[1]谭 鑫*,李欣义,吴瑛琳,等. 简单且大尺寸超疏水硅橡胶涂层的制备 [J].电镀与精饰,2023,(10):90-96.[doi:10.3969/j.issn.1001-3849.2023.10.015]
　Tan Xin*,Li Xinyi,Wu Yinglin,et al.Simple and large size method for preparing superhydrophobic silicone rubber coating[J].Plating & Finishing,2023,(10):90-96.[doi:10.3969/j.issn.1001-3849.2023.10.015]
点击复制

简单且大尺寸超疏水硅橡胶涂层的制备
()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2023年10
页码:
90-96
栏目:
出版日期:
2023-10-15

文章信息/Info

Title:
Simple and large size method for preparing superhydrophobic silicone rubber coating
作者:
（1.三峡大学 电气与新能源学院 湖北省微电网工程技术研究中心，湖北 宜昌 443002； 2.三峡大学 材料与化工学院 无机非金属晶体与能量转换材料重点实验室，湖北 宜昌 443002）
Author(s):
（1. Hubei Provincial Engineering Technology Research Center for Microgrid， College of Electrical Engineering & New Energy， Three Gorges University， Yichang 443002， China； 2. Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials， College of Materials and Chemical Engineering， Three Gorges University， Yichang 443002， China）
关键词:
超疏水; 硅橡胶; 硅烷偶联剂; 大尺寸制备
Keywords:
super-hydrophobic ;  silicone rubber ;  silane coupling agent ;  large size preparation
分类号:
TQ178
DOI:
10.3969/j.issn.1001-3849.2023.10.015
文献标志码:
A
摘要:
采用疏水气相纳米二氧化硅构建粗糙结构，双组分室温硫化硅橡胶（ RTV - 2 ）作为黏合剂增加涂层的机械性能，制备的涂层水接触角达到 155.5 ° ，滚动角达到 8 ° 。加入硅烷偶联剂（ KH-570 ）对涂层疏水改性后，涂层水接触角达到 160.5 ° ，滚动角达到 4 ° 。采用自清洁实验、机械性能实验、耐气候老化实验对涂层性能进行了测试，结果表明涂层具有良好的自清洁、机械性能高、耐气候老化等优点。涂层实验步骤简单、药品经济型高、不需要高温固化。室温下 2 h 可以完成涂层制备的全过程，适用于大尺寸制备。实验方案为超疏水涂层商用化提供了一定的思路。
Abstract:
： The rough structure of the coating was constructed by hydrophobic vapor nano-silica ， and the mechanical properties of the coatings were increased by using two-component silicone rubber （ RTV-2 ） as adhesive. The hydrophobic angle of the prepared coating reached 155.5 ° and the rolling angle reached 8 °. After adding silane coupling agent （ KH-570 ） to the hydrophobic modification of the coating ， the hydrophobic angle of the coating reached 160.5 ° and the rolling angle reached 4 °. The coating properties were tested by self-cleaning experiment ， mechanical property experiment and weather-aging resistance experiment. The results showed that the coating had the advantages of good self-cleaning ， high mechanical property and weather-aging resistance. The coating experiment was simple ， economical and did not require high temperature curing. The whole process of coating preparation can be completed in 2 h at room temperature ， which was suitable for large size preparation. The experimental scheme can provide some references for the commercialization of superhydrophobic coatings.

参考文献/References:



[1] Barthlott W, Neinhuis C. Purity of the sacred lotus, or escape from contamination in biological surfaces[J]. Planta, 1997, 202(1): 1-8.

[2] Darvizeh M, Darvizeh A, Rajabi H, et al. Free vibra tion analysis of dragonfly wings using finite element method[J]. The International Journal of Multiphysics, 2009, 3(1): 101-110.

[3] Gao X, Yan X, Yao X, et al. The dry-style antifogging properties of mosquito compound eyes and artificial analogues prepared by soft lithography[J]. Advanced Materials, 2007, 19(17): 2213-2217.

