Zhang Xihuan,Wang Pengjie,Wang Mingan,et al.Study on a new type of spinel heterostructure catalyst and oxygen evolution reaction[J].Plating & Finishing,2024,(9):10-18.[doi:doi: 10.3969/j.issn.1001-3849.2024.09.002]
一种新型尖晶石异质结构的催化剂及析氧反应的研究
- Title:
- Study on a new type of spinel heterostructure catalyst and oxygen evolution reaction
- 分类号:
- TQ151.6
- 文献标志码:
- A
- 摘要:
- 为提高在碱性环境中的过渡金属的电催化性能并降低使用成本，合成一种新型尖晶石异质结构的催化剂，并研究R-CFO在1.0 mol/L KOH溶液中的电催化活性及其催化机理。以硝酸钴、硝酸铁、三氯化钌为原料，制备出RuO2@CoFe2O4新型材料。通过XRD、TEM、XPS、电化学实验和理论计算等方法，研究R-CFO在1.0 mol/L KOH溶液中的催化活性及其催化机理。电催化实验表明，合成的新型催化剂R-CFO在碱性环境下的电流密度为10 mA/cm2时的过电位和Tafel斜率仅仅需要215 mV和50.93 mV/dec，电流-时间变化曲线中表现出催化剂较为稳定，合成的R-CFO电催化剂表现出优异的催化性能。因此，本文提出了一种很有前途的方法，对电催化具有潜在应用价值。
- Abstract:
- In order to improve the electrocatalytic performance of transition metals in alkaline environment and reduce the cost, a novel spinel heterostructure catalyst was synthesized, and the electrocatalytic activity and catalytic mechanism of R-CFO in 1.0 mol/L KOH solution were studied. Using cobalt nitrate, iron nitrate and ruthenium trichloride as raw materials, RuO2@CoFe2O4 new material was prepared. The catalytic activity and mechanism of R-CFO in 1.0 mol/L KOH solution were studied by XRD, TEM, XPS, electrochemical experiments and theoretical calculation. Electrocatalytic experiments show that the overpotential and Tafel slope of the synthesized new catalyst R-CFO only require 215 mV and 50.93 mV/dec when the current density is 10 mA/cm 2 under alkaline environment. The current time curve shows that the catalyst is relatively stable. The synthesized R-CFO electrocatalyst showed excellent catalytic performance. Therefore, a promising method is proposed in this paper, which has potential application value for electrocatalysis
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