Xu Jingcai *.Comprehensive experimental teaching design on the preparation and magnetic reversal mechanism of magnetic nanowire array by electrochemical deposition method[J].Plating & Finishing,2023,(12):116-123.[doi:doi ： 10.3969/j.issn.1001-3849.2023.12.017]
电化学沉积制备磁纳米线阵列及磁反转机制综合实验教学设计
- Title:
- Comprehensive experimental teaching design on the preparation and magnetic reversal mechanism of magnetic nanowire array by electrochemical deposition method
- Keywords:
- magnetic nanoarrays ; electrochemical deposition ; first-order reversal curve ; comprehensive experiment ; teaching design
- 分类号:
- TQ153.2
- 文献标志码:
- A
- 摘要:
- 为提升材料科学与工程专业和材料化学专业本科生结构功能一体化材料设计能力，设计了“电化学沉积制备磁纳米线阵列及磁反转机制”综合性研究实验。实验过程涵盖了电化学制备、微结构表征、磁性能测试，以及利用 FORCs 技术分析磁反转机制等知识。该实验设计通过多维度、多层次设计实验内容和科研全流程模拟，可提升学生的现场实验操作技能和实验设计能力，帮助学生深入了解材料电化学制备及其磁学性质，掌握相关仪器的操作，提升分析实验数据和解决问题的能力，有助于学生科学素养的养成。
- Abstract:
- ： To enhance the integrated material design ability of undergraduate students in the fields of materials science and engineering and materials chemistry ， a comprehensive experiment titled “ Electrochemical deposition for preparation of magnetic nanowire arrays and their magnetic reversal mechanism ” is designed. The experiment covers knowledge of electrochemical preparation ， microstructure characterization ， magnetic property testing and the magnetic reversal mechanisms analyzed by the first-order reversal curve （ FORCs ） . The multi-dimensional and multi-level experimental design and the simulation of the whole process of scientific research can improve experimental operation skills and design capabilities of students ， especially in the field of electrochemical deposition of magnetic nanowire array materials. It can help students to deeply understand the electrochemical preparation of materials and their magnetic properties ， master the operation of relevant instruments ， improve the ability to analyze experimental data and solve problems ， and help them develop scientific literacy.
参考文献/References:
[1] 韩秀峰 , 王丽 , 郭春生 . 高等学校实践育人存在的问题及对策探究 [J]. 高教学刊 , 2023, 9(13): 163-166.
[2] 张强 , 孙艳艳 , 马肃 , 等 . 地方高校应用化学综合实验课程教学改革实践 [J]. 河南化工 , 2023, 40(2): 60-62.
[3] 卜路霞 , 廉文静 , 尹立辉 , 等 . 应用型人才培养模式下电化学分析技术的教学研究 [J]. 电镀与精饰 , 2022, 44(9): 97-100.
[4] 李菲晖 , 巩运兰 , 高镜涵 , 等 . 基于创新人才培养机制的电化学实验课程改革初探 [J]. 电镀与精饰 , 2021, 43(4): 52-54.
[5] 陈冠锋 , 彭金奇 . 思政元素融入高校材料科学课程的路径研究 [J]. 材料保护 , 2021, 54(3): 52-54.
[6] Kwak M, Han L, Chen J J, et al. Interfacing inorganic nanowire arrays and living cells for cellular function analysis[J]. Small, 2015, 11(42): 5600-5610.
[7] Piraux L. Magnetic nanowires[J]. Applied Sciences-basel, 2020, 10(5): 1832.
[8] 孟香茗 , 宋振兴 , 卜路霞 , 等 . 电沉积法制备纳米线阵列的研究进展 [J]. 电镀与精饰 , 2021, 43(6): 35-40.
[9] 姜永军 , 许刚茜 , 刘学杰 , 等 . AAO 模板快速制备方法探究 [J]. 材料保护 , 2019, 52(5): 97-101.
[10] 袁新国 , 彭乔 . 多孔阳极氧化铝模板法交流电沉积单晶镍纳米线阵列 [J]. 材料保护 , 2011, 44(8): 1-3.
[11] Jani A M M, Habiballah A S, Halim M Z B A. Nanoporous anodic aluminum oxide (NAAO) for catalytic, biosensing and template synthesis applications (A review)[J]. Current Nanoscience, 2019, 15(1): 49-63.
[12] 孙小彤 , 陈南 , 梁含雪 , 等 . 阳极氧化铝模板限域制备一维杂化纳米材料及其多样化应用的研究进展 [J]. 应用化学 , 2020, 37(2): 123-133.
[13] Kashi M A, Montazer A H. Template-based electrodeposited nonmagnetic and magnetic metal nanowire arrays as building blocks of future nanoscale applications[J]. Journal of Physics D-Applied Physics, 2022, 55(23): 233002.
[14] Vivas L G, Vazquez M, Escrig J, et al. Magnetic anisotropy in CoNi nanowire arrays: Analytical calculations and experiments[J]. Physical Review B, 2012, 85(3): 035439.
[15] Lederman M, Schultz S, Ozaki M. Measurement of the dynamics of the magnetization reveral in individual single domain ferromagnetic particles[J]. Physical Review Letters, 1994, 73(14): 1986-1989.
[16] Alikhani M, Ramazani A, AlmasiKashi M, et al. Irreversible evolution of angular-dependent coercivity in Fe 80 Ni 20 nanowire arrays: Detection of a single vortex state[J]. Journal of Magnetism and Magnetic Materials, 2016, 414: 158-167.
