[1]范宇涵,侯攀超,宋振兴*,等.doi: 10.3969/j.issn.1001-3849.2025.10.016石墨烯/水性环氧树脂复合涂层的耐腐蚀性能研究[J].电镀与精饰,2025,(10):121-128.
　Jiang Yuxin,Jiang Ge,Hong Lin,et al.Investigation on the corrosion resistance properties of graphene-reinforced waterborne epoxy composite coatings Fan Yuhan1, Hou Panchao1, Song Zhenxing1*, Kuang Hong 2, Wang Liang3,[J].Plating & Finishing,2025,(10):121-128.
点击复制

doi: 10.3969/j.issn.1001-3849.2025.10.016石墨烯/水性环氧树脂复合涂层的耐腐蚀性能研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年10
页码:
121-128
栏目:
出版日期:
2025-10-31

文章信息/Info

Title:
Investigation on the corrosion resistance properties of graphene-reinforced waterborne epoxy composite coatings Fan Yuhan1, Hou Panchao1, Song Zhenxing1*, Kuang Hong 2, Wang Liang3,
作者:
范宇涵1; 侯攀超1; 宋振兴1*; 匡 泓2; 王 亮3; 蒋宇欣4; 姜 戈5; 洪 琳5; 刘文柱5
(1. 天津科技大学 理学院,天津 300457 ;2. 无锡星亿智能环保装备股份有限公司,江苏 无锡 214153 ;3. 无锡市安能金属制品有限公司,江苏 无锡 214254 ;4. 沈阳东环电镀科技有限公司,辽宁 沈阳 110172 ;5. 丹东市鸭绿江金属表面处理中心,辽宁 丹东 118009)
Author(s):
Jiang Yuxin4;  Jiang Ge5;  Hong Lin5;  Liu Wenzhu5
(1. College of Science, Tianjin University of Science and Technology, Tianjin 300457, China; 2. Wuxi Xingyi Intelligent Environmental Protection Equipment Co., Ltd., Wuxi 214153, China; 3. Wuxi An Neng Metal Products Co., Ltd., Wuxi 214254, China; 4. Shenyang Donghuan Electroplating Technology Co., Ltd., Shenyang 110172, China; 5. Dandong City Yalu River Metal Surface Treatment Center, Dandong 118009, China)
关键词:
石墨烯; 水性环氧树脂; 复合涂层; 耐腐蚀性能
Keywords:
graphene;  waterborne epoxy resin;  composite coating;  corrosion resistance performance
分类号:
TQ153.2
文献标志码:
A
摘要:
为提高电镀锌层的耐腐蚀性能，将氧化石墨烯(GO)分散液加入到水性环氧树脂(WEP)涂料中，并将其涂覆于电镀锌层表面，得到GO/WEP复合涂层。采用扫描电子显微镜、红外光谱、电化学测试技术对复合涂层进行了分析。结果表明：通过扫描电子显微镜发现复合涂层中的GO颗粒之间无明显间隙，致密性良好；由红外光谱测试证实GO在WEP中成功掺杂；通过阳极极化测试发现，相较于纯WEP涂层，GO/WEP复合涂层的腐蚀电位值正移0.108 V，腐蚀电流密度值减小3.454×10–5 A/cm 2；交流阻抗测试说明，GO的掺杂提高了复合薄膜的耐腐蚀性能，GO分散液添加量为0.6%的GO/WEP复合涂层耐腐蚀性能最佳。
Abstract:
To enhance the corrosion resistance of electro-galvanized coatings, graphene oxide (GO) dispersion was added to waterborne epoxy resin (WEP) coatings and applied to the surface of electro-galvanized layers to obtain GO/WEP composite coatings. The composite coatings were analyzed by scanning electron microscopy, infrared spectroscopy, and electrochemical testing techniques. The results showed that no obvious gaps were observed between the GO particles in the composite coatings by scanning electron microscopy, indicating good compactness. Infrared spectroscopy confirmed the successful doping of GO in WEP. Anodic polarization tests revealed that the corrosion potential of the GO/WEP composite coating was positively shifted by 0.108 V compared to the pure WEP coating, and the corrosion current density decreased by 3.454×10–5 A/cm 2. AC impedance tests indicated that the doping of GO improved the corrosion resistance of the composite films. The GO/WEP composite coating with a GO dispersion addition of 0.6% exhibited the best corrosion resistance

参考文献/References:

