CAO Qi,HUANG Congyun,HUANG Guosheng*,et al.Comparative Study on the Characteristics of Fe-Based Amorphous Coatings for Cold Spraying and Plasma Spraying[J].Plating & Finishing,2020,(5):1-12.[doi:10.3969/j.issn.1001-3849.2020.05.0010]
冷喷涂和等离子喷涂Fe基非晶涂层特征对比研究
- Title:
- Comparative Study on the Characteristics of Fe-Based Amorphous Coatings for Cold Spraying and Plasma Spraying
- Keywords:
- Fe-based amorphous coating cold spraying plasma spraying heat treatment mechanical properties
- 文献标志码:
- A
- 摘要:
- 采用传统热喷涂方法制备非晶涂层存在晶化度高和孔隙率高两个主要缺点,而新兴的冷喷涂技术具有解决这两个缺点的潜力。本文通过对比等离子喷涂和冷喷涂铁基非晶涂层的性能特征,探讨冷喷涂技术在非晶涂层应用方面的可行性。研究表明,冷喷涂涂层中含有更高的非晶含量,氧化程度更低,且结合强度高达27 MPa。随着热处理温度的升高,冷喷涂涂层在700 ℃下开始发生晶化,不断析出晶化相,涂层变得更加致密,微观形貌中无裂纹出现,显微硬度由喷涂态的1150 HV增加到1400 HV。而等离子喷涂涂层在600 ℃就已经发生晶化,且有裂纹出现。因此,冷喷涂涂层的机械性能优于等离子喷涂涂层,冷喷涂涂层的整体性能更好,应用冷喷涂制备非晶合金涂层有更大的潜力。
- Abstract:
- The preparation of amorphous coatings by traditional thermal spraying method has two main shortcomings like high crystallization degree and porosity, and the new cold spraying technology has the potential to solve these two shortcomings. In this paper, the feasibility of cold spraying technology in the application of amorphous coatings is discussed by comparing the properties of plasma sprayed and cold sprayed iron based amorphous coatings. The results show that the cold sprayed coating contains higher amorphous content, lower oxidation degree and higher bonding strength of 27 MPa. With the increase of heat treatment temperature, the cold spraying coating began to crystallization at 700 ℃, and the crystallization phase was precipitated continuously, the coating became more compact, no cracks appeared in the micromorphology, and the microhardness increased from sprayed 1150 HV to 1400 HV. However, the plasma sprayed coating has been crystallized at 600 ℃, and cracks have appeared. Therefore, the mechanical properties of cold sprayed coatings are better than those of plasma sprayed coatings, and the overall properties of cold sprayed coatings are better than those of plasma sprayed coatings. The preparation of amorphous alloy coatings by cold spraying has greater potential.
参考文献/References:
[1] Yoon S, Kim J, Bae G, et al. Formation of coating and tribological behavior of kinetic sprayed Fe-based bulk metallic glass[J]. Journal of Alloys and Compounds, 2011, 509(2): 347-353.
[2] 胡壮麒, 张海峰. 块状非晶合金及其复合材料研究进展[J]. 金属学报, 2010, 46(11): 1391-1421.
Hu Z Q, Zhang H F. Recent progress in the area of bulk amorphous alloys and composites[J]. Acta Metalica Sinica, 2010, 46(11): 1391-1421 (in Chinese).
[3] 程江波, 梁秀兵, 徐滨士, 等. 铁基非晶纳米晶涂层组织及耐冲蚀性能的研究[J]. 稀有金属材料与工程, 2009, 38(12): 2141-2145.
Cheng J B, Liang X B, Xu B S, et al. Microstructure and erosion resistance of Fe-based amorphous/nan rystalline coatings[J]. Rare Metal Materials and Engineering, 2009, 38(12): 2141-2145 (in Chinese).
[4] 龚玉兵, 王善林, 柯黎明, 等. Fe基非晶合金涂层的研究进展[J]. 热加工工艺, 2017(10): 14-17.
Gong Y B, Wang S L, Ke L M, et al. Research progress of Fe-based amorphous alloy coatings[J]. Hot Working Technology, 2017(10): 14-17 (in Chinese).
[5] 马晓琳, 周勇, 刘玉栋. 热喷涂铁基非晶合金材料的研究进展[J]. 热处理技术与装备, 2015(4): 28-32.
Ma X L, Zhou Y, Liu Y D. Research progress of Fe-based amorphous alloy materials prepared by thermal spraying[J]. Heat Treatment Technology and Equipment, 2015(4): 28-32 (in Chinese).
[6] 韩烨, 朱胜利, 井上明久. 铁基软磁非晶合金和块状金属玻璃的研究进展[J]. 功能材料, 2016(3): 38-43.
