Wu Yu * Li Yueqiao Hong Wei Shen Yizhou * Du Gang Shen Zhicong.Research advance in densification for micro-arc oxidation film on magnesium alloy[J].Plating & Finishing,2024,(11):76-85.
镁合金微弧氧化膜致密化技术研究进展
- Title:
- Research advance in densification for micro-arc oxidation film on magnesium alloy
- Keywords:
- magnesium alloy ; micro-arc oxidation ; densification ; pretreatment ; post-treatment
- 分类号:
- TG174.4
- 文献标志码:
- A
- 摘要:
- 镁合金作为轻质结构材料,在装备轻量化领域展示了巨大的应用潜力。由于镁合金的化学活性较高,表面生成的氧化膜疏松多孔,严苛的服役环境对其长效稳定性构成严重威胁。采用表面防护技术有效提升镁合金的耐蚀性,延长其使用寿命。在镁合金表面改性防护技术中,微弧氧化技术具有显著的技术特征,被认为是最有前景的镁合金表面防护技术之一。然而镁合金微弧氧化膜存在本质的多孔结构特征,影响膜的防护效果。为扩大镁合金的应用领域,需要对微弧氧化膜进行致密化处理。本文综述了镁合金微弧氧化膜致密化技术的发展概况,总结了微弧氧化膜致密化技术的主要策略,以期为高致密镁合金微弧氧化膜的设计提供理论指导。最后,对镁合金微弧氧化膜致密化技术的未来发展趋势进行了展望。
- Abstract:
- : Magnesium alloy , as a lightweight structural material , has shown great potential for application in the field of equipment lightweight. While Mg alloy has high chemical activity , and the generated oxide film of surface has loose pores , harsh service environment poses a serious threat to their long-term stability. Surface protection technology effectively enhances the corrosion resistance of magnesium alloy and extends their service life. In the surface modification and protection technology of magnesium alloy , micro-arc oxidation technology has significant technical characteristics and is considered as one of the most promising surface protection technologies for Mg alloy. However , the micro-arc oxidation film on Mg alloy has inherent porous structure , which affects protective effect of film. To expand the application of Mg alloy , it is necessary to densify micro-arc oxidation film. This article provided an overview of the development of densification for micro-arc oxidation film on Mg alloy , and summarized the main strategies for densification , aiming to provide theoretical guidance for designing densified micro-arc oxidation film on Mg alloy. Finally , the future development direction of densification for micro-arc oxidation film on Mg alloy was discussed.
参考文献/References:
[1] Němcová A, Skeldon P, Thompson G E, et al. Influence of plasma electrolytic oxidation on fatigue performance of AZ61 magnesium alloy[J]. Corrosion Science, 2014, 82(5): 58-66.
[2] 蒋百灵 , 张淑芬 , 吴国建 , 等 . 镁合金微弧氧化陶瓷层显微缺陷与相组成及其耐蚀性 [J]. 中国有色金属学报 , 2002, 12(3): 454-457.
[3] 吴畏 , 陈腊梅 , 张丹丹 , 等 . 镁锂合金微弧氧化的研究进展 [J]. 电镀与精饰 , 2023, 45(5): 71-79.
[4] Tang H, Tao W, Wang C. et al. Fabrication of hydroxyapatite coatings on AZ31 Mg alloy by micro-arc oxidation coupled with sol-gel treatment[J]. RSC Advances, 2018, 8(22): 12368-12375.
[5] 方云鹏 , 杜克勤 , 郭泉忠 , 等 . 负向电压对 LA91 镁锂合金微弧氧化膜耐蚀性的影响 [J]. 电镀与精饰 , 2021, 43(3): 21-26.
[6] 吴瑜 , 陈刚 , 王红杰 , 等 . 电解液成分对 AZ80 镁合金微弧氧化膜耐蚀性的影响 [J]. 热加工工艺 , 2023, 52(14): 85-89.