[1].曾连连, 常强, 钟细明, 等. 热镀锌表面超疏水膜层构筑及其耐腐蚀性能研究[J]. 材料保护, 2025, 58(1): 40-48.
[2].喻济兵. 电镀锌技术在工业中的发展和应用[J]. 船电技术, 2018, 38(2): 35-36, 49.
[3].曹楚南. 中国材料的自然环境腐蚀[M]. 北京: 化学工业出版社, 2005: 10-17.
[4].Marcus P. Corrosion mechanisms in theory and practice[M]. Boca Raton: Crc Press, 2011: 938-941.
[5].Seré P R, Banera M, Egli W A, et al. Effect on temporary protection and adhesion promoter of silane nanofilms applied on electro-galvanized steel[J]. International Journal of Adhesion and Adhesives, 2016, 65: 88-95.
[6].Samarah V H, Sandra H P, Celso V S, et al. A comparative study on graphene oxide and carbon nanotube reinforcement of PMMA-Siloxane-silica anticorrosive coatings[J]. Acs Applied Materials, 2016, 8(25): 16339-16350.
[7].Ali H, Majid R A, Majid M, et al. Recent advances and future perspectives for carbon nanostructures reinforced organic coating for anti-corrosion application[J]. Surfaces and Interfaces, 2021, 23: 100994.
[8].Wu K, Gui T, Dong J, et al. Synthesis of robust polyaniline microcapsules via UV-initiated emulsion polymerization for self-healing and anti-corrosion coating[J]. Progress in Organic Coatings, 2022, 162: 106592
[9].Han R, He H, Liu X, et al. Anti-corrosion and self-healing coatings with polyaniline/epoxy copolymer-urea-formaldehyde microcapsules for rusty steel sheets [J]. Journal of Colloid and Interface Science, 2022, 616: 605-617.
[10].丁言祯. 无机建筑涂料的发展趋势[J]. 中国涂料, 2022, 37(5): 60-64.
[11].Huo S Q, Wang J, Yang S, et al. Synthesis of a novel phosphorus-nitrogen type flame retardant composed of maleimide, triazine-trione, and PHO phosphaphenanthrene and its flame retardant effect on epoxy resin[J]. Polymer Degradation and Stability, 2016, 131: 106-113.
[12].孔庆华. 环氧树脂材料在建筑工程中的应用研究进展[J]. 合成材料老化与应用, 2025, 54(1): 69-72.
[13].Ai D, Mo R, Wang H H, et al. Preparation of waterbome epoxy dispersion and its application in 2K waterbome epoxy coatings[J]. Progress in Organic Coatings, 2019, 136: 105258.
[14].Zhang J, Huang H, Ma J, et al. Preparation and properties of corrosion-resistant coatings from waterborne polyurethane modified epoxy emulsion[J]. Frontiers in Materials, 2019, 6: 185.
[15].Xu L L, Ren J, Lu J H, et al. Preparation of double linked waterborne epoxy resin coating using titanium curing agent and aminopropyltriethoxysilane and its anticorrosive properties[J]. International Journal of Electrochemical Science, 2021, 16(7): 210768.
[16].Wang X, Gao K, Caldona E B, et al. Cellulose nanocrystals-reinforced waterborne epoxy coatings with enhanced corrosion resistance for steel[J]. International Journal of Biological Macromolecules, 2024, 257:128755.
[17].Chen Y N, Ren B H, Gao S Y, et al. The sandwich-like structures of polydopamine and 8-hydroxyquinoline coated graphene oxide for excellent corrosion resistance of epoxy coatings[J]. Journal of Colloid and Interface Science, 2020, 565: 436-448.
[18].黄小庆, 杨建军, 吴庆云, 等. 植酸/聚间苯二胺修饰纳米SiO2制备水性环氧复合涂层及其防腐性能[J].高分子材料科学与工程, 2024, 40(1): 34-44.
[19].Zhu K, Li J Y, Wang H H, et al. Comparative study on anticorrosion enhancement of carboxylated and sulfonated self-doped polyaniline on waterborne epoxy coating[J]. Journal of Macromolecular Science Part A, 2020, 58(4): 249-261.
[20].崔明君, 任思明, 张广安, 等. 六方氮化硼掺杂水性环氧树脂耐腐蚀性能的研究[J]. 中国腐蚀与防护学报, 2016, 36(6): 566-572.
[21].童庆玲, 黄小庆, 杨建军, 等. 三聚氰胺改性纳米SiO2水性环氧涂层的制备及防腐性能[J]. 精细化工, 2025, 1-11.
[22].Kyhl L, Nielsen S F, Cabo A G, et al. Graphene as an anti-corrosion coating layer[J]. Faraday Discuss, 2015, 180: 495-509.
[23].Cai H, Li X, Zhang Y, et al. A high corrosion-resistant waterborne epoxy resin coating improved by addition of multi-interface structured zinc phosphate particles[J]. journal of materials research and technology, 2023, 26: 7829-7844.
[24].Chamberland J P, Sellathurai A J, Parent J S, et al. Optimized hydrogel electrodes for supercapacitors from high-concentration aqueous graphene nanoplatelet disper-sions[J]. Journal of Power Sources, 2024, 605: 234435.
[25].Guo S, Chen J, Zhang Y, et al. Graphene-based films: Fabrication, interfacial modification, and applications[J]. Nanomaterials, 2021, 11(10): 2539.
[26].Kyhl L, Nielsen S F, Cabo A G, et al. Graphene as an anti-corrosion coating layer[J]. Faraday Discuss, 2015, 180: 495509.
[27].Gearba R I, Mueller K M, Veneman P A, et al. Atom-scale covalent electrochemical modification of single-layer graphene on SiC substrates by diaryliodonium salts[J]. Journal of Electroanalytical Chemistry, 2015, 753: 9-15.
[28].Ramezanzndeh B, Niroumandrad S, Ahmadi A, et al. Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of aminofunction-alized graphene oxide[J]. Corrosion Science, 2016, 103: 283-304.
[29].李晓征, 吴茹梦, 张红军, 等. 一种铝及铝合金氰化镀银前处理酸洗工艺研究[J]. 电镀与精饰, 2024, 46(11): 30-35.
[30].奚军生, 袁景追, 喻岚, 等. 钝化液中金属杂质对镀锌层三价铬钝化的影响[J]. 电镀与涂饰, 2024, 43(6): 117-122.
[31].Hao S S, Sun X F, Song W, et al. Effect of modified graphene on corrosion resistance of epoxy resin coating[J]. Paint & Coatings Industry, 2018, 48(12): 34.