Han Y, Zhu S L, Inoue A. The development of Fe-based soft magnetic amorphous and bulk metallic glassy alloys[J]. Journal of Functional Materials, 2016(3): 38-43 (in Chinese).
[7] 倪晓俊, 薄希辉, 赵新彬, 等. 等离子喷涂Fe-Co基非晶合金涂层的结构与电磁屏蔽性能[J]. 粉末冶金工业, 2018, 28(5): 50-54.
Ni X J, Bo X H, Zhao X B, et al. Microstructure and electromagnetic shielding performance of plasma-sprayed Fe-Co-based amorphous alloy coatings[J]. Powder Metallurgy Industry, 2018, 28(5): 50-54 (in Chinese).
[8] 姜超平. 等离子喷涂铁基非晶涂层结构与性能研究[D]. 西安: 长安大学, 2010.
[9] 高涵, 魏先顺, 梁丹丹, 等. 超音速火焰喷涂Fe基非晶合金涂层材料的摩擦磨损性能研究[J]. 表面技术, 2018, 47(2): 55-63.
Gao H, Wei X S, Liang D D, et al. Friction and wear properties of HVAF sprayed Fe-based amorphous alloy coatings[J]. Surface Technology, 2018, 47(2): 55-63 (in Chinese).
[10] 黄飞, 康嘉杰, 岳文, 等. 超音速火焰喷涂制备铁基非晶合金涂层的研究现状[J]. 材料导报, 2018, 32(21): 115-121.
Huang F, Kang J J, Yue W, et al. A State-of-the-art review of Fe-based amorphous alloy coatings prepared by high-velocity oxygen fuel spray process[J]. Materials Review, 2018, 32(21): 115-121 (in Chinese).
[11] 梁秀兵, 王林磊, 陈永雄, 等. 高速电弧喷涂FeCrBSiMnNbW非晶纳米晶涂层组织及性能[J]. 装甲兵工程学院学报, 2012(5): 95-98.
Liang X B, Wang L L, Chen Y X, et al. Structure and property of FeCrBSiMnNbW amorphous and nanocrystalline coating prepared by high velocity arc spraying[J]. Journal of Armored Force Engineering Institute, 2012(5): 95-98 (in Chinese).
[12] 张绍强. 电弧喷涂Fe基非晶涂层的制备及摩擦学性能研究[D]. 洛阳: 河南科技大学, 2010.
[13] Choi S J, Lee H S, Jang J W, et al. Corrosion behavior in a 3.5 wt% NaCl solution of amorphous coatings prepared through plasma-spray and cold-spray coating processes[J]. Metals & Materials International, 2014, 20(6): 1053-1057.
[14] 安宇龙, 赵晓琴, 周惠娣, 等. 大气等离子喷涂制备Fe基非晶涂层及微观结构表征[J]. 中国表面工程, 2013, 26(5): 64-69.
An Y L, Zhao X Q, Zhou H D, et al. Preparation and microstructure characterization of atmosphere plasma sprayed Fe-based amorphous coating[J]. China Surface Engineering, 2013, 26(5): 64-69 (in Chinese).
[15] 解路, 熊翔, 王跃明. 不同热喷涂技术制备铁基非晶涂层的结构和耐磨性能[J]. 粉末冶金材料科学与工程, 2019, 24(3): 212-219.
Xie L, Xiong X, Wang Y M. Microstructure and tribological properties of plasma, high velocity oxy-fuel and detonation sprayed iron-based coatings[J]. Materials Science and Engineering of Powder Metallurgy, 2019, 24(3): 212-219 (in Chinese).
[16] 傅斌友, 贺定勇, 赵力东. 电弧喷涂铁基非晶涂层的磨粒磨损性能研究[J]. 摩擦学学报, 2008, 28(5): 428-432.
Fu B Y, He D Y, Zhao L D. Abrasive resistance of arc sprayed coatings containing Fe-based amorphous phase[J]. Tribology, 2008, 28(5): 428-432 (in Chinese).
[17] Tao Y, Xiong T, Sun C, et al. Effect of α-Al2O3 on the properties of cold sprayed Al/α-Al2O3 composite coatings on AZ91D magnesium alloy[J]. Applied Surface Science, 2009, 256(1): 261-266.
[18] 李耿, 周勇, 薛飒, 等. 冷喷涂技术[J]. 热处理技术与装备, 2009, 30(4): 11-14.
Li G , Zhou Y , Xue S, et al. Cold spray technology[J]. Heat Treatment Technology and Equipment, 2009, 30(4): 11-14 (in Chinese).
[19] Mccune R C, Donlon W T, Popoola O O, et al. Characterization of copper layers produced by cold gas-dynamic spraying[J]. Journal of Thermal Spray Technology, 2000, 9(1): 73-82.
