ZENG Zhiwen,DU Cong,et al.Advances in Research on Titanium Substrate Lead Dioxide Electrode[J].Plating & Finishing,2021,(8):48-53.[doi:10.3969/j.issn.1001-3849.2021.08.011]
钛基体二氧化铅电极改性研究进展
- Title:
- Advances in Research on Titanium Substrate Lead Dioxide Electrode
- 文献标志码:
- A
- 摘要:
- 本文介绍以钛金属为基体的二氧化铅阳极材料的改性研究进展,针对钛基体二氧化铅电极氧化技术在催化活性与稳定性上的不足,主要从基体、中间层、表面活性层三个方面的改性研究进行概括总结,包括基体改性、增加电极镀层、掺杂金属元素、离子、氧化物、活性颗粒改性等方法,指出了二氧化铅电极在处理废水和目标污染物降解机制存在的问题,并对其未来的发展方向进行展望。
- Abstract:
- In this paper, the research progress of the modification of lead dioxide anode materials based on titanium metal was introduced. In view of the lack of catalytic activity and stability of the titanium dioxide lead dioxide electrode oxidation technology, the studies on modification of substrate, intermediate layer and surface active layer were summarized, including matrix modification, increase the electrode coating, metal elements doping, ion, oxide, activated particles modification methods. The problems of lead dioxide electrode in treating wastewater and degradation mechanism of target pollutants were pointed out, and the future development direction of lead dioxide anode was prospected.
参考文献/References:
[1] 赵媛媛, 王德军, 赵朝成. 电催化氧化处理难降解废水用电极材料的研究进展[J]. 材料导报, 2019, 33(7): 50-57.
Zhao Y Y, Wang D J, Zhao C C. Progress in electrode materials for refractory wastewater treatment by electrocatalytic oxidation [J]. Materials Review, 2019, 33(7): 50-57 (in Chinese).
[2] Duan X, Ma F, Yuan Z, et al. Electrochemical degradation of phenol in aqueous solution using PbO2 anode [J]. Journal of the Taiwan Institute of Chemical Engineers, 2013, 44(1): 95-102.
[3] Sui X, Duan X, Xu F, et al. Fabrication of three-dimensional networked PbO2 anode for electrochemical oxidation of organic pollutants in aqueous solution[J]. Journal of the Taiwan Institute of Chemical Engineers, 2019, 100, 74-84.
[4] Zhao W, Xing J, Chen Det al. Electrochemical degradation of Musk ketone in aqueous solutions using a novel porous Ti/SnO2-Sb2O3/PbO2 electrodes[J]. Journal of Electroanalytical Chemistry, 2016, 775, 179-188.
[5] Xie R, Meng X, Sun P, et al. Electrochemical oxidation of ofloxacin using a TiO2-based SnO2-Sb/polytetrafluoroethylene resin-PbO2 electrode: Reaction kinetics and mass transfer impact [J]. Applied Catalysis B Environmental, 2017, 203, 515-525.
[6] 梁镇海, 丁永波, 孙颜发,等. 渗氮钛基PbO2耐酸阳极的电化学性能[J]. 稀有金属材料与工程, 2010, 39(A01): 56-59.
Liang Z H, Ding Y B, Sun Y F, et al. Study on electrochemical properties of TiN0.26/SnO2-Sb2Ox/PbO2 electrode [J]. Rare Metal Materials and Engineering, 2010, 39(A01): 56-59 (in Chinese).
[7] Wang L, Pan F, Wang L. Preparation and characterization of antimony-doped tin dioxide interlayer and β-PbO2 film on porous titanium[J]. International Journal of Electrochemical Science, 2014, 9, 3628-3636.
[8] Yang X, Zou R, Huo F, et al. Preparation and characterization of Ti/SnO2-Sb2O3-Nb2O5/PbO2 thin film as electrode material for the degradation of phenol [J]. Journal of hazardous materials, 2009, 164(1): 367-373.
[9] Zheng Y, Su W, Chen S, et al. Ti/SnO2-Sb2O5-RuO2/α-PbO2/β-PbO2 electrodes for pollutants degradation [J]. Chemical Engineering Journal, 2011, 174(1): 304-309.
[10] 徐浩, 延卫, 常乐. Pb3O4层引入对钛基PbO2电极强化寿命的影响[J]. 稀有金属材料与工程, 2012, 41(3): 462-466.
Xu H, Yan W, Chang L. Effect of Pb3O4 layer introduction on the accelerated life of the Ti-PbO2 electrodes [J]. Rare Metal Materials and Engineering, 2012, 41(3): 462-466 (in Chinese).
[11] Tang Z, Zhou J, Qi L, et al. Preparation of Ti/Sb-SnO2-GO/PbO2 electrode and its application in electrochemical oxidation treatment of ultralow-concentration residual hydrazine in water [J]. International Journal of Electrochemical Science, 2017, 12, 4465-4478.