[17] Proenca M P, Sousa C T, Ventura J, et al. Identifying weakly-interacting single domain states in Ni nanowire arrays by FORC[J]. Journal of Alloys and Compounds, 2017, 699: 421-429.
[18] Xu J C, Wang J, Hong B, et al. Growth and magnetic interaction of single crystalline Ni gradient-diameter magnetic nanowire arrays[J]. Journal of Materials Science, 2019, 54(17): 11538-11545.
[19] Xu J C, Zhang J, Wang J, et al. Effects of gradient diameter on magnetic properties of FeNi alloys nanowires arrays[J]. Journal of Magnetism and Magnetic Materials, 2020, 499: 166207.
[20] Xu J C, Hong B, Peng X L, et al. Preparation and magnetic properties of gradient diameter FeCoNi alloysnanowires arrays[J]. Chemical Physics Letters, 2021, 767: 138368.
[21] 徐靖才 . 具有梯度直径的 Ni 基磁纳米有序阵列的制备及磁性能研究 [D]. 杭州 : 浙江工业大学 , 2021.
[22] Schlesinger M, Paunovic M. Modern Electroplating[M].Wiley, New York, 2000.
[23] 阴津华 , Hee C H, 潘礼庆 . 反铁磁耦合记录介质的一级翻转曲线 [J]. 物理学报 , 2008, 57(11): 7287-7291.
[24] 秦华峰 , 刘青松 , 潘永信 . 一阶反转曲线 (FORC) 图的原理及应用实例 [J]. 地球物理学报 , 2008, 51(3): 743-751.
[25] Wernsdorfer W, Doudin B, Mailly D, et al. Nucleation of magnetization reversal in individual nanosized nickel wires[J]. Physical Review Letters, 1996, 77(9): 1873-1876.
[26] Proenca M P, Ventura J, Sousa C T, et al. Angular first-order reversal curves: an advanced method to extract magnetization reversal mechanisms and quantify magnetostatic interactions[J]. Journal of Physics-condensed Matter, 2014, 26(11): 116004.
相似文献/References:
[1]张雪娜,冯贝贝,索文华,等.电沉积法制备Ni-GO复合镀层的工艺及力学性能研究[J].电镀与精饰,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.08.0010]
ZHANG Xuena,FENG Beibei,SUO Wenhua,et al.Study on the Process and Mechanical Properties of Ni-GO Composite Coating Prepared by Electrodeposition[J].Plating & Finishing,2020,(12):1.[doi:10.3969/j.issn.1001-3849.2020.08.0010]
[2]叶成茁,丁运虎*,毛祖国,等.光纤腐蚀传感器Fe-C薄膜电沉积工艺研究[J].电镀与精饰,2023,(2):49.[doi:10.3969/j.issn.1001-3849.2023.02.008]
Ye Chengzhuo,Ding Yunhu*,Mao Zuguo,et al.Electrodeposition process of Fe-C film for fiber optic corrosion sensor[J].Plating & Finishing,2023,(12):49.[doi:10.3969/j.issn.1001-3849.2023.02.008]
[3]王明明,徐子轩,王守豪,等.电化学镀镍层的润湿性能研究[J].电镀与精饰,2023,(7):26.[doi:10.3969/j.issn.1001-3849.2023.07.004]
Wang Mingming,Xu Zixuan,Wang Shouhao,et al.Study on wetting properties of electrodeposited nickel coating[J].Plating & Finishing,2023,(12):26.[doi:10.3969/j.issn.1001-3849.2023.07.004]
[4]王智欣,高圆圆,高林君,等.基于半导体复合材料电解制氯用于海洋光学窗口防生物污损[J].电镀与精饰,2023,(7):43.[doi:10.3969/j.issn.1001-3849.2023.07.006]
Wang Zhixin,Gao Yuanyuan,Gao Linjun,et al.Study on anti-biofouling of ocean optical window based on electrolytic chlorination of semiconductor composites[J].Plating & Finishing,2023,(12):43.[doi:10.3969/j.issn.1001-3849.2023.07.006]
[5]刘敬春*,赵子晔,赵建国,等.AZ31B镁合金表面电化学沉积LDH涂层及其耐腐蚀性能研究[J].电镀与精饰,2024,(7):22.[doi:10.3969/j.issn.1001-3849.2024.07.004]
Liu Jingchun*,Zhao Ziye,Zhao Jianguo,et al.The corrosion resistance of LDH coatings constructed via electrodeposition technique on AZ31B[J].Plating & Finishing,2024,(12):22.[doi:10.3969/j.issn.1001-3849.2024.07.004]
[6]高吉成,程金晶,张 喆,等.稀土Ce对Ni-Co镀层组织与性能影响创新实验设计与教学实践[J].电镀与精饰,2024,(12):129.
Gao Jicheng*,Cheng Jinjing,Zhang Zhe,et al.Innovative experimental design and teaching practice of the effect of the rare earth Ce on the microstructure and properties of Ni-Co coatings[J].Plating & Finishing,2024,(12):129.
备注/Memo
收稿日期： 2023-04-21 修回日期： 2023-06-05 作者简介： 徐靖才（ 1987 —），男，博士，实验师， email ： xujingcai@cjlu.edu.cn 基金项目： 浙江省属高校基本科研业务费专项资金（ 2022YW37 ）