XIAO Ge,YANG Xiaobo,XIANG Keyou,et al.New Development in Phosphating Process of Electro Galvanized and Hot Dip Galvanized Steel Sheet[J].Plating & Finishing,2021,(9):31-38.[doi:10.3969/j.issn.1001-3849.2021.09.006]
电镀锌及热浸镀锌钢板磷化工艺新进展
- Title:
- New Development in Phosphating Process of Electro Galvanized and Hot Dip Galvanized Steel Sheet
- Keywords:
- electro-galvanized sheet hot-dip galvanized sheet phosphating process corrosion resistance
- 文献标志码:
- A
- 摘要:
- 碳钢零件上进行电镀锌或者热浸镀锌是为了提高其耐腐蚀性能,而且在严酷的服役环境条件下,还需要在镀锌钢板表面进行磷化处理,然后再进行电泳涂漆等表面保护工序,磷化的目的一方面是可以提升与后续电泳漆膜的结合力,另外一方面是进一步提升这种表面处理零件在严酷环境条件下的防腐蚀性能。本文分别介绍了汽车钢板常用的两种镀锌层(电镀锌和热浸镀锌)的微观相结构特点,获得的磷化膜层的特点以及磷化工艺参数的影响等,分析探讨了这两类镀锌钢板(包括钢板上的锌合金镀层)的磷化工艺发展的新趋势。
- Abstract:
- The purpose of galvanizing or hot-dip galvanizing on carbon steel parts is to improve their corrosion resistance. In addition, under severe service conditions, phosphating treatment is also required on the surface of galvanized steel sheet, followed by electrophoretic painting and other surface protection processes. On the one hand, the purpose of phosphating is to enhance the adhesion with subsequent electrophoretic paint film. On the other hand, it is to further improve the corrosion resistance of the surface treated parts under severe environmental conditions. In this paper, the micro phase structure characteristics of two kinds of zinc coating (electro galvanizing and hot-dip galvanizing) commonly used in automobile steel sheet, the characteristics of obtained phosphating coating and the influence of phosphating process parameters are introduced.And the new development trend of phosphating process of these two kinds of zinc coating (including zinc alloy coating on steel sheet) are analyzed and discussed.
参考文献/References:
[1] 唐春华. 锌及锌合金板材的磷化工艺[J]. 材料保护, 2000, 33(11): 26-35.
Tang C H. Phosphating process of zinc and zinc alloy sheet[J]. Materials Protection, 2000, 33(11): 26-35 (in Chinese).
[2] 郝晓东, 刘昕, 张建, 等. 钢板表面状态对磷酸盐保护膜的影响[J]. 轧钢, 2013, 30(6): 25-28.
Hao X D, Liu X, Zhang J, et al. Influences of plate surface states on phosphate protective film[J]. Steel Rolling, 2013, 30(6): 25-28 (in Chinese).
[3] 唐春华. 金属表面磷化技术[M]. 北京: 化学工业出版社, 2011: 3-4.
[4] 王红洲. 21世纪面向汽车工业的磷化技术[J]. 汽车工艺与材料, 2006, 6: 5-10.
Wang H Z. Phosphating technology for automotive industry in the 21th century[J]. Automobile Technology &Material, 2006, 6: 5-10 (in Chinese).
[5] 原霞, 王衍强. 汽车用镀锌钢板磷化处理专利技术分析[J]. 云南化工, 2019, 46(4): 122-123.
Yuan X, Wang Y Q. Patent technology analysis of phosphating treatment of galvanized steel plate for automobile[J]. Yunnan Chemical Technology, 2019, 46(4): 122-123 (in Chinese).
[6] 朱久发. 汽车用镀锌板预磷化和磷化技术[J]. 武钢技术, 2007, 45(3): 49-53.
Zhu J F. Brief introduction to prephosphating and phosphating technology of galvanizedsteel sheets for automobile[J]. Wisco Technology, 2007, 45(3): 49-53 (in Chinese).
[7] 谭海林, 李新立, 李安忠, 等. 电镀锌板的磷化[J]. 汽车工艺与材料, 2004(3): 19-24.
