构的阳极氧化膜，主要含有 Al 、 O 、 S 、 C 和 Ti 元素，表面接触角达到 153.2 ° ，呈现超疏水状态。超疏水阳极氧化膜具有良好的结合力，在自然环境中能保持稳定的超疏水状态，耐久性良好，还具有良好的耐蚀性，可以有效抑制铝合金基体腐蚀。
Abstract:
： The durable super-hydrophobic anodic oxide film was prepared on the surface of 6463 aluminum alloy commonly used in the construction industry by anodic oxidation process combined with sealing treatment and low surface energy modification. The morphology ， components and surface contact angle of the samples were characterized ， and the corrosion resistance and durability were tested through simulation experiments. The results showed that after anodic oxidation ， sealing treatment and surface modification ， an anodic oxide film with micro-nano hierarchical structure was formed on the surface of aluminum alloy sample ， which mainly contained elements Al ， O ， S ， C and Ti ， and the surface contact angle reached 153.2 ° ， presenting a super-hydrophobic state. The super-hydrophobic anodic oxide film had good binding force and good durability ， it can maintain a stable super-hydropho bic state in the natural environment. And it also had good corrosion resistance ， which can effectively inhibit the corrosion of aluminum alloy matrix.

参考文献/References:



[1] 熊金平 , 赵艺阁 , 周勇 , 等 . 铝合金表面氧化膜去除方法研究进展 [J]. 电镀与精饰 , 2013, 35(11): 15-19.

[2] Zhang Y, Chen Y, Bian G, et al. Electrochemical behavior and corrosion mechanism of anodized 7B04 aluminum alloy in acid NaCl environments[J]. Journal of Alloys and Compounds, 2021(886): 161231.

[3] 李丽 , 马成骥 , 张京叶 . 铝合金表面化学转化技术的研究进展 [J]. 材料保护 , 2019, 52(1): 113-117.

[4] Zhang K, Yu S. Preparation of wear and corrosion resistant micro-arc oxidation coating on 7N01 aluminum alloy[J]. Surface and Coatings Technology, 2020(388): 125453.

[5] 商富强 , 黄丽清 , 李刚 , 等 . 超亲水和具有不同黏性的超疏水阳极氧化铝膜的制备 [J]. 材料导报 , 2020, 34(5): 10003-10007.

[6] Wu Y, Zhang C. Analysis of anti-condensation mechanism on superhydrophobic anodic aluminum oxide surface[J]. Applied Thermal Engineering, 2012, 58(1-2): 664-669.

[7] Wu R M, Liang S Q, Chen H, et al. Fabrication of a super-hydrophobic micro-nanoporous aluminum surface by anodic oxidation[J]. Applied Mechanics and Materials, 2012(200): 190-193.

[8] 李敏 , 邹斌 . 基于阳极氧化技术制备超疏水表面及其在金属防护中的应用 [J]. 材料保护 , 2021(2): 50-54.

[9] 黄允芳 , 蔡锡昌 . 采用氟钛酸盐封闭阳极氧化铝型材的研究 [J]. 电镀与精饰 , 2016, 38(6): 15-17.

[10] 邓先钦 . 铜合金基体表面超疏水膜的构建及其防腐蚀性能研究 [D]. 上海 : 上海电力学院 , 2012.

[11] 翁天宇 , 赖德林 , 李晓聪 , 等 . 热浸镀锌层磷酸盐 - 铈盐复合处理制备超疏水膜层研究 [J]. 材料研究学报 , 2018, 32(11): 801-810.

[12] 王燕华 , 钟莲 , 刘圆圆 , 等 . 镁基体超疏水表面制备及表征 [J]. 腐蚀科学与防护技术 , 2010, 22(4): 329-332.

[13] Hou Y P, Feng S L, Dai L M, et al. Droplet manipulation on wettable gradient surfaces with micro-/nano-hierarchical structure[J]. Chemistry of Materials, 2016, 28(11): 3625-3629.

[14] 狄志勇 . 超疏水微 / 纳米二级结构涂层的制备及其结构与性能 [D]. 南京 : 南京航空航天大学 , 2010.

[15] Kim J H, Mirzaei A, Kim H W , et al. Realization of superhydrophobic aluminum surfaces with novel micro-terrace nano-leaf hierarchical structure[J]. Applied Surface Science, 2018(451): 207-217.

[16] Zhu J, Zhang T, Liu Y, et al. Fabrication of a superhydrophobic surface by modulating the morphology of organogels[J]. Soft Matter, 2021, 17(13): 3745-3752.

[17] 王英君 , 刘洪雷 , 王国军 , 等 . 新型高强稀土 Al-Zn-Mg-Cu-Sc 铝合金的阳极氧化及其抗腐蚀性能研究 [J]. 中国腐蚀与防护学报 , 2020, 40(2): 131-138.

[18] Guo Y F, Zhang K, Liu L, et al. Effects of sealing process by sol-gel technology on corrosion and wear resistance of aluminum anodic oxide film[J]. Transactions of Materials and Heat Treatment, 2014, 35(9):182-187.

[19] 钱建才 , 邹洪庆 , 方敏 , 等 . 铝合金阳极氧化膜防护性能及失效规律研究 [J]. 装备环境工程 , 2019, 16(3): 58-62.

[20] 庞晓旭 , 何青竹 , 李梦凯 , 等 . AL5252 铝合金阳极氧化及封孔处理后的性能 [J]. 材料保护 , 2019, 52(3): 84-87.

