He Haotao,Wang Chen,Li Jinhui,et al.Study on laser surface modification of AZ91 magnesium alloy for automobile[J].Plating & Finishing,2023,(5):41-50.[doi:10.3969/j.issn.1001-3849.2023.05.006]
汽车用AZ91镁合金的表面激光改性研究
- Title:
- Study on laser surface modification of AZ91 magnesium alloy for automobile
- Keywords:
- laser cladding ; laser power ; scanning speed ; wear volume ; corrosion resistance
- 分类号:
- TG174.4
- 文献标志码:
- A
- 摘要:
- 为了解决压铸 AZ91 镁合金耐蚀和耐磨性能较差的问题,采用激光熔覆的方法在汽车用压铸 AZ91 镁合金表面制备了激光熔覆层,研究了激光功率和激光扫描速度对熔覆层成型、截面和表面形貌、物相组成、耐蚀和耐磨性能的影响。结果表明,过小 / 过大激光功率或者过大扫描速度会使得熔覆层中产生气孔、熔坑等缺陷;不同激光功率和扫描速度下,熔覆层与 AZ91 镁合金基体结合良好, AZ91 镁合金表面激光熔覆层都主要由 α -Mg 、 Mg 17 Al 12 、 AlCu 4 、 Al 4 MgY 和 MgAl 相组成;随着激光功率增加,熔覆层表面晶界间距离和晶粒尺寸增大,熔覆层平均维氏硬度会逐渐减小;随着激光扫描速度增加,熔覆层厚度和熔覆层晶粒尺寸逐渐减小。激光熔覆层的耐蚀性和耐磨性都优于 AZ91 镁合金基体, Al-Cu/Y 2 O 3 熔覆层适宜的激光熔覆工艺为:激光功率 1100 W 、扫描速度 500 mm/min ,此时激光熔覆层与基体结合良好,熔覆层致密、晶粒细小、硬度较高,具有良好的耐蚀性和耐磨性。
- Abstract:
- : In order to solve the problem of poor corrosion resistance and wear resistance of die cast AZ91 magnesium alloy , the laser cladding layer was prepared on the surface of die casting AZ91 magnesium alloy for automobile by laser cladding , the effects of laser power and laser scanning speed on the formation , cross section and surface morphology , phase composition , corrosion resistance and wear resistance of the cladding layer were studied. The results showed that , too small / too large laser power or too high scanning speed will cause defects such as pores and craters in the cladding layer ; under different laser power and scanning speed , the cladding layer and AZ91 magnesium alloy substrate are well bonded. The laser cladding layer on the surface of AZ91 magnesium alloy is mainly composed of α -Mg , Mg 17 Al 12 , AlCu 4 , Al 4 MgY and MgAl ; with the increase of laser power , the distance between grain boundaries and grain size on the surface of cladding layer increase , and the average hardness of cladding layer decreases gradually ; with the increase of laser scanning speed , the thickness and grain size of cladding layer decrease gradually. The corrosion resistance and wear resistance of the laser clad ding layer are better than these of AZ91 magnesium alloy substrate. The suitable laser cladding process for Al-Cu/Y 2 O 3 cladding layer is : laser power 1100 W , scanning speed 500 mm/min , while the laser cladding layer and the substrate are well combined , the cladding layer is dense , fine grain , high hardness , and has good corrosion resistance and wear resistance.
参考文献/References:
[1] Manroo S A, Khan N Z, Ahmad B. Study on surface modification and fabrication of surface composites of magnesium alloys by friction stir processing: a review[J]. Journal of Engineering and Applied Science, 2022, 69(1):1-23.
[2] 刘璐超 , 娄丽 . 镁合金的表面处理 [J]. 材料开发与应用 , 2022, 37(1): 98-102.
[3] 林基辉 , 刘德鑫 , 李耀 , 等 . 激光合金化技术在表面改性中的应用研究进展 [J]. 热加工工艺 , 2020, 49(8): 13-16.