Tan H L, Li X L, Li A Z, et al. Phosphating of electrogalvanizedsheet[J]. Automobile Technology & Material, 2004(3): 19-24 (in Chinese).
[8] 孙晨航, 曹洋. 电镀锌磷化产品工艺与质量稳定控制[J]. 金属世界, 2020, 4: 75-77, 80.
Sun C H, Cao Y. Technology and quality stability control of electrogalvanizing phosphating products[J]. Metal World, 2020, 4: 75-77, 80 (in Chinese).
[9] Bustamante G, Fabri-Miranda F J, Margarit C P, et al. Influence of prephosphating on painted electrogalvanizedsteel[J]. Progress in Organic Coating, 2003, 46(3): 84-90.
[10] Filho J F S, Lins V F C. Crystallographic texture and morphology of an electrodeposited zinc layer[J]. Surface Coating Technology, 2006, 200(9): 2892-2899.
[11] 顾训雷, 单玉桥, 刘常升. 工艺参数对高速电镀锌层形貌和织构的影响[J]. 中国有色金属学报, 2011, 21(8): 1910-1915.
Gu X L, Shan Y Q, Liu C S. Effects of technological parameters on morphology and texture of high speed galvanized coatings[J]. The Chinese Journal of Nonferrous Metals, 2011, 21(8): 1910-1915 (in Chinese).
[12] 曾险峰, 刘刚, 谭小生, 等. 锌合金表面涂装前磷化处理对膜层结合力的影响[J]. 材料保护, 2018, 51(3): 64-67, 82.
Zeng X F, Liu G, Tan X S, et al. Effects of pre-phosphating treatment before coating-process on the adhesion of coating of zinc alloy[J]. Materials Protection, 2018, 51(3): 64-67, 82 (in Chinese).
[13] 陈泽民, 张巧云, 李志林. 电泳涂装常温磷化工艺及磷化膜性能[J]. 中国腐蚀与防护学报, 2008, 28(6): 351-354.
Chen Z M, Zhang Q Y, Li Z L. Phosphating technology and phosphating film property at room temperature before electrophuretic coating[J]. Journal of Chinese Society for Corrosion and Protection, 2008, 28(6): 351-354 (in Chinese).
[14] 李金华. 磷化膜对锌板表面涂层附着力的影响[J]. 表面技术, 2006, 35(2): 33-34.
Li J H. The effect of phosphating films on the adhesive force of coatings on the surface of galvanized iron boards[J]. Surface Technology, 2006, 35(2): 33-34 (in Chinese).
[15] 董蓓, 魏星, 刘渊媛, 等. 磷化工艺对电镀锌预磷化板磷化膜质量的影响[J]. 材料保护, 2018, 51(12): 72-76.
Dong B, Wei X, Liu Y Y, et al. Effect of phosphating process on the quality of phosphating film on electrogalvanized Sheet[J]. Materials Protection, 2018, 51(12): 72-76 (in Chinese).
[16] 杨成志, 董蓓, 彭周, 等. 表面缺陷对预磷化电镀锌板磷化膜质量的影响[J]. 材料保护, 2018, 51(2): 9-13.
Yang C Z, Dong B, Peng Z, et al. Effect of surface defects on quality of phosphating film on electrogalvanized steel sheet[J]. Materials Protection, 2018, 51(2): 9-13 (in Chinese).
[17] Klusmann E, Schultze J W. pH-Microscopy: technical application in phosphating solutions[J]. Electrochimica Acta, 2003, 48: 3325-3332.
[18] 张雨泉, 顾训雷, 杨芃, 等. 电镀锌预磷化板晶粒度和粗糙度的工艺控制[J]. 材料与冶金学报, 2015, 14(1): 40-43.
Zhang Y Q, Gu X L, Yang P, et al. Controlling process of grain size and surface roughness of prephosphated galvanized steel[J]. Journal of Materials and Metallurgy, 2015, 14(1): 40-43 (in Chinese).