[20] 刘倩楠, 刘咏, 李飞, 等. 热处理对Fe基非晶合金涂层的相组成及摩擦磨损行为的影响[J]. 粉末冶金材料科学与工程, 2012, 17(5): 586-591.
Liu Q, Liu Y, Li F, et al. Effect of heat treatment on micro-structure and wear behaviors of Fe-base amorphous alloy coatings[J]. Materials Science and Engineering of Powder Metallurgy, 2012, 17(5): 586-591 (in Chinese).
[21] Choi H, Yoon S, Kim G, et al. Phase evolutions of bulk amorphous NiTiZrSiSn feedstock during thermal and kinetic spraying processes[J]. Scripta Materialia, 2005, 53(1): 125-130.
[22] Yoon S, Bae G, Xiong Y, et al. Strain-enhanced nanocrystallization of a CuNiTiZr bulk metallic glass coating by a kinetic spraying process[J]. Acta Materialia, 2009, 57(20): 6191-6199.
[23] 王晓放, 李芳, 赵爱娃, 等. 喷嘴出口截面形状对冷喷涂涂层性能影响的数值分析[J]. 机械工程材料, 2006, 30(12): 84-86.
Wang X F, Li F, Zhao A, et al. Computational simulation of the effect of nozzle export section shape on cold spraying technology for material modification[J]. Materials for Mechanical Engineering, 2006, 30(12): 84-86 (in Chinese).
[24] 邱善广. 低压冷喷涂铝涂层的防腐性能研究[D]. 青岛: 中国海洋大学, 2013.
[25] 付伟, 黄国胜, 程旭东, 等. NiAl/NiCoCrAlY/8YSZ复合喷涂层的微观结构与性能研究[J]. 表面技术, 2019, 48(4): 75-81.
Fu W, Huang G S, Cheng X D, et al. Microstructure and properties of NiAl/NiCoCrAlY/8YSZ composite coatings[J]. Surface Technology, 2019, 48(4): 75-81 (in Chinese).
[26] Moridi A, Hassani M, Guagliano M, et al. Cold Spray Coating: Review of material systems and future perspectives[J]. Surface Engineering, 2014,30(6): 369-395.
[27] 马建平. 非晶态Al-Ce-Fe和Al-Ce-Ni晶化与腐蚀行为研究[D]. 包头: 内蒙古科技大学, 2015.
[28] 宋艳玲, 索忠源. 晶化行为对TiZr基块体非晶合金腐蚀性能的影响[J]. 特种铸造及有色合金, 2019, 39(1): 110-112.
Song Y L, Suo Z Y. Effect of crystalline behavior on corrosion resistance of TiZr-based bulk amorphous alloy[J]. Special Casting and Nonferrous Alloys, 2019, 39(1): 110-112 (in Chinese).
[29] 朱宗强, 傅明喜, 李丙丁, 等. 预处理对铁基非晶合金晶化过程的影响[J]. 特种铸造及有色合金, 2015, 35(2): 208-209.
Zhu Z Q, Fu M X, Li B D, et al. Effects of pretreatment on crystallization process of iron based amorphous alloy[J]. Special Casting and Nonferrous Alloys, 2015, 35(2): 208-209 (in Chinese).
[30] Inoue A. Bulk amorphous and nanocrystalline alloys with high functional properties[J]. Materials Science and Engineering A, 2001, 304/306: 1-10.
[31] Fu B Y, He D Y, Zhao L D. Effect of heat treatment on the microstructure and mechanical properties of Fe-based amorphous coatings[J]. Journal of Alloys and Compounds, 2009, 480(2): 422-427.
相似文献/References:
[1]任子阳,汤嘉昊,殷世铜,等. 冷喷涂制备铝基涂层研究进展及应用现状分析 [J].电镀与精饰,2023,(8):74.[doi:10.3969/j.issn.1001-3849.2023.08.012]
Ren Ziyang,Tang Jiahao,Yin Shitong,et al.Research progress and application status analysis of aluminum-based coatings prepared by cold spraying[J].Plating & Finishing,2023,(5):74.[doi:10.3969/j.issn.1001-3849.2023.08.012]
[2]张怡颖,张留艳 *,韩兆康,等.低压冷喷涂制备Al-Ni-xCr复合涂层及其磨损特性研究[J].电镀与精饰,2024,(5):36.[doi:10.3969/j.issn.1001-3849.2024.05.005]
Zhang Yiying,Zhang Liuyan *,Han Zhaokang,et al.Study on the wear characteristics of Al-Ni-xCr composite coating prepared by low pressure cold spraying[J].Plating & Finishing,2024,(5):36.[doi:10.3969/j.issn.1001-3849.2024.05.005]
备注/Memo
收稿日期: 2019-11-21;修回日期: 2019-12-26
通信作者: 黄国胜, email: huanggs@sunrui.net