相似文献/References:

[1]王宏*,刘继超.封孔处理对钕铁硼永磁材料化学镀Ni-Zn-P镀层耐蚀性的影响[J].电镀与精饰,2020,(11):5.[doi:10.3969/j.issn.1001-3849.2020.11.0020]
　WANG Hong*,LIU Jichao.Effect of Sealing Treatment on Corrosion Resistance of Electroless Ni-Co-P Coating on NdFeB Permanent Magnetic Material[J].Plating & Finishing,2020,(6):5.[doi:10.3969/j.issn.1001-3849.2020.11.0020]
[2]祁怀伟*,吴心元,王亮兵,等.6061铝合金阳极氧化膜的抗霉菌研究[J].电镀与精饰,2020,(11):39.[doi:10.3969/j.issn.1001-3849.2020.11.0080]
　QI Huaiwei*,WU Xinyuan,WANG Liangbing,et al.Study on the Anti-Mold Performance of 6061Aluminum Alloy Anodic Oxidation Film[J].Plating & Finishing,2020,(6):39.[doi:10.3969/j.issn.1001-3849.2020.11.0080]
[3]王宏智,吴心元,吕成斌,等.3A21铝合金本色阳极氧化膜的抗霉菌研究[J].电镀与精饰,2021,(7):52.[doi:10.3969/j.issn.1001-3849.2021.07.010]
　WANG Hongzhi,WU Xinyuan,LYU Chengbin,et al.Study on the Antifungal Activity of 3A21 Aluminum Alloy Anodic Oxidation Film[J].Plating & Finishing,2021,(6):52.[doi:10.3969/j.issn.1001-3849.2021.07.010]
[4]郭绍福,赵春红*.植酸封孔对铝制件阳极氧化膜耐蚀性的影响[J].电镀与精饰,2021,(8):6.[doi:10.3969/j.issn.1001-3849.2021.08.002]
　GUO Shaofu,ZHAO Chunhong*.Effect of Phytic Acid Sealing on Corrosion Resistance of Anodic Oxidation Film on Aluminum Parts[J].Plating & Finishing,2021,(6):6.[doi:10.3969/j.issn.1001-3849.2021.08.002]
[5]李海宏,郝 健*.铝合金柠檬酸-硫酸阳极氧化及性能研究[J].电镀与精饰,2022,(2):20.[doi:10.3969/j.issn.1001-3849.2022.02.005]
　LI Haihong,HAO Jian *.Anodic Oxidation of Aluminum Alloy with Citric Acid-Sulfuric Acid and Its Properties[J].Plating & Finishing,2022,(6):20.[doi:10.3969/j.issn.1001-3849.2022.02.005]
[6]骆 骢,马 硕*.无铬封闭处理对ZL101A铝合金阳极氧化膜耐蚀性能的影响[J].电镀与精饰,2022,(2):46.[doi:10.3969/j.issn.1001-3849.2022.02.010]
　LUO Cong,MA Shuo *.Effect of Chromium-Free Sealing Treatment on Corrosion Resistance of Anodic Oxide Films on ZL101A Aluminum Alloy[J].Plating & Finishing,2022,(6):46.[doi:10.3969/j.issn.1001-3849.2022.02.010]
[7]吴姗姗,于瑾佳*,刘历波.铈盐封孔对建筑铝合金阳极氧化膜耐蚀性的影响[J].电镀与精饰,2022,(4):1.[doi:10.3969/j.issn.1001-3849.2022.04.001]
　WU Shanshan,YU Jinjia*,LIU Libo.Effect of Cerium Salt Sealing on Corrosion Resistance of Anodic Oxide Film on Architectural Aluminum Alloy[J].Plating & Finishing,2022,(6):1.[doi:10.3969/j.issn.1001-3849.2022.04.001]
[8]高培云.锆盐封孔对建筑铝合金阳极氧化膜耐蚀性能的影响[J].电镀与精饰,2022,(5):44.[doi:10.3969/j.issn.1001-3849.2022.05.008]
　GAO Peiyun.Effect of Zirconium Salt Sealing on Corrosion Resistance of Anodic Oxide Film on Aluminium Alloy Used in Construction[J].Plating & Finishing,2022,(6):44.[doi:10.3969/j.issn.1001-3849.2022.05.008]
[9]王臻卓.电力设备材料酒石酸阳极氧化及其腐蚀行为研究[J].电镀与精饰,2022,(6):26.[doi:10.3969/j.issn.1001-3849.2022.06.006]
　WANG Zhenzhuo.Study on Tartaric Acid Anodic Oxidation of Electrical Equipment Materials and Its Corrosion Behavior[J].Plating & Finishing,2022,(6):26.[doi:10.3969/j.issn.1001-3849.2022.06.006]
[10]邱小云,王冀恒. 铝合金阳极氧化膜沸水-稀土盐双重封闭及力学性能研究 [J].电镀与精饰,2022,(7):30.[doi:10.3969/j.issn.1001-3849.2022.07.006]
　QIU Xiaoyun,WANG Jiheng.Dual Sealing of Anodic Oxidation Film on Aluminum Alloy with Boiling Water and Rare Earth Salt and Mechanical Properties[J].Plating & Finishing,2022,(6):30.[doi:10.3969/j.issn.1001-3849.2022.07.006]

备注/Memo

收稿日期： 2021-11-18 修回日期： 2022-02-14 作者简介： 成张佳宁（ 1993 —），女，博士，高级工程师， email ： chengzh_1158@163.com 基金项目： 住房和城乡建设部科技计划项目（ K42014159 ）

更新日期/Last Update: 2022-06-12