[1]刘元海,尹凤雷,慕仙莲,等.铜表面镍/银/铑复合镀层的制备及其耐腐蚀性研究?/div>[J].电镀与精饰,2024,(1):79-83.[doi:10.3969/j.issn.1001-3849.2024.01.012]
 Liu Yuanhai,Yin Fenglei,Mu Xianlian,et al.Preparation and corrosion resistance of Ni/Ag/Rh composite coatings on copper surface[J].Plating & Finishing,2024,(1):79-83.[doi:10.3969/j.issn.1001-3849.2024.01.012]
点击复制

铜表面镍/银/铑复合镀层的制备及其耐腐蚀性研究?/div>
()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2024年1
页码:
79-83
栏目:
出版日期:
2024-01-15

文章信息/Info

Title:
Preparation and corrosion resistance of Ni/Ag/Rh composite coatings on copper surface
作者:
(1.中国特种飞行器研究所,湖北 荆门 448000; 2.天津航空机电有限公司,天津 300308)
Author(s):
Liu Yuanhai 1 Yin Fenglei 1 Mu Xianlian 1 Xu Taotao 2* Qi Huaiwei 2
(1.China Institute of Special Air Vehicles, Jingmen 448000, China; 2.Tianjin Aviation
Electromechanical Co., Ltd., Tianjin 300308, China)

关键词:
复合镀层铑镀层耐蚀性电沉积
Keywords:
composite coating Rh coating corrosion resistance electrodeposition
分类号:
TQ153.1
DOI:
10.3969/j.issn.1001-3849.2024.01.012
文献标志码:
A
摘要:
采用化学镀和电沉积的方法在紫铜片上制备了镍 / 银 / 铑复合镀层。使用光学显微镜和扫描电子显微镜( SEM )观察镍 / 银 / 铑复合镀层的微观结构;通过 X 射线能谱分析( EDS )检查镀层的化学组成;采用 X 射线衍射仪器( XRD )表征镀层的相结构和晶体结构;利用酸性盐雾实验测试了不同镍镀层厚度的镍 / 银 / 铑复合镀层在盐雾环境下的耐蚀性能。结果表明:各镀层之间结合紧密,镀层表面平整无孔隙;在其它条件相同的情况下,镍镀层厚的复合镀层的耐蚀性优于镍镀层薄的复合镀层。
Abstract:
: Ni/Ag/Rh composite coatings were prepared on copper sheets by means of electroless plating and electrodeposition. The microstructure of Ni/Ag/Rh composite coating was observed by optical microscope and scanning electron microscope ( SEM ) . The chemical composition of the coating was checked by energy-dispersive X-ray spectroscopy ( EDS ) . The phase structure and crystal structure of the coating was characterized by X-ray diffraction instrument ( XRD ) . The corrosion resistance of Ni/Ag/Rh composite coatings with different nickel coating thicknesses in salt spray environments was tested using acidic salt spray experiments. The results show that the bonding between the coatings is tight , and the surface of the coatings is flat without pores. Under the same other conditions , the corrosion resistance of composite coatings with thick nickel coatings is better than that of composite coatings with thin nickel coatings.

参考文献/References:



[1] Weisberg A M. Rhodium plating[J]. Metal Finishing, 1999, 97(1): 292-296.

[2] 李一冉 , 姚力筝 , 董梓凝 , 等 . " 铑 " 有所 " 铱 "[J]. 大学化学 , 2021, 36(10): 23-27.

[3] 唐萌圣 . 电沉积贵金属铑 [J]. 材料保护 , 1998, 31(4): 19.

[4] Golvano-Escobal I, Surinach S, Baró M D, et al. Electrodeposition of sizeable and compositionally tunable rhodium-iron nanoparticles and their activity toward hydrogen evolution reaction[J]. Electrochimica Acta, 2016, 194: 263-275.

[5] Sathe B R. High aspect ratio rhodium nanostructures for tunable electrocatalytic performance[J]. Physical Chemistry Chemical Physics, 2013, 15(20): 7866-7872.

[6] 肖耀坤 , 钟美娥 , 张峰 , 等 . 铑电镀工艺的研究现状与展望 [J]. 材料保护 , 2005, 38(2): 37-40.

[7] 杨富国 . 不锈钢件镀铑工艺 [J]. 表面技术 , 2000, 29(6): 48-49.

[8] Abys J A, Dullaghan C A, Epstein P, et al. Rhodium sulfate compounds and rhodium plating: U.S. Patent 6,241,870[P]. 2001-6-5.

[9] Angus H C. Electrodeposition of rhodium and ruthenium for slip-ring surfaces[J]. Transactions of the IMF, 2017, 43(1): 135-142.

[10] Son S H, Lee H K, Park S C. Kinetics of rhodium electrodeposition for semiconductor interconnect applications[J]. Surface and Interface Analysis, 2010, 42(6‐7): 1244-1246.

[11] Wu W P, Liu J W, Zhang Y, et al. The influence of current density and bath temperature on electrodeposition of rhodium film from sulfate-phosphate aqueous solutions[J]. Journal of Applied Electrochemistry, 2019, 49(10): 1043-1054.

[12] 肖耀坤 , 张峰 , 王旭辉 , 等 . 不同基材上装饰性镀铑的电化学行为及镀层性能 [J]. 中国有色金属学报 , 2005, 15(2): 305-309.

[13] 孙金虎 , 李辉 , 钟庆东 , 等 . 镍 / 铜 / 锌多层镀层的制备及其耐蚀性 [J]. 腐蚀与防护 , 2017, 38(12): 928-932.

