[1]邹豪君,韩兴威,顾广年,等.doi: 10.3969/j.issn.1001-3849.2025.08.001壳聚糖/氧化石墨烯吸附剂的制备及性能研究[J].电镀与精饰,2025,(08):1-8.
　Zou Haojun,Han Xingwei*,Gu Guangnian,et al.Preparation and performance of chitosan/graphene oxide adsorbent[J].Plating & Finishing,2025,(08):1-8.
点击复制

doi: 10.3969/j.issn.1001-3849.2025.08.001壳聚糖/氧化石墨烯吸附剂的制备及性能研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年08
页码:
1-8
栏目:
出版日期:
2025-08-31

文章信息/Info

Title:
Preparation and performance of chitosan/graphene oxide adsorbent
作者:
邹豪君1; 韩兴威1; 顾广年2; 陆 冲1; 高 雪1; 王斯佳1
(1. 沈阳理工大学 环境与化学工程学院,辽宁 沈阳 110159 ;2. 力拓(肥料)
Author(s):
Zou Haojun1;  Han Xingwei1*;  Gu Guangnian2;  Lu Chong1;  Gao Xue1;  Wang Sijia1
(1. School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110159, China; 2. Rio Tino Fertilizer (Shenyang) Co., Ltd., Shenyang 110122, China)
关键词:
壳聚糖; 氧化石墨烯; 镍离子; 吸附
Keywords:
chitosan;  graphene oxide;  nickel ions;  adsorption
分类号:
TQ323.5，TQ424
文献标志码:
A
摘要:
为了解决电镀废液中广泛存在的金属镍离子(Ni2+)污染大、回收难的问题，采用共混法设计合成了壳聚糖/氧化石墨烯(CS/GO)复合材料，再通过离子印迹技术制得CS/GO Ni2+印迹复合材料。研究了振荡时间、初始浓度、pH值和共存离子等因素对CS/GO吸附Ni2+的性能的影响。结果表明，CS/GO复合材料在溶液pH为6，振荡时间为100 min，Ni2+初始浓度为300 mg·L?1的条件下的吸附效果较好。CS/GO复合材料吸附Ni2+的过程符合拟二级动力学模型和Langmuir模型，其对Ni2+的最大吸附量可以达到1 002.665 0 mg·g?1，经过5次的吸附-脱附试验后，吸附量是第一次吸附量的92.15%，仍保持优异的吸附性能。
Abstract:
In order to address the issue of elevated pollution levels and the challenging recovery of nickel metal ions (Ni2+) present in significant quantities in electroplating waste solutions, chitosan/graphene oxide (CS/GO) composites were designed and synthesized using a blending method, in which CS/GO Ni2+ imprinted composites were made by ion-imprinting technique. The impact of oscillation time, initial concentration, pH and coexisting ions on the efficacy of CS/GO for Ni?? adsorption was examined. The results showed that excellent adsorption performance of CS/GO composite material was obtained under the conditions of solution pH 6, oscillation time of 100 min, and initial concentration of Ni 2+of 300 mg·L?1. The adsorption process of Ni2+ by CS/GO composites conformed to the pseudo-second-order kinetic model and Langmuir model, and its maximum adsorption capacity for Ni 2+ can reach 1 002.665 0 mg·g ?1. After five cycles of adsorption-desorption tests, the adsorption capacity was 92.15% of the first cycle, and the excellent adsorption performance was still maintained

参考文献/References:

[1].彭彬, 孙超. 热氧化法处理含镍电镀废水的工艺研究[J]. 电镀与精饰, 2023, 45(11): 40-45.
[2].傅明连, 高果, 陈彰旭, 等. Fe3O4@SiO2@CTS镍离子印迹聚合物的制备与吸附性能研究[J]. 化学研究与应用, 2023, 35(3): 614-619.
[3].Tsai T H, Chou H W, Wu Y F. Removal of nickel from chemical plating waste solution through precipitation and production of microsized nickel hydroxide particles[J]. Separation and Purification Technology, 2020, 251: 117315.
[4].雷军鹏, 金鑫, 王紫燕. 离子交换法从硫酸亚铁溶液中分离镍实验研究[J]. 有色金属工程, 2024, 14(6): 62-67.
[5].贺框, 杜建伟, 马英, 等. 膜分离技术在化学镀镍清洗水回用中的应用[J]. 电镀与涂饰, 2017, 36(11): 587-593.
[6].Jin W, Zhang Y. Sustainable electrochemical extraction of metal resources from waste streams: From removal to recovery[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(12): 4693-4707.
[7].Qin H Q, Hu T J, Zhai Y B, et al. The improved methods of heavy metals removal by biosorbents: A review[J]. Environmental Pollution, 2020, 258: 113777.
[8].Salih S S, Shihab M A, Mohammed H N, et al. Chitosan-vermiculite composite adsorbent: Preparation, characterization, and competitive adsorption of Cu (II) and Cd (II) ions[J]. Journal of Water Process Engineering, 2024, 59: 105044.
[9].Begum S, Yuhana N Y, Saleh N M, et al. Review of chitosan composite as a heavy metal adsorbent: Material preparation and properties[J]. Carbohydrate Polymers, 2021, 259: 117613.
[10].Rahaman M H, Islam M A, Islam M M, et al. Biodegradable composite adsorbent of modified cellulose and chitosan to remove heavy metal ions from aqueous solution[J]. Current Research in Green and Sustainable Chemistry, 2021, 4(4): 100119.
[11].Okura N S, Sabi G J, Crivellenti M C, et al. Improved immobilization of lipase from Thermomyces lanuginosus on a new chitosan-based heterofunctional support: Mixed ion exchange plus hydrophobic interactions[J]. International Journal of Biological Macromolecules, 2020, 163: 550-561.
[12].中国环境监测总站. GB/T 11910—1989, 水质镍的测定 丁二酮肟分光光度法[S]. 北京: 中国标准出版社, 1989.
[13].Le T T N, Le V T, Dao M U, et al. Preparation of magnetic graphene oxide/chitosan composite beads for effective removal of heavy metals and dyes from aqueous solutions[J]. Chemical Engineering Communications, 2019, 206(10): 1337-1352.
[14].Lima E C, Hosseini-Bandegharaei A, Moreno-Piraján J C, et al. A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van’t Hoof equation for calculation of thermodynamic parameters of adsorption[J]. Journal of Molecular Liquids, 2019, 273: 425-434.
[15].Falyouna O, Bensaida K, Maamoun I, et al. Synthesis of hybrid magnesium hydroxide/magnesium oxide nanorods [Mg (OH)2/MGO] for prompt and efficient adsorption of ciprofloxacin from aqueous solutions[J]. Journal of Cleaner Production, 2022, 342: 130949.
[16].Jia M, Wang F, Bian Y, et al. Sorption of sulfamethazine to biochars as affected by dissolved organic matters of different origin[J]. Bioresource Technology, 2018, 248: 36-43.
[17].Yang X, Wu P, Chu W, et al. Peroxymonosulfate/LaCoO3 system for tetracycline degradation: Performance and effects of co-existing inorganic anions and natural organic matter[J]. Journal of Water Process Engineering, 2021, 43: 102231.
[18].Jiang J, Jiang X, Zou Y, et al. Facile synthesis of acid catalyzed sulfonic acid-amide functionalized magnetic sodium alginate and its efficient adsorption for ciprofloxacin and moxifloxacin[J]. Journal of Cleaner Production, 2023, 391: 136122.
[19].Kunoh T, Yamamoto T, Sugimoto S, et al. Leptothrixcholodnii response to nutrient limitation[J]. Frontiers in Microbiology, 2021, 12: 691563.
[20].Yang P, Yu F, Yang Z, et al. Graphene oxide modified κ-carrageenan/sodium alginate double-network hydrogel for effective adsorption of antibiotics in a batch and fixed-bed column system[J]. Science of the Total Environment, 2022, 837: 155662.
[21].Puccia V, Avena M J. On the use of the Dubinin-Radushkevich equation to distinguish between physical and chemical adsorption at the solid-water interface[J]. Colloid and Interface Science Communications, 2021, 41: 100376.
[22].Salih S S, Ghosh T K. Highly efficient competitive removal of Pb(II) and Ni(II) by chitosan/diatomaceous earth composite[J]. Journal of Environmental Chemical Engineering, 2018, 6(1): 435-443.
[23].Xiao Y, Ma C, Jin Z, et al. Functional covalent organic framework for exceptional Fe2+, Co2+ and Ni 2+ removal: An upcycling strategy to achieve water decontamination and reutilization as smoke suppressant and flame retardant simultaneously[J]. Chemical Engineering Journal, 2021, 421: 127837.
[24].He Y, Gou S, Zhou L, et al. Amidoxime-functionalized polyacrylamide-modified chitosan containing imidazoline groups for effective removal of Cu2+ and Ni 2+[J]. Carbohydrate Polymers, 2021, 252: 117160.
[25].Sahebjamee N, Soltanieh M, Mousavi S M, et al. Removal of Cu2+, Cd2+ and Ni 2+ ions from aqueous solution using a novel chitosan/polyvinyl alcohol adsorptive membrane[J]. Carbohydrate Polymers, 2019, 210: 264-273.
[26].樊红日, 梁兴唐, 何紫莹, 等. 羧甲基纤维素/聚乙烯亚胺气凝胶对Ni(Ⅱ)的吸附性能研究[J]. 化工新型材料, 2023, 51(12): 207-211, 217.
[27].Peng G, Deng S, Liu F, et al. Superhigh adsorption of nickel from electroplating wastewater by raw and calcined electroplating sludge waste[J]. Journal of Cleaner Production, 2020, 246: 118948.
[28].Zhao S, Meng Z, Fan X, et al. Removal of heavy metals from soil by vermiculite supported layered double hydroxides with three-dimensional hierarchical structure[J]. Chemical Engineering Journal, 2020, 390: 124554.
[29].单凤君,张婷婷,王双红. 氧化石墨烯/海藻酸钠复合材料对Ni2+的吸附特性研究[J]. 化工新型材料, 2020, 48(10): 206-210.