[12] 唐长斌, 郑超, 于丽花等. 电镀镍中间层对钛基二氧化铅阳极性能的影响[J]. 稀有金属材料与工程, 2019, 48(1): 143-151.
Tang C B, Zheng C, Yu L H, et al. Effect of electroplating nickel inter-layer on performance of Ti-based lead dioxide electrodes [J]. Rare Metal Materials and Engineering, 2019, 48(1): 143-151 (in Chinese).
[13] Duan X, Zhao C, Liu W, et al. Fabrication of a novel PbO2 electrode with a graphene nanosheet interlayer for electrochemical oxidation of 2-chlorophenol [J]. Electrochimica Acta, 2017, 240, 424-436.
[14] Tang C, Lu Y, Wang F, et al. Influence of a MnO2-WC interlayer on the stability and electrocatalytic activity of titanium-based PbO2 anodes[J]. Electrochimica Acta, 2020, 331, 135381.
[15] Cao J, Zhao H, Cao F, et al. Electrocatalytic degradation of 4-chlorophenol on F- doped PbO2 anodes[J]. Electrochimica Acta, 2009, 54(9): 2595-2602.
[16] Bian X, Xia Y, Zhan T, et al. Electrochemical removal of amoxicillin using a Cu doped PbO2 electrode: Electrode characterization, operational parameters optimization and degradation mechanism[J]. Chemosphere, 2019, 233, 762-770.
[17] Xia Y, Dai Q, Chen J. Electrochemical degradation of aspirin using a Ni doped PbO2 electrode[J]. Journal of Electroanalytical Chemistry, 2015, 744, 117-125.
[18] 赵曼曼, 姚颖悟, 周涛. 二氧化铅电极掺杂改性研究进展[J]. 电镀与精饰, 2013, 35(3): 7-12.
Zhao M M, Yao Y W, Zhou T. Research progress on modification of PbO2 electrodes [J]. Plating & Finishing, 2013, 35(3): 7-12 (in Chinese).
[19] Yao Y, Teng G, Yang Y, et al. Electrochemical oxidation of acetamiprid using Yb-doped PbO2 electrodes: Electrode characterization, influencing factors and degradation pathways[J]. Separation and Purification Technology, 2019, 211, 456-466.
[20] Mai X, Yulu M, Wenliang S, et al. Preparation and characterization of Fe-Ce co-doped Ti/TiO2 NTs/PbO2 nanocomposite electrodes for efficient electrocatalytic degradation of organic pollutants[J]. Journal of Electroanalytical Chemistry, 2018, 823, 193-202.
[21] Dai Q, Xia Y, Sun C, et al. Electrochemical degradation of levodopa with modified PbO2 electrode: Parameter optimization and degradation mechanism[J]. Chemical Engineering Journal, 2014, 245, 359-366.
[22] Yao Y, Jiao L, Cui L, et al. Preparation and characterization of PbO2-CeO2 nanocomposite electrode with high cerium content and its appplication in the electrocatalytic degradation of malachite green[J]. Journal of The Electrochemical Society, 2015, 162(9): H693-H698.
[23] Yang Y, Cui L, Li M, et al. Electrochemical removal of metribuzin in aqueous solution by a novel PbO2/WO3 composite anode: Characterization, influencing parameters and degradation pathways[J]. Journal of the Taiwan Institute of Chemical Engineers, 2019, 102, 170-181.
[24] Xu Z, Liu H, Niu J, et al. Hydroxyl multi-walled carbon nanotube-modified nanocrystalline PbO2 anode for removal of pyridine from wastewater[J]. Journal of hazardous materials, 2017, 327, 144-152.
[25] Duan X, Ma F, Yuan Z, et al. Comparative studies on the electro-catalytic oxidation performance of surfactant-carbon nanotube-modified PbO2 electrodes[J]. Journal of Electroanalytical Chemistry, 2012, 677, 90-100.
[26] Li X, Xu H, Yan W. Effects of twelve sodium dodecyl sulfate (SDS) on electro-catalytic performance and stability of PbO2 electrode[J]. Journal of Alloys and Compounds, 2017, 718, 386-395.
[27] Duan X, Xu F, Wang Y, et al. Fabrication of a hydrophobic SDBS-PbO2 anode for electrochemical degradation of nitrobenzene in aqueous solution[J]. Electrochimica Acta, 2018, 282, 662-671.
[28] Li X, Xu H, Yan W. Fabrication and characterization of PbO2 electrode modified with polyvinylidene fluoride (PVDF)[J]. Applied Surface Science, 2016, 389, 278-286.
[29] Duan X, Ma F, Yuan Z, et al. Lauryl benzene sulfonic acid sodium-carbon nanotube-modified PbO2 electrode for the degradation of 4-chlorophenol[J]. Electrochimica Acta, 2012, 76, 333-343.
备注/Memo
收稿日期: 2020-05-27;修回日期: 2020-07-15
作者简介: 曾志文(1994—),男,硕士,研究方向为电催化降解水污染物,E-mail:18848957172@163.com
基金项目: 国家自然科学