[14] 王建兴 , 黄少军 , 唐伦圆 , 等 . 镍 - 钴 / 镍 / 镍 - 钴镀层的制备及电化学性能 [J]. 材料保护 , 2012, 45(9): 17-20.

[15] Aliofkhazraei M, Walsh F C, Zangari G, et al. Development of electrodeposited multilayer coatings: A review of fabrication, microstructure, properties and applications[J]. Applied Surface Science Advances, 2021, 6: 100141.

[16] Khadem M, Penkov O V, Yang H K, et al. Tribology of multilayer coatings for wear reduction: A review[J]. Friction, 2017, 5(3): 248-262.

[17] 顾卓明 , 黄婉娟 . 耐磨复合镀层工艺的研究 [J]. 表面技术 , 2002(2): 14-17.

[18] 徐欣 , 李庆明 , 刘兴民 , 等 . 镍 - 金刚石复合镀层的制备工艺及耐磨性比较 [J]. 金属功能材料 , 2022, 29(1): 100-105.

[19] 杨奎 . 工艺参数对电沉积 Ni-Fe-SiC 复合镀层耐磨、耐蚀性能的影响 [D]. 长春 : 长春工业大学 , 2022.

[20] 顾卓明 , 黄婉娟 , 王仁兵 . 多层复合镀层工艺与性能的研究 [J]. 机械工程材料 , 2002, 26(10): 26-29.

[21] 费敬银 , 刘江宏 , 梁国正 , 等 . 电沉积法制备组分调制 Zn-Ni 合金多层镀层 [J]. 腐蚀科学与防护技术 , 2006, 18(1): 24-27.

相似文献/References:

[1]沈岳军*,罗华江,王少营,等.温度对Ni-P/PTFE复合镀层性能的影响[J].电镀与精饰,2019,(8):1.[doi:10.3969/j.issn.1001-3849.2019.08.001]
 SHEN Yuejun*,LUO Huajiang,WANG Shaoying,et al.Effect of Temperature on the Properties of Ni-P/PTFE Composite Coating[J].Plating & Finishing,2019,(1):1.[doi:10.3969/j.issn.1001-3849.2019.08.001]
[2]王晓丽,顾海,赵紫怡,等.电沉积金属基复合镀层制备研究进展[J].电镀与精饰,2021,(8):44.[doi:10.3969/j.issn.1001-3849.2021.08.010]
 WANG Xiaoli,GU Hai,ZHAO Ziyi,et al.Research Progress of Fabricating Metal-Matrix Composite Coating by Electrodeposition[J].Plating & Finishing,2021,(1):44.[doi:10.3969/j.issn.1001-3849.2021.08.010]
[3]赵金国*,乔 勋,阎治安.热处理对Ni-P-BN(h)镀层硬度和自润滑性能的影响[J].电镀与精饰,2022,(1):63.[doi:10.3969/j.issn.1001-3849.2022.01.011]
 ZHAO Jinguo*,QIAO Xun,YAN Zhian.Effect of Heat Treatment on Hardness and Self-Lubrication of Ni-P-BN(h) Composite Coating[J].Plating & Finishing,2022,(1):63.[doi:10.3969/j.issn.1001-3849.2022.01.011]
[4]孙 伟,张淑婷*,杜开平,等.汽油机活塞顶面镀层的设计与仿真研究[J].电镀与精饰,2023,(2):79.[doi:10.3969/j.issn.1001-3849.2023.02.013]
 Sun Wei,Zhang Shuting*,Du Kaiping,et al.Design and simulation research of electroplated coating on piston top of gasoline engine[J].Plating & Finishing,2023,(1):79.[doi:10.3969/j.issn.1001-3849.2023.02.013]
[5]姚伦芳,杨 强,刘定富*.纳米Al2O3颗粒掺杂对化学镀Ni-Cu-P镀层耐蚀性的影响[J].电镀与精饰,2023,(11):27.[doi:10.3969/j.issn.1001-3849.2023.11.004]
 Yao Lunfang,Yang Qiang,Liu Dingfu*.Effect of nano-Al 2 O 3 doping on corrosion resistance of electroless Ni-Cu-P coating[J].Plating & Finishing,2023,(1):27.[doi:10.3969/j.issn.1001-3849.2023.11.004]
[6]周 鑫,王晓丽*,皇 磊,等.喷射复合电沉积技术研究进展[J].电镀与精饰,2024,(1):55.[doi:10.3969/j.issn.1001-3849.2024.01.009]
 Zhou Xin,Wang Xiaoli*,Huang Lei,et al.Research progress of jet composite electrodeposition technology[J].Plating & Finishing,2024,(1):55.[doi:10.3969/j.issn.1001-3849.2024.01.009]
[7]杜丹丹,田晓东*,卢嘉成.铝合金表面Ni-SiC-CaF2复合镀层的组织和性能研究[J].电镀与精饰,2024,(10):16.
 Du Dandan,Tian Xiaodong,Lu Jiacheng.Microstructure and properties of Ni-SiC-CaF2 composite coatings on aluminum alloy surface[J].Plating & Finishing,2024,(1):16.
[8]张颖超.doi: 10.3969/j.issn.1001-3849.2026.03.005室内单晶硅装饰电镀涂层材料的制备及其性能[J].电镀与精饰,2026,(03):35.
 ZHANG Yingchao.Preparation and performance of indoor monocrystalline silicon decorative electroplating coating materials[J].Plating & Finishing,2026,(1):35.

备注/Memo

备注/Memo:
收稿日期: 2023-08-31 修回日期: 2023-09-26 作者简介: 刘元海( 1981 ―),男,硕士,研究员, email : liuyuanhai100@163.com * 通信作者: 徐涛涛, email : xutaotao105@126.com?/html>
更新日期/Last Update: 2024-01-07