[19] 郑凯, 施凯顺, 李红艺, 等. 低碳钢表面锌-镍合金镀层的质量评价[J]. 电镀与精饰, 2013, 35(2): 5-7, 31.
Zheng K, Shi K S, Li H Y, et al. Quality evaluation of zinc-nickel alloy layer on low carbon steel surface[J]. Plating and Finishing, 2013, 35(2): 5-7, 31 (in Chinese).
[20] 黎敏, 郝玉林, 赵晓非, 等. 磷化对热镀锌板电泳漆膜抗石击腐蚀性能的影响[J]. 电镀与涂饰, 2019, 38(3): 104-108.
Li M, Hao Y L, Zhao X F, et al. Effect of phosphating on corrosion resistance of electrophoretic coating on hot-dip galvanized steel sheet after stone chipping[J]. Electroplating & Finishing, 2019, 38(3): 104-108 (in Chinese).
[21] 计遥遥, 王辉, 李子涛, 等. 表面形貌对热浸镀锌钢板锆系前处理性能的影响[J]. 安徽冶金科技职业学院学报, 2020, 30(3): 9-11.
Ji Y Y, Wang H, Li Z T, et al. Surface morphology of hot dip galvanized steel sheet as its influence on compatibility with zirconium-based film[J]. Journal of Anhui Vocational College of Metallurgy and Technology, 2020, 30(3): 9-11 (in Chinese).
[22] 刘武华, 胡燕慧, 张浩, 等. 磷化处理对无铬钝化热镀锌板耐蚀性能的影响[J]. 轧钢, 2020, 37(3): 40-43.
Liu W H, Hu Y H, Zhang H, et al. Effect of phosphating on corrosion resistance of chromium freepassivated hot dip galvanized sheet[J]. Steel Rolling, 2020, 37(3): 40-43 (in Chinese).
[23] 刘贤明, 王彤, 郑健斌. 光整热镀锌板磷化过程中铝离子的影响及消除[J]. 电镀与涂饰, 2002, 21(4): 48-50.
Liu X M, Wang T, Zheng J B. Effect and elimination of aluminum ions in phosphating of bright and level hot dip galvanized sheet[J]. Electroplating & Finishing, 2002, 21(4): 48-50 (in Chinese).
[24] Wolpers M, Angeli J. Activation of galvanized steel surface before zinc phosphating-XPS and GDOES investigations[J]. Applied Surface Science, 2001, 179: 281-291.
[25] 林碧兰, 孔纲, 卢锦堂, 等. 热镀锌层上磷酸锌转化膜的生长与耐蚀性[J]. 中国有色金属学报, 2007, 17(5): 800-806.
Lin B L, Kong G, Lu J T, et al. Growth and corrosion resistance of zinc phosphate conversion coatings on hot dip galvanized steel[J]. The Chinese Journal of Nonferrous Metals, 2007, 17(5): 800-806 (in Chinese).
[26] 董蓓, 涂元强, 杨成志. 磷酸钛表调工艺对电镀锌磷化膜质量的影响[J]. 材料保护, 2016, 49(10): 53-55.
Dong B, Tu Y Q, Yang C Z. Effect of surface activating process of titanium phosphate on quality of phosphating film onelectrogalvanized steel[J]. Materials Protection, 2016, 49(10): 53-55 (in Chinese).
[27] 叶法军, 李承樵. 表调对汽车涂装磷化成膜的影响[J]. 材料保护, 2006, 39(11): 62-64.
Ye F J, Li C Q. Effect of surface modulation by colloidal Ti-Salt on the performance of phosphating coating used for automobile[J]. Materials Protection, 2006, 39(11): 62-64 (in Chinese).
[28] 张创优, 汤晓东, 张振海, 等. 镀锌钢板表面新型晶态磷化技术的研究[J]. 材料保护, 2016, 49(6): 35-38.
Zhang C Y, Tang X D, Zhang Z H, et al. Novel crystalline phosphaling technology on surface of galvanized steel sheet[J]. Materials Protection, 2016, 49(6): 35-38 (in Chinese).
[29] 李红玲, 张圣麟, 杨玉萍. 环保型磷化促进