相似文献/References:

[1]何 睿,许艳玲*,曾希野,等.氧化石墨烯/四氧化三铁磁性复合材料对Cr(VI)的吸附研究[J].电镀与精饰,2019,(9):1.[doi:10.3969/j.issn.1001-3849.2019.09.001]
　HE Rui,XU Yanling*,ZENG Xiye,et al.Study on Adsorption Behavior of Cr(VI) by Graphene Oxide/Ferrous Oxide Magnetic Composites[J].Plating & Finishing,2019,(08):1.[doi:10.3969/j.issn.1001-3849.2019.09.001]
[2]李丽君,卜路霞*,刘树彬,等.不同表面活性剂对氧化石墨烯分散性的影响[J].电镀与精饰,2020,(6):23.[doi:10.3969/j.issn.1001-3849.2020.06.0050]
　LI Lijun,BU Luxia*,LIU Shubin,et al.Effects of Different Surfactants on Dispersibility of Graphene Oxide[J].Plating & Finishing,2020,(08):23.[doi:10.3969/j.issn.1001-3849.2020.06.0050]
[3]张雪娜,冯贝贝,索文华,等.电沉积法制备Ni-GO复合镀层的工艺及力学性能研究[J].电镀与精饰,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.08.0010]
　ZHANG Xuena,FENG Beibei,SUO Wenhua,et al.Study on the Process and Mechanical Properties of Ni-GO Composite Coating Prepared by Electrodeposition[J].Plating & Finishing,2020,(08):1.[doi:10.3969/j.issn.1001-3849.2020.08.0010]
[4]杨 明,陈国美,倪自丰*,等.40Cr基体表面GO/BTESPT硅烷复合膜的制备和性能表征[J].电镀与精饰,2020,(9):16.
　YANG Ming,CHEN Guomei,NI Zifeng*,et al.Preparation and Characterization of GO/BTESPT Silane Composite Film on 40Cr Substrate[J].Plating & Finishing,2020,(08):16.
[5]孙林静,毕韶丹*,韩兴威.纤维素/壳聚糖复合微球的制备及对铜（Ⅱ）的吸附性能研究[J].电镀与精饰,2022,(5):21.[doi:doi： 10.3969/j.issn.1001-3849.2022.05.004]
　SUN Linjing,BI Shaodan*,HAN Xingwei.Preparation of Cellulose/Chitosan Composite Cicrospheres and Its Adsorption Properties for Copper （Ⅱ）[J].Plating & Finishing,2022,(08):21.[doi:doi： 10.3969/j.issn.1001-3849.2022.05.004]
[6]赵佐平 *,屈凯静,胡思雨,等. 壳聚糖活性污泥复合吸附剂对含锰、镍废水处理的研究 [J].电镀与精饰,2022,(8):51.[doi:10.3969/j.issn.1001-3849.2022.08.009]
　ZHAO Zuoping *,QU Kaijing,HU Siyu,et al.Study on the Treatment of Manganese and Nickel Wastewater with Chitosan Activated Sludge Composite Adsorbent?/html>[J].Plating & Finishing,2022,(08):51.[doi:10.3969/j.issn.1001-3849.2022.08.009]
[7]纪 茜,刘 伟*,肖天铸,等.镁合金表面MgF2/Mg-MOF-74@壳聚糖涂层的制备及性能[J].电镀与精饰,2023,(11):32.[doi:10.3969/j.issn.1001-3849.2023.11.005]
　Ji Qian,Liu Wei*,Xiao Tianzhu,et al.Preparation and properties of MgF 2 /Mg-MOF-74@chitosan composite coatings on magnesium alloy[J].Plating & Finishing,2023,(08):32.[doi:10.3969/j.issn.1001-3849.2023.11.005]
[8]刘 凯,沈喜训 *,马 祥,等.氧化石墨烯强化银镀层的耐蚀性和耐磨性研究[J].电镀与精饰,2024,(5):11.[doi:10.3969/j.issn.1001-3849.2024.05.002]
　Liu Kai,Shen Xixun *,Ma Xiang,et al.Study on corrosion resistance and wear resistance of silver coatings strengthened by graphene oxide[J].Plating & Finishing,2024,(08):11.[doi:10.3969/j.issn.1001-3849.2024.05.002]
[9]侯攀超,杨 玥,周景淼,等.ZnO/GO复合薄膜电极的制备及其耐腐蚀性能[J].电镀与精饰,2024,(10):50.
　Hou Panchao,Yang Yue,Zhou Jingmiao,et al.Preparation and corrosion resistance of ZnO/GO composite thin film electrodes[J].Plating & Finishing,2024,(08):50.
[10]李孝坤雷鸣科 黄 帅.doi: 10.3969/j.issn.1001-3849.2025.02.001烧结钕铁硼电沉积Co-Mo-P/GO复合镀层及耐蚀性研究[J].电镀与精饰,2025,(02):1.
　Li Xiaokun*,Lei Mingke,Huang Shuai.Electrodeposition of Co-Mo-P/GO composite coating on sintered NdFeB and its corrosion resistance[J].Plating & Finishing,2025,(08):1.

更新日期/Last Update: 2025-08-11