[4] Manatunga D C, de Silva R M, de Silva K M N. Double layer approach to create durable superhydrophobicity on cotton fabric using nano silica and auxiliary non fluorinated materials[J]. Applied Surface Science, 2016, 360: 778-788.

[5] Gao S, Sun J, Liu P, et al. A robust polyionized hydrogel with an unprecedented underwater anti-crude-oil-adhesion property[J]. Advanced Materials, 2016, 28(26): 5307-5314.

[6] Wang P, Yao T, Li Z, et al. A superhydrophobic/electrothermal synergistically anti-icing strategy based on graphene composite[J]. Composites Science and Technology, 2020, 198: 108307.

[7] Tie L, Li J, Liu J, Guo Z, et al. Dual superlyophobic surfaces with superhydrophobicity and underwater superoleophobicity[J]. Journal of Materials Chemistry A, 2018, 6(25): 11682-11687.

[8] Shi X, Zhao L, Wang J, et al. Toward easily enlarged superhydrophobic copper surfaces with enhanced corrosion resistance, excellent self-cleaning and anti-icing performance by a facile method[J]. Journal of Nanoscience and Nanotechnology, 2020, 20(10): 6317-6325.

[9] Okoshi M, Pambudi W S. Fabrication of superhydrophobic silicone rubber by ArF-excimer-laser-induced microstructuring for repelling water in water[J]. Applied Physics Express, 2016, 9(11): 112701.

[10] Ju J, Yao X, Hou X, et al. A highly stretchable and robust non-fluorinated superhydrophobic surface[J]. Journal of Materials Chemistry A, 2017, 5(31): 16273-16280.

[11] Peng W, Gou X, Qin H, et al. Creation of a multifunctional superhydrophobic coating for composite insulators[J]. Chemical Engineering Journal, 2018, 352: 774-781.

[12] Zylka P. Biomimetic surface-conducting silicone rubber obtained by physical deposition of MWCNT[J]. Smart Materials and Structures, 2015, 24(6): 065040.

[13] Tian H, Wang F, Ge S, et al. A simple and effective way to fabricate mechanical robust superhydrophobic surfaces[J]. RSC Advances, 2016, 6(34): 28563-28569.

[14] Sun J, Shi X, Du Y, et al. A robust, flexible superhydrophobic sheet fabricated by in situ growth of micro-nano-SiO 2 particles from cured silicone rubber[J]. Journal of Sol-Gel Science and Technology, 2019, 91(1): 208-215.

[15] Chen L, Wang X, Yang T, et al. Superhydrophobic micro-nano structures on silicone rubber by nanosecond laser processing[J]. Journal of Physics D: Applied Physics, 2018, 51(44): 445301.

[16] Roach P, Shirtcliffe N J, Newton M I. Progress in superhydrophobic surface development[J]. Soft Matte, 2008, 4(2): 224-240.

[17] He Q, Wang G, Zhang Y, et al. Thermo-oxidative ageing behavior of cerium oxide/silicone rubber[J]. Journal of Rare Earths, 2020, 38(4): 436-444.

[18] Han R, Wang Z, Zhang Y, et al. Thermal stability of CeO 2 /graphene/phenyl silicone rubber composites[J]. Polymer Testing, 2019, 75: 277-283.

[19] 曹小华 , 钟婵娟 , 穆晶 . H 6 P 2 W 18 O 62 /KH570-SiO 2 催化剂的制备、表征及催化合成乙酸正丁酯 [J]. 功能材料 , 2020, 51(8): 8117-8122.