[7] 祝海涛 , 孙金峰 , 孟永强 , 等 . Na 2 WO 4 含量对镁合金微弧氧化膜层颜色和耐蚀性的影响 [J]. 表面技术 , 2023, 52(10): 241-249.
[8] Cui L Y, Gao S D, Li P P, et al. Corrosion resistance of a self-healing micro-arc oxidation/polymethyltrimethoxysilane composite coating on magnesium alloy AZ31[J]. Corrosion Science, 2017, 118: 84-95.
[9] 韩东 , 连勇 , 张津 . K 2 ZrF 6 对镁合金微弧氧化膜抗点燃性能的影响 [J]. 表面技术 , 2021, 50(6): 55-63.
[10] Liu C C, Zhang W C, Xu T, et al. Preparation and corrosion resistance of a self-sealing hydroxyapatite-MgO coating on magne sium alloy by microarc oxidation[J]. Ceramics International, 2022, 48(10): 13676-13683.
[11] 陈明 , 马跃洲 , 马颖 , 等 . 电压增幅对镁合金微弧氧化膜层性能的影响 [J]. 稀有金属材料与工程 , 2010, 39(11): 1943-1947.
[12] 薛文斌 , 陈廷芳 , 李永良 , 等 . AZ31 镁合金搅拌摩擦焊接头微弧氧化表面防护研究 [J]. 材料工程 , 2012, 40(12): 1-6.
[13] Rapheal G, Kumar S, Scharnagl N, et al. Effect of current density on the microstructure and corrosion properties of plasma electrolytic oxidation (PEO) coatings on AM50 Mg alloy produced in an electrolyte containing clay additives[J]. Surface & Coatings Technology, 2016, 289: 150-164.
[14] Gheytani M, Bagheri H R, Masiha H R, et al. Effect of SMAT preprocessing on MAO fabricated nanocomposite coating[J]. Surface Engineering, 2014(4): 244-255.
[15] 魏征 , 马保吉 , 李龙 , 等 . 镁合金表面超声滚压预处理对微弧氧化膜耐蚀性能的影响 [J]. 中国腐蚀与防护学报 , 2021, 41(1): 117-124.
[16] Soliman H, Hamdy A S. Comparative study of micro-arc oxidation treatment for AM, AZ and MZ magnesium alloys[J]. Protection of Metals and Physical Chemistry of Surfaces, 2015, 51(4): 620-629.
[17] Hussein R O, Northwood D O, Nie X. The effect of processing parameters and substrate composition on the corrosion resistance of plasma electrolytic oxidation (PEO) coated magnesium alloys[J]. Surface & Coatings Technology, 2013, 237(12): 357-368.
[18] 马颖 , 王永欣 , 张洪峰 , 等 . 固溶处理对 AZ91D 镁合金微弧氧化的影响 [J]. 中国有色金属学报 , 2009, 19(10): 1741-1747.
[19] 张春燕 , 杨武 , 马超 . 镁合金激光重熔后微弧氧化膜的微观组织和耐蚀性能 [J]. 材料保护 , 2017, 50(2): 5-9.
[20] 管秀荣 , 朱宏达 , 李学田 , 等 . 微弧氧化增强镁合金钼酸盐转化膜层的制备 [J]. 表面技术 , 2019, 48(11): 347-355.
[21] Liu F, Yu J L I, Jia G U, et al. Preparation and performance of coating on rare-earth compounds-immersed magnesium alloy by micro-arc oxidation[J]. Transactions of Nonferrous Metals Society of China, 2012, 22(7): 1647-1654.
[22] 蒋百灵 , 刘东杰 . 制约微弧氧化技术应用开发的几个科学问题 [J]. 中国有色金属学报 , 2011, 21(10): 2402-2407.
[23] 郭洁 , 梁军 , 阎逢元 , 等 . 三种微弧氧化镁合金高温油润滑条件下的摩擦学性能 [J]. 化学研究 , 2009, 20(3): 59-63.
