[1]都玲玲,王 雁,刘成松,等.doi: 10.3969/j.issn.1001-3849.2025.05.011纳米带状V2O3正极材料的制备及其储锌性能[J].电镀与精饰,2025,(05):74-79.
　Zhang Tao,Luo Hao,Yang Qian,et al.Preparation of V2O3 nanobelt cathode materials and their zinc storage properties Du Lingling1, Wang Yan2*, Liu Chengsong2, Wang Yaqing2,[J].Plating & Finishing,2025,(05):74-79.
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doi: 10.3969/j.issn.1001-3849.2025.05.011纳米带状V2O3正极材料的制备及其储锌性能()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年05
页码:
74-79
栏目:
出版日期:
2025-05-31

文章信息/Info

Title:
Preparation of V2O3 nanobelt cathode materials and their zinc storage properties Du Lingling1, Wang Yan2*, Liu Chengsong2, Wang Yaqing2,
作者:
都玲玲1; 王 雁2; 刘成松2; 王亚清2; 张 涛2; 罗 浩2; 杨 倩2; 苏 芸2
(1. 新乡学院 3D 打印学院,河南 新乡 453000; 2. 新乡学院 物理与电子工程学院,河南 新乡 453000)
Author(s):
Zhang Tao2;  Luo Hao2;  Yang Qian2;  Su Yun2
(1. School of 3D Printing, Xinxiang University, Xinxiang 453000, China; 2. School of Physics and Electronic Engineering, Xinxiang University, Xinxiang 453000, China)
关键词:
纳米带; 正极材料; 三氧化二钒; 水系锌离子电池; 储锌性能
Keywords:
nanobelt;  cathode materials;  vanadium trioxide;  aqueous zinc ion batteries;  zinc storage performance
分类号:
TQ317；TM912
文献标志码:
A
摘要:
具有许多优点的水系锌离子电池被认为是先进储能器件的潜在侯选者之一。然而，本身固有低电导率的钒基正极材料在充放电过程中容易发生相变和水系电解液中容易发生副反应，导致其储锌性能不理想。在此，利用4-羟基-3,5-二甲基苯甲腈与乙酰丙酮氧钒之间的配位反应，通过溶剂热反应和一步高温锻烧处理成功制备出纳米带状结构的三氧化二钒(V2O3)。采用各种表征手段对V2O3的形貌和结构进行了探究。纳米带状V2O3因其独特的结构、优异的离子传输性能、多价态变化特性，使其在储锌电化学性能方面表现出色。在0.5/5 A·g–1电流密度下，V2O3正极材料循环100/2 000圈后放电比容量仍然保持263/159 mAh·g–1。因此，提供了一种可以大规模合成具有优异储锌性能正极材料的思路，也为水系锌离子电池正极商业化提供了一种选择。
Abstract:
Aqueous zinc-ion batteries, which have many advantages, are considered to be one of the potential candidates for advanced energy storage devices. However, vanadium-based cathode materials, which have inherently low electrical conductivity, are prone to phase transition during charge and discharge and side reactions in aqueous electrolytes, resulting in unsatisfactory zinc storage performance. Using the coordination reaction between 4-hydroxy-3,5-dimethylbenzonitrile and vanadium acetylacetonate, nanobelt-structured vanadium trioxide (V2O3) was successfully prepared by solvothermal reaction and high-temperature calcination. Various characterization methods were used to investigate the morphology and structure of V2O3. Due to their unique structure, excellent ion transport performance, and multi-valence state change characteristics, V2O3 nanobelts perform excellently in zinc storage. At a current density of 0.5/5 A·g –1, the discharge specific capacity of the V2O3 cathode material still remains at 263/159 mAh·g–1 after 100/2 000 cycles. By synthesizing cathodes with excellent zinc storage performance on a large scale, it provides a means for commercializing aqueous zinc-ion battery cathodes.

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相似文献/References:

[1]蒋玲玲*,陆月朋.VO2·xH2O纳米棒用于水系锌离子电池正极材料[J].电镀与精饰,2024,(6):48.[doi:10.3969/j.issn.1001-3849.2024.06.007]
　Jiang Lingling *,Lu Yuepeng.VO 2 · x H 2 O nanorods used as cathode materials for aqueous zinc-ion batteries[J].Plating & Finishing,2024,(05):48.[doi:10.3969/j.issn.1001-3849.2024.06.007]

更新日期/Last Update: 2025-05-19