Li Ning.Ultrasonic assisted electrodeposition of Zn-Ni-P/nano-ZrO 2 composite coatings on iron matrix and their properties[J].Plating & Finishing,2023,(7):8-16.[doi:10.3969/j.issn.1001-3849.2023.07.002]
超声波辅助铁基体电沉积Zn-Ni-P/纳米ZrO2复合镀层及性能研究
- Title:
- Ultrasonic assisted electrodeposition of Zn-Ni-P/nano-ZrO 2 composite coatings on iron matrix and their properties
- 关键词:
- Zn-Ni-P/ 纳米 ZrO 2 复合镀层; 超声波辅助电沉积; ZrO 2 颗粒; 耐磨性能; 耐腐蚀性能
- Keywords:
- Zn-Ni-P/nano-ZrO 2 composite coating ; ultrasonic assisted electrodeposition ; ZrO 2 particles ; wear resistance ; corrosion resistance
- 分类号:
- TQ153
- 文献标志码:
- A
- 摘要:
- 通过电沉积并辅助超声波振荡在铁基体上制备出 Zn-Ni-P/ 纳米 ZrO 2 复合镀层。研究了镀液中 ZrO 2 颗粒浓度对复合镀层中 ZrO 2 颗粒含量以及复合镀层表面形貌、相结构、硬度、耐磨性能和耐腐蚀性能的影响。结果表明：随着镀液中 ZrO 2 颗粒浓度从 5 g/L 增加至 30 g/L ， ZrO 2 颗粒含量呈现先升高后降低趋势，复合镀层的形貌特征发生变化，导致硬度、耐磨性能和耐腐蚀性能存在差异，但不同复合镀层的相结构无明显差异，都含有单质 Zn 、 Ni 5 Zn 21 和 ZrO 2 相。镀液中 ZrO 2 颗粒浓度为 20 g/L 时，复合镀层中 ZrO 2 颗粒含量达到 10.43% ，该复合镀层的晶粒细小且结合紧密，表现出良好的致密性，硬度达到 503.5 HV ，平均摩擦系数和磨损失重仅为 0.48 和 3.42 mg ，电荷转移电阻和低频端阻抗值分别达到 6.34×10 3 Ω ·cm 2 和 6.84×10 3 Ω ·cm 2 ，其性能与 Zn-Ni-P 合金镀层相比显著提高。适当增加镀液中 ZrO 2 颗粒浓度有利于提高复合镀层中 ZrO 2 颗粒含量，使复合镀层的晶粒明显细化且致密性改善，具有较强的阻碍局部塑性变形和承载能力，并且能有效抑制电化学腐蚀，从而表现出更好的性能。
- Abstract:
- ： Zn-Ni-P/nano-ZrO 2 composite coatings were prepared on iron matrix by ultrasonic assisted electrodeposition ， and the effect of ZrO2 particles concentration in the plating solution on the content of ZrO 2 particles in the composite coating and the surface morphology ， phase structure ， hardness ， wear resistance and corrosion resistance of the composite coating was studied. The results showed that ， with the increase of ZrO2 particles concentration in the plating solution from 5 g/L to 30 g/L ， the content of ZrO 2 particles increased first and then decreased ， and the morphology characteristics of the composite coating changed ， resulting in obvious differences in the hardness ， wear resistance and corrosion resistance. However ， there is no significant difference in the phase structure ， and different composite coatings all contain elemental Zn ， Ni 5 Zn 21 and ZrO 2 phases. When the ZrO2 particles concentration in the plating solution is 20 g/L ， the content of ZrO 2 particles in the composite coating reaches 10.43%. The composite coating has fine and tightly-bonded grains and shows good compactness ， and the hardness reaches 503.5 HV. The average friction coefficient and wear weightlessness are only 0.48 and 3.42 mg ， and the charge-transfer resistance and low-frequency terminal impedance are 6.34×10 3 Ω ·cm 2 and 6.84×10 3 Ω ·cm 2 ， respectively. The performance of composite coating is significantly improved compared with that of Zn-Ni-P alloy coating. Appropriately increasing the concentration of ZrO2 particles in the plating solution is beneficial to increase the content of ZrO 2 particles in the composite coating ， so that the grains of the composite coating is significantly refined and the compactness is improved ， which has a strong resistance to the local plastic deformation and bearing capacity ， and effectively inhibits the electrochemical corrosion ， thus resulting in better performance.
参考文献/References:
[1] 高荣龙 , 向可友 , 林建华 , 等 . Zn-Ni 合金镀层中添加第三种元素和纳米颗粒的研究新进展 [J]. 表面技术 , 2018, 47(10): 262-268.