相似文献/References:

[1]唐祝兴,余 孟.ZnO/石墨烯复合光催化材料的制备及性能研究[J].电镀与精饰,2019,(7):20.[doi:10.3969/j.issn.1001-3849.2019.07.005]
　TANG Zhuxing,YU Meng.Preparation and Properties of ZnO / Graphene Composite Photocatalyst[J].Plating & Finishing,2019,(10):20.[doi:10.3969/j.issn.1001-3849.2019.07.005]
[2]赵 晶,刘诗伟,杨雨欣,等.电沉积制备纳米金-石墨烯复合材料修饰电极测定氨苄西林[J].电镀与精饰,2022,(11):41.[doi:10.3969/j.issn.1001-3849.2022.11.008]
　ZHAO Jing,LIU Shiwei,YANG Yuxin,et al.Electrodeposition of Au Nanoparticle-Graphene Composites Modified Electrode for Ampicillin Detection[J].Plating & Finishing,2022,(10):41.[doi:10.3969/j.issn.1001-3849.2022.11.008]
[3]巩鹏妮,弓巧娟 *,梁云霞,等.镍钴硫化物、石墨烯与聚苯胺复合材料在超级电容器中的应用研究进展[J].电镀与精饰,2023,(3):90.[doi:10.3969/j.issn.1001-3849.2023.03.013]
　Gong Pengni,Gong Qiaojuan *,Liang Yunxia,et al.Research progress of Ni-Co sulfide graphene and polyaniline composites applied in supercapacitors[J].Plating & Finishing,2023,(10):90.[doi:10.3969/j.issn.1001-3849.2023.03.013]
[4]史雨菲,李小丽,何天翊,等.石墨烯基材料在3D打印领域的研究进展[J].电镀与精饰,2023,(7):74.[doi:10.3969/j.issn.1001-3849.2023.07.010]
　Shi Yufei,Li Xiaoli,He Tianyi,et al.Research progress of graphene-based materials in 3D printing field[J].Plating & Finishing,2023,(10):74.[doi:10.3969/j.issn.1001-3849.2023.07.010]
[5]陈 可,张 琦,王凯凤,等. 聚酰亚胺复合薄膜性能研究 [J].电镀与精饰,2024,(2):96.[doi:10.3969/j.issn.1001-3849.2024.02.014]
　Chen Ke,Zhang Qi,Wang Kaifeng,et al.Study on the properties of polyimide composite film[J].Plating & Finishing,2024,(10):96.[doi:10.3969/j.issn.1001-3849.2024.02.014]
[6]邓名洋*,李瑞金,张南瑞,等. 石墨烯添加剂与电流密度对铝锂合金阳极氧化膜层耐蚀性能的影响 [J].电镀与精饰,2024,(2):101.[doi:10.3969/j.issn.1001-3849.2024.02.015]
　Deng Mingyang*,Li Ruijin,Zhang Nanrui,et al.Effect of graphene additive and current density on corrosion resistance of anodized coatings on aluminium-lithium alloys[J].Plating & Finishing,2024,(10):101.[doi:10.3969/j.issn.1001-3849.2024.02.015]

更新日期/Last Update: 2025-10-17