[1]孙文明*,闫晟煜.阳极氧化和封孔处理改善铝合金表面性能的研究[J].电镀与精饰,2022,(4):20-24.[doi:10.3969/j.issn.1001-3849.2022.04.005]
 SUN Wenming *,YAN Shengyu.Study on Improvement of Surface Properties of Aluminum Alloy by Anodic Oxidation and Sealing Treatment[J].Plating & Finishing,2022,(4):20-24.[doi:10.3969/j.issn.1001-3849.2022.04.005]
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阳极氧化和封孔处理改善铝合金表面性能的研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2022年4
页码:
20-24
栏目:
出版日期:
2022-04-15

文章信息/Info

Title:
Study on Improvement of Surface Properties of Aluminum Alloy by Anodic Oxidation and Sealing Treatment
作者:
孙文明1*闫晟煜2
(1.浙江农业商贸职业学院 汽车技术系,浙江 绍兴 312000; 2.长安大学 汽车学院,陕西 西安 710064)
Author(s):
SUN Wenming 1* YAN Shengyu 2
( 1.Department of Automotive Technology Zhejiang Agricultural Business College Shaoxing 312000 China 2.College of Automobile Chang an University Xi an 710064 China )
关键词:
润湿性耐腐蚀性能抗污染性能阳极氧化氟钛酸铵封孔
Keywords:
分类号:
TQ153.6
DOI:
10.3969/j.issn.1001-3849.2022.04.005
文献标志码:
A
摘要:
为了改善铝合金表面耐腐蚀性能和抗污染性能,采用阳极氧化工艺对铝合金预先表面处理,然后通过氟钛酸铵封孔使其具有光催化活性。表征了不同类型铝合金试样的微观形貌和表面成分,并测试了表面水滴接触角、极化曲线以及对亚甲基蓝的降解率。结果表明:阳极氧化后铝合金表面仍然呈亲水性且无光催化活性,抗污染性能较差。氟钛酸铵封孔反应产物可以封堵微孔提高阳极氧化膜的致密性,并且使铝合金表面具有疏水特性和光催化活性,能够隔离腐蚀介质延缓腐蚀发展,同时在光催化作用下降解有机污染物,从而改善铝合金表面耐腐蚀性能和抗污染性能。
Abstract:
: Aluminum alloy was treated by anodic oxidation and then sealed with ammonium fluorotitanate having photocatalytic activity in order to improve its surface corrosion resistance and antifouling property. The microstructure and surface components of different types of aluminum alloy sample were characterized , and the contact angle of water droplet , polarization curves and degradation rate to methylene blue were also tested. The results showed that the aluminum alloy after anodic oxidation still present hydrophilicity and has no photocatalytic activity , and its antifouling property was poor. The reaction products generated during sealing with ammonium fluorotitanate can fill micropores and improve the compactness of anodic oxide film , and make aluminum alloy having hydrophobic property and photocatalytic activity. It can isolate the corrosive medium and delay the corrosion development , and degrade the organic pollutants under photocatalytic action , thus improve surface corrosion resistance and antifouling property of aluminum alloy.

参考文献/References:



[1] Liu X J, Gao J C, Li C, et al. Investigation on precision warm hydroforming with independent circumferential pressure of high-performance aluminum alloy parts with special-shaped bottom[J]. The International Journal of Advanced Manufacturing Technology, 2020, (109): 201-213.

[2] 胡斌 . 汽车行业发展对轻质结构部件的需求与展望 [J]. 精密成形工程 , 2020, 12(3): 120-124.

[3] Yin H, Liu J, Yang F. Hybrid structure design of lightweight robotic arms based on carbon fiber reinforced plastic and aluminum alloy[J]. IEEE Access, 2019(7): 64932-64945.

[4] 庞晓旭 , 何青竹 , 李梦凯 , 等 . AL5252 铝合金阳极氧化及封孔处理后的性能 [J]. 材料保护 , 2019, 52(3): 84-87.

[5] 尤媛 , 曲凤娇 , 肖宝靓 , 等 . 铝合金阳极氧化膜封孔质量检验方法的对比研究 [J]. 铝加工 , 2019(4): 38-41.

[6] Jo H, Lee S, Kim D, et al. Low temperature sealing of anodized aluminum alloy for enhancing corrosion resistance[J]. Materials, 2020, 13(21): 4904.

[7] Zhang Y G, Chen Y L, Bian G X, et al. Electrochemical behavior and corrosion mechanism of anodized 7B04 aluminum alloy in acid NaCl environments[J]. Journal of Alloys and Compounds, 2021(886): 161231.

[8] 张欣宇 , 李荣先 , 王臻 , 等 . Al 2 O 3 /TiO 2 复合膜的结构及光催化性能 [J]. 电镀与精饰 , 2007, 29(1): 12-15.

[9] 邢俊恒 , 夏正斌 , 张燕红 , 等 . 阳极氧化参数对 TiO 2 薄膜结晶行为影响的研究进展 [J]. 化工进展 , 2013, 32(3): 592-598.

[10] 黄允芳 , 蔡锡昌 . 采用氟钛酸盐封闭阳极氧化铝型材的研究 [J]. 电镀与精饰 , 2016, 38(6): 15-17.

[11] 朱祖芳 . 铝合金阳极氧化与表面处理技术 [M]. 北京 : 化学工业出版社 , 2010.

[12] 徐雷秋 , 万晓峰 , 董菁 , 等 . 盐酸 - 激光复合刻蚀 +SA 修饰制备镁合金表面超疏水结构的耐腐蚀性能 [J]. 机械工程材料 , 2019, 43(10): 6-10.

[13] 张拓 , 阮军 . 荷叶疏水机理与仿乳突固体颗粒在超疏水涂层中的应用研究进展 [J]. 涂料工业 , 2019, 49(7): 81-87.

[14] 李玉峰 , 高文博 , 史凌志 , 等 . 超疏水涂层的制备及其对 Mg-Li 合金的防腐蚀性能 [J]. 中国表面工程 , 2020, 33(5): 1-9.

[15] 李芳 . 钴钛氧化物异质结的构筑及光催化性能研究 [D]. 北京 : 北京化工大学 , 2016.

[16] Oh W C, Choi J G, Zhang F J, et al. Synthesis of expanded graphite-titanium oxide composite and its photocatalytic performance[J]. Journal of the Korean Ceramic Society, 2010, 47(3): 210-215.

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备注/Memo

备注/Memo:
收稿日期: 2021-08-19 修回日期: 2021-09-24 作者简介: 孙文明( 1985 —),硕士,讲师,主要研究方向:机械工程、车辆 CAD/CAE 、表面工程等 , email : KKlldw@163.com 基金项目: 2021 年浙江省教育厅一般科研项目( Y202145955 )
更新日期/Last Update: 2022-04-20