SUN Chunlian*,ZHANG Liang,ZHANG Mingshui,et al.Research Progress on Giant Dielectric Materials[J].Plating & Finishing,2019,(12):30-34.[doi:10.3969/j.issn.1001-3849.2019.12.007]
巨介电材料的研究进展
- Title:
- Research Progress on Giant Dielectric Materials
- Keywords:
- giant dielectric materials; high dielectric constant; low dielectric loss; research progress
- 文献标志码:
- A
- 摘要:
- 随着电子工业的发展,为了满足电容器、存储器、谐振器、滤波器等重要电子器件的高性能化和尺寸微型化的需求,高介电常数材料越来越引起人们的重视。研制出新型的高介电常数材料,在宽频、宽温范围内,既具备高介电常数和低介质损耗,又有良好的频率和温度稳定性,是高容量电容器发展的需要。本文对现有的介电材料进行总结,并揭示了其巨介电机理。
- Abstract:
- With the development of the electronics industry, in order to meet the high performance and size miniaturization of important electronic devices such as capacitors, memories, resonators, filters, etc., the high dielectric constant materials have attracted more and more attention. The development of a new high dielectric constant material, which has high dielectric constant, low dielectric loss, good frequency and temperature stability in the wide frequency range and wide temperature range, is necessary to the development of the high capacity condenser. This article summarizes the existing dielectric materials and reveals their giant dielectrics mechanism.
参考文献/References:
[1] Cheng X, Li Z, Wu J. Colossal permittivity in ceramics of TiO2 co-doped with niobium and trivalent cation[J]. Journal of Materials Chemistry A, 2015, 3: 5805-5810.
[2] Thurnauer H. Ferroelectric ceramics: History and technology[J]. Journal of the American Ceramic Society, 1999, 82(4): 797-818.
[3] Hosono Y, Harada K, Yamashita Y. Crystal growth and electrical properties of lead-free piezoelectric material (Na1/2Bi1/2)TiO3-BaTiO3[J]. Japanese Journal of Applied Physics, 2001, 40(9): 5722-5726.
[4] Yao G, Wang X, Wu Y, et al. Nb doped 0.9BaTiO3-0.1(Bi0.5Na0.5)TiO3 ceramics with stable dielectric properties at high temperature[J]. Journal of the American Ceramic Society, 2012, 95(2): 614-618.
[5] Li L, Zhang B. The effect of bimodal model on the ultra-broad temperature stable BaTiO3-Na0.5Bi0.5TiO3-Nb2O5 system[J]. Scripta Materialia, 2016, 114: 170-174
[6] Lu D, Yue Y, Sun X. Novel X7R BaTiO3 ceramics co-doped with La3+ and Ca2+ ions[J]. Journal of Alloys and Compounds, 2014, 586: 136-141.
[7] Wu J, Nan C W, Lin Y, et al. Giant dielectric permittivity observed in Li and Ti doped NiO[J]. Physical Review Letters, 2002, 89(21):217601.
[8] Kim J H, Lee Y, Souchkov A, et al. Infrared study of giant dielectric constant in Li and Ti doped NiO[J]. Physics, 2004, 70(17):3352-3359.
[9] Lin Y, Jiang L, Zhao R, et al. High-permittivity core/shell tructured NiO-based ceramics and their dielectric response mechanism[J]. Physical Review B, 2005, 72(1):14-20.
[10] Lin Y, Wang J, Jiang L, et al. High permittivity Li and Al doped NiO ceramics[J]. Applied Physics Letters, 2004, 85(23):5664-5666.
[11] Ramirez A P, Subramanian M A, Gardel M, et al. Giant dielectric constant response in a copper-titanate[J]. Solid State Communications, 2000, 115(5): 217-220.
[12] Liu Y, Withers R L, Wei X Y. Structurally frustrated relaxor ferroelectric behavior in CaCu3Ti4O12[J]. Physical Review B, 2005, 72(13): 134-140.
[13] Chung S Y, Kim I D, Kang S J L. Strong nonlinear current-voltage behaviour in perovskite-derivative calcium copper titanate[J]. Nature Materials, 2004, 3(11): 774-778.
[14] Sinclair D C, Adams T B, Morrison F D, et al. CaCu3Ti4O12: One-step internal barrier layer capacitor[J]. Applied Physics Letters, 2002, 80(12): 2153-2155.
[15] Li W, Schwartz R W. Maxwell-wagner relaxations and their contributions to the high permittivity of calcium copper titanate ceramics[J]. Physical Review B, 2007, 22(1): 33-36.
[16] Prakash B S, Varma K B R. Influence of sintering conditions and doping on the dielectric relaxation originating from the surface layer effects in CaCu3Ti4O12 ceramics[J]. Journal of the Physics and Chemistry of Solids, 2007, 68(4): 490-502.
[17] Sun L; Wang Z; Hao W, et al. Influence of zirconium doping on microstructure and dielectric properties of CaCu3Ti4O12 synthesized by the sol-gel method[J]. Journal of Alloys and Compounds, 2015, 651: 283-289.
[18] Rani S; Ahlawat N, Punja R, et al. Dielectric and impedance studies of La and Zn co-doped complex perovskite CaCu3Ti4O12 ceramic[J]. Ceramics International, 2018, 44(18): 23125-23136.
[19] 杨昌辉, 周小莉, 徐刚, 等. 溶胶-凝胶法制备巨介电常数材料CaCu3Ti4O12[J]. 硅酸盐学报, 2006, 34(6): 753-756.
[20] Hu W, Liu Y, Withers R L, et al. Electron-pinned defect-dipoles for high-performance colossal permittivity materials[J]. Nature Materials, 2013, 12(9): 821-826.
[21] Zhao X G, Liu P, Song Y C, et al. Retraction: Origin of colossal permittivity in (In1/2Nb1/2)TiO2 via broadband dielectric spectroscopy[J]. Physical Chemistry Chemical Physics, 2015, 17(37): 24475-24475.
[22] Li Z, Luo X, Wu W, et al. Niobium and divalent-modified titanium dioxide ceramics: Colossal permittivity and composition design[J]. Journal of the American Ceramic Society, 2017, 100(12): 1-7.
[23] Yang C, Wei X, Hao J. Disappearance and recovery of colossal permittivity in (Nb+Mn) co-doped TiO2[J]. Ceramics International, 2018, 44(11): 12395-12400.
[24] Ke S, Li T, Ye M, et al. Origin of colossal dielectric response in (In + Nb) co-doped TiO2 rutile ceramics: a potential electrothermal material[J]. Sciencific Reports, 2017, 7: 10144-10153.
[25] Nachaithong T, Thongbai P, Maensiri S. Colossal permittivity in (In1/2Nb1/2)xTi1-xO2 ceramics prepared by a glycine nitrate process[J]. Journal of the European Ceramic Society, 2017, 37(2): 655-660.
备注/Memo
收稿日期: 2019-06-27;修回日期: 2019-11-17
通信作者: 孙春莲,email:suncl1972@163.com