[24] 李红龙 , 宁成云 , 劳永华 , 等 . 氟离子浓度对镁合金微弧氧化膜层形成影响规律 [J]. 稀有金属材料与工程 , 2013, 42(8): 1707-1710.
[25] 孟令飞 , 张春华 , 张松 , 等 . ZrO 2 纳米颗粒含量对 AZ91D 镁合金微弧氧化膜耐蚀性的影响 [J]. 航空材料学报 , 2023, 43(1): 98-104.
[26] Song Y, Dong K H, Shan D Y, et al. Investigation of a novel self-sealing pore micro-arc oxidation film on AM60 magnesium alloy[J]. Journal of Magnesium & Alloys, 2013, 1(1): 82-87.
[27] Laleh M, Kargar F, Rouhaghdam A S. Formation of a compact oxide layer on AZ91D magnesium alloy by microarc oxidation via addition of cerium chloride into the MAO electrolyte[J]. Journal of Coatings Technology & Research, 2011, 8(6): 765-771.
[28] 董凯辉 , 孙硕 , 宋影伟 , 等 . 镁合金新型氟钛酸盐电解液体系微弧氧化电参数的优化 [J]. 中国有色金属学报 , 2014, 24(9): 2220-2227.
[29] Hussein R O, Northwood D O, Nie X. The influence of pulse timing and current mode on the microstructure and corrosion behaviour of a plasma electrolytic oxidation (PEO) coated AM60B magnesium alloy[J]. Journal of Alloys & Compounds, 2012, 541: 41-48.
[30] 张荣发 , 单大勇 , 韩恩厚 , 等 . 电流模式对镁合金微弧氧化膜性能的影响 [J]. 稀有金属材料与工程 , 2006, 35(9): 1392-1395.
[31] Cui X J, Lin X Z, Liu C H, et al. Microstructure and properties of MAO coatings for AZ91D magnesium alloy in varies work mode[J]. Materials Science Forum, 2013, 747/748: 178-183.
[32] 陈宏 , 黄杰 , 陈永楠 , 等 . 二次电压对 AZ91D 镁合金微弧氧化封孔的影响 [J]. 表面技术 , 2017, 46(5): 12-16.
[33] Wang Z X, Zhang J W, Ye F, et al. Properties of micro-arc oxidation coating fabricated on magnesium under two steps current-decreasing mode[J]. Frontiers in Materials, 2020, 7: 1-13.
[34] 宋仁国 . 微弧氧化技术的发展及其应用 [J]. 材料工程 , 2019, 47(3): 50-62.
[35] 翟彦博 , 陈红兵 , 马秀腾 . AZ31B 镁合金微弧氧化电解液温度对膜组织与性能的影响 [J]. 材料保护 , 2013, 46(4): 16-18, 22.
[36] Li S, Bai J, Feng L, et al. Research on micro-arc oxidation coatings with thermal control on magnesium alloy[J]. Physics Procedia, 2013, 50: 185-190.
[37] 朱枝胜 , 李文芳 , 易爱华 , 等 . 电解液温度对 AZ31B 镁合金黑色微弧氧化膜的影响 [J]. 表面技术 , 2019, 48(3): 53-61.
[38] 田德祥 , 刘新利 , 王德志 . 超声波在材料工程中的应用研究进展 [J]. 材料研究与应用 , 2022, 16(6): 942-958.
[39] 杜东方 , 章友谊 , 李明 . 超声处理对 Ti6Al4V 合金微弧氧化涂层结构和性能的影响 [J]. 表面技术 , 2018, 47(4): 207-212.
[40] 丁兆勇 , 牛宗伟 , 张超 , 等 . WE54 镁合金超声波辅助微弧氧化膜性能的研究 [J]. 电镀与环保 , 2019, 39(3): 59-62.
[41] 王嘉伟 , 田林海 , 林乃明 , 等 . 超声功率比对 AZ31B 镁合金微弧氧化复合陶瓷层耐蚀性能的影响 [J]. 热加工工艺 , 2022, 51(6): 107-110.