[4] 刘延涛 , 宋瑞芹 , 安丰发 , 等 . 铸造镁合金表面处理现状及发展趋势 [J]. 专用汽车 , 2022(1): 56-58.
[5] Das A K. Recent trends in laser cladding and alloying on magnesium alloys: A review[J]. Materials Today: Proceedings, 2022, 51(P1) : 723-727.
[6] Azadi M, Ivanov K, Rezanezhad S, et al. Scanning and transmission electron microscopy analysis for surface-modified AM60 magnesium alloy by pulsed electron beam irradiation[J]. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 2022(513): 9-13.
[7] 刘明杰 , 刘恒慨 , 方立友 . 体育器械用镁合金材料的激光表面改性处理 [J]. 应用激光 , 2022, 42(2):84-90.
[8] 向峻伯 , 王从明 , 陈凯镔 , 等 . 汽车用 MB15 镁合金的表面改性与耐腐蚀性能 [J]. 金属热处理 , 2019, 44(12): 186-192.
[9] 崔反东 , 高小丽 , 冯宇琴 . AZ91D 镁合金电镀 Al-Zn 复合镀层及耐蚀性研究 [J]. 电镀与精饰 , 2022, 44(3): 12-17.
[10] Saxena A, Raman R. Role of surface preparation in corrosion resistance due to silane coatings on a magnesium alloy[J]. Molecules (Basel, Switzerland), 2021, 26(21): 6663-6672.
[11] Liu F J, Li A D, Shen Z K, et al. Microstructure and corrosion behavior of Al-Ti-TiC- CNTs/AZ31 magnesium matrix composites prepared using laser cladding and high speed friction stir processing[J]. Optics & Laser Technology, 2022, 152: 108078-108085.
[12] Zhu Y Y, Gao W D, Huang H D, et al. Investigation of corrosion resistance and formation mechanism of calcium-containing coatings on AZ31B magnesium alloy[J]. Applied Surface Science, 2019, 487:581-592.
[13] 刘明杰 , 刘恒慨 , 方立友 . 体育器械用镁合金材料的激光表面改性处理 [J]. 应用激光 , 2022, 42(2): 84-90.
[14] 薛海涛 , 刘晓锋 , 秦克丽 . 镁合金体育器械的表面改性与性能研究 [J]. 粉末冶金工业 , 2021, 31(3): 55-62.
[15] Lin SP, Nie ZR, Hui H, et al. Annealing behavior of a modified 5083 aluminum alloy[J]. Materials and Design, 2010, 31(3): 1607-1612.
[16] Xu L, Liu N, Cao L, et al. Influences of electrolytes on tribocorrosion performance of MAO coating on AZ31B magnesium alloy in simulated body fluid[J]. International Journal of Applied Ceramic Technology, 2021, 18(5): 1657-1669.
[17] Lu H, Li W, Qin E, et al. The gradient microstructure and high-temperature wear behavior of the Co-Cr-Mo -Si coating by laser cladding[J]. Journal of Thermal SprayTechnology, 2021, 30(4): 968-976.
[18] Asoh H, Asakura K, Hashimoto H. Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy[J]. RSC Advances. 2020, 10(15): 9026- 9036.
[19] Wang Y. Correlations between the growth mechanism and corrosion resistance of plasma electrolytic oxidation coatings on AZ31B magnesium alloy[J]. International Journal of Electrochemical Science, 2019(14): 11465-11479.
[20] Srinivasan A, Li Y H, Lu N, et al. Microstructural evolution and properties analysis of laser surface melted and Al/SiC cladded magnesium-rare earth alloys[J]. Journal of Alloys and Compounds, 2020, 848: 156598-156605.
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备注/Memo
收稿日期: 2022-09-01 修回日期: 2022-11-29 作者简介: 和豪涛( 1982- ),男,硕士,副教授,研究方向;汽车材料、表面工程等, email : hnjyhe@163.com 基金项目: 河南省科技攻关计划项目( 182102210296 )?/html>