[2] 付川 , 祁俊生 . 正交试验优化电镀 Zn-Ni-P 合金工艺 [J]. 表面技术 , 2003, 32(6): 43-45.
[3] 刘军松 , 刘定富 , 苏琪 , 等 . 有机添加剂对电镀 Zn-Ni-P 合金的影响 [J]. 电镀与精饰 , 2019, 41(7): 6-9
[4] 刘军松 , 刘定富 , 苏琪 , 等 . 电镀 Zn-Ni-P 合金及其耐蚀性研究 [J]. 电镀与精饰 , 2019, 41(2): 1-5.
[5] 谭育慧 , 王艳 , 章朦 , 等 . 电解铜箔表面电沉积 Zn-Ni-P-La 合金工艺 [J]. 应用化学 , 2015, 32(4): 458-463
[6] Kumar C M P, Lakshmikanthan A, Chandrashekarappa M P G, et al. Electrodeposition based preparation of Zn-Ni alloy and Zn- Ni-WC nano-composite coatings for corrosion-resistant applications[J]. Coatings, 2021, 11(6): 712.
[7] Li Baosong, Li Dandan, Xia Wenzhe, et al. Synthesis and characterization of a novel Zn-Ni and Zn-Ni/Si 3 N 4 composite coating by pulse electrodeposition[J]. Applied Surface Science, 2018(458): 665-677.
[8] Ataie S A, Zakeri A. Improving tribological properties of (Zn-Ni)/nano Al 2 O 3 composite coatings produced by ultrasonic assisted pulse plating[J]. Journal of Alloys and Compounds, 2016(674): 315-322.
[9] 杨惠良 . 硫酸盐镀液中紫铜电沉积 Ni-Co/WC 复合镀层的工艺条件优化 [J]. 电镀与精饰 , 2021, 43(6): 30-34.
[10] 赵金国 , 肖传军 , 乔勋 , 等 . 热处理对 Ni-P/WS 2 复合镀层硬度及自润滑性能的影响 [J]. 材料保护 , 2022, 55(3): 19-22.
[11] 杨艳玲 , 申勇峰 , 陈进耿 , 等 . 超声波搅拌－脉冲电沉积法制备纳米镍 [J]. 金属学报 , 2007, 43(8): 883-888.
[12] 兰龙 , 谭俊 , 杜军 , 等 . 超声波辅助选择性电沉积技术研究进展 [J]. 中国机械工程 , 2015, 26(9): 1260-1270.
[13] Laszczynska A, Winiarski J, Szczygie B, et al. Electrodeposition and characterization of Ni-Mo-ZrO 2 composite coatings[J]. Applied Surface Science, 2016(369): 224-231.
[14] 孙万昌 , 佘晓林 , 侯冠群 , 等 . ZrO 2 含量对 Ni-Co-ZrO 2 复合镀层显微硬度和耐磨性能的影响 [J]. 人工晶体学报 , 2014, 44(6): 1555-1560.
[15] 吕臣凯 , 盛敏奇 , 钟庆东 . 超声波作用下电沉积纳米晶 Co-W 合金镀层 [J]. 腐蚀与防护 , 2015, 36(2): 192-196.
[16] Dhakal D R, Kshetri Y K, Gyawali G, et al. Understanding the effect of Si 3 N 4 nanoparticles on wear resistance behavior of electroless Nickel-Phosphorus coating through structural investigation[J]. Applied Surface Science, 2021, 541(1): 1-12.
[17] 段昭宇 , 李长生 , 开绍森 , 等 . 镀镍石墨 /NiCrW 合金复合材料的微观组织和摩擦学性能 [J]. 材料保护 , 2021, 54(4): 1-6.
[18] Wang L, Ren J, Zhao Y, et al. Effect of Ti microparticles on the microstructure and properties of Ni-Ti composite coating prepared by electrodeposition[J]. Journal of Alloys and Compounds, 2022(908): 164313.
[19] 谢凤宽 , 章浩 , 刘谦 . 钛合金微弧氧化膜层摩擦学性能的研究进展 [J]. 材料保护 , 2022, 55(5): 167-178.
[20] 孔丹 , 罗志强 , 金胜然 . 铜合金的表面化学镀层制备与摩擦学性能研究 [J]. 电镀与精饰 , 2022, 44(8): 23-30.
备注/Memo
收稿日期： 2022-11-03 修回日期： 2022-11-13 作者简介： 李宁（ 1986 ―），硕士，讲师，研究方向为纳米材料、表面工程等， email ： Teach_li252001@126.com 基金项目： 山东省自然科学基金面上项目（ ZR2021ME132 ）；山东省教育科学“十三五”规划课题（ 2020ZC273 ）?/html>