相似文献/References:

[1]肖成龙,梁世雍,于兆勤*.可控阵列微柱超疏水表面实验研究[J].电镀与精饰,2020,(7):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
　XIAO Chenglong,LIANG Shiyong,YU Zhaoqin*.Experimental Study on Superhydrophobic Surface of Controllable Array Microcolumns[J].Plating & Finishing,2020,(10):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
[2]陈宇威,魏长伟,罗洪秦,等. 基于方波交流极化制备彩色超疏水不锈钢表面的研究 [J].电镀与精饰,2022,(9):25.[doi:10.3969/j.issn.1001-3849.2022.09.005]
　CHEN Yuwei,WEI Changwei,LUO Hongqin,et al.Preparation of Colored Superhydrophobic Stainless Steel Surface Based on Square-Wave AC Polarization[J].Plating & Finishing,2022,(10):25.[doi:10.3969/j.issn.1001-3849.2022.09.005]
[3]张 婷*,宋健民.聚谷氨酸修饰BN对BN@聚谷氨酸/硅橡胶复合材料性能的影响研究[J].电镀与精饰,2023,(3):45.[doi:10.3969/j.issn.1001-3849.2023.03.007]
　Zhang Ting*,Song Jianmin.Effect of polyglutamic acid modified BN on properties of BN@polyglutamic acid/silicone rubber composites[J].Plating & Finishing,2023,(10):45.[doi:10.3969/j.issn.1001-3849.2023.03.007]
[4]刘井坤,欧阳义波,段体岗,等.复合流体涂层用于Cu金属的防腐蚀研究[J].电镀与精饰,2023,(11):46.[doi:10.3969/j.issn.1001-3849.2023.11.007]
　Liu Jingkun,Ouyang Yibo,et al.Compositing fluid infused surface on Cu for corrosion inhibition[J].Plating & Finishing,2023,(10):46.[doi:10.3969/j.issn.1001-3849.2023.11.007]
[5]余金桂*,阮赣江,章桥新.基于碳纳米管涂装的超疏水表面及性能研究[J].电镀与精饰,2024,(6):78.[doi:10.3969/j.issn.1001-3849.2024.06.011]
　Yu Jingui*,Ruan Ganjiang,Zhang Qiaoxin.Study on superhydrophobic surface and properties based on carbon nanotube coating[J].Plating & Finishing,2024,(10):78.[doi:10.3969/j.issn.1001-3849.2024.06.011]
[6]刘季润,魏寅莎,欧阳义波,等.doi: 10.3969/j.issn.1001-3849.2025.07.005铝表面一步法电沉积制备超疏水涂层及防腐蚀研究[J].电镀与精饰,2025,(07):29.
　Liu Jirun,Wei Yinsha,Ouyang Yibo,et al.Preparation of superhydrophobic coating and its corrosion resistance on aluminum surface by one-step electrodeposition[J].Plating & Finishing,2025,(10):29.
[7]朱耿增,杜宝帅,姜 波,等.doi: 10.3969/j.issn.1001-3849.2025.10.012喷涂工艺对超疏水涂层性能的影响[J].电镀与精饰,2025,(10):83.
　Fan Zhibin,Zhang Bangwen.Effect of spraying process on properties of superhydrophobic coatings Zhu Gengzeng1,2,3, Du Baoshuai1,3, Jiang Bo1,3, Zhang Bingliang1,3,[J].Plating & Finishing,2025,(10):83.
[8]徐 洋,李 珂,刘季润,等.doi: 10.3969/j.issn.1001-3849.2026.03.001电沉积技术在金属表面构建防腐蚀超疏水涂层研究进展[J].电镀与精饰,2026,(03):1.
　XU Yang,LI Ke,LIU Jirun,et al.Research progress on anticorrosion of superhydrophobic coatings on metal surfaces using electrodeposition technology[J].Plating & Finishing,2026,(10):1.

备注/Memo

备注/Memo:
收稿日期： 2022-12-06 修回日期： 2023-03-01 * 通信作者： 谭鑫（ 1995 —），男，硕士研究生， email ： 2252341327@qq.com
更新日期/Last Update: 2023-10-07