[42] Wang C, Zhong Y B, Ren W L, et al. Effects of parallel magnetic field on electrocodeposition behavior of Ni/nanoparticle composite electroplating-science direct[J]. Applied Surface Science, 2008, 254(18): 5649-5654.
[43] Zhao J, Xi J J, Wang Z G, et al. The effects of magnetic field on micro-arc oxidation ceramic coating on magnesium Alloys[J]. Advanced Materials Research, 2014, 960/961: 143-147.
[44] 王晟 , 刘康康 , 马颖 , 等 . 阴阳极距离对镁合金微弧氧化膜层性能及负载模型的影响 [J]. 中国有色金属学报 , 2020, 30(12): 2798-2808.
[45] Zhang L L, Wu Y Z, Zeng T, et al. Preparation and characterization of a sol-gel AHEC pore-sealing film prepared on micro arc oxidized AZ31 magnesium alloy[J]. Metals, 2021, 11(5): 784-795.
[46] 崔学军 , 魏劲松 , 宁闯明 , 等 . 氮气流量对 AZ31B 镁合金表面 MAO/TiN 涂层性能的影响 [J]. 中国表面工程 , 2017, 30(2): 27-34.
[47] 李岩 , 章晴云 , 卢小鹏 , 等 . 微弧氧化工艺参数对镁合金表面水滑石复合膜层耐蚀性的影响 [J]. 表面技术 , 2021, 50(8): 327-336.
[48] Guo M, Cao L, Lu P, et al. Anticorrosion and cytocompatibility behavior of MAO/PLLA modified magnesium alloy WE42[J]. Journal of Materials Science: Materials in Medicine, 2011, 22(7): 1735-1740.
[49] Chen Y H, Wu L, Yao W H, et al. Synthesis of ZIF-67 film in micro-arc oxidation anticorrosion coating on AZ31 magnesium alloy[J]. Transactions of Nonferrous Metals Society of China, 2023, 33(9): 2631-2645.
[50] 蒋世权 , 吴方 , 王媛媛 , 等 . 镁合金表面微弧氧化 / 自组装复合膜的耐蚀性能 [J]. 表面技术 , 2021, 50(4): 294-303.
[51] 韩晓光 , 雷明凯 , 朱小鹏 , 等 . 强流脉冲离子束辐照镁合金微弧氧化膜的耐腐蚀性能 [J]. 中国有色金属学报 , 2012, 22(2): 337-342.
[52] Yang S K, Wang C, Li F Z, et al. One-step in situ growth of a simple and efficient pore-sealing coating on micro-arc oxidized AZ31B magnesium alloy[J]. Journal of Alloys and Compounds, 2022, 909: 164710-164722.
[53] 时惠英 , 董利芳 , 蒋百灵 , 等 . AZ31B 镁合金表面微弧电泳复合膜层微观结构及耐蚀性表征 [J]. 稀有金属材料与工程 , 2015, 44(7): 1679-1684.
[54] 王志虎 , 白力静 , 王爱玲 , 等 . AZ91 镁合金表面微弧氧化与磁控溅射镀铜复合处理层的微观组织与性能 [J]. 稀有金属材料与工程 , 2018, 47(8): 2561-2566.
[55] Jiang D, Xia X, Hou J, et al. Enhanced corrosion barrier of microarc-oxidized Mg alloy by self-healing superhydrophobic silica coating[J]. Industrial & Engineering Chemistry Process Design and Development, 2019, 58: 165-178.
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备注/Memo
收稿日期: 2024-01-27 修回日期: 2024-02-18 作者简介: 吴瑜( 1994 —),男,硕士研究生,主要从事金属材料分析和表面改性研究, email : 395016693@qq.com * 通信作者: 吴瑜, email : 395016693@qq.com ;沈一洲,教授,主要研究方向:材料表面工程, email : shenyizhou@nuaa.edu.cn 基金项目: 金华市公益性技术应用研究项目( 2022-4-073 ) 镁合金微弧氧化膜致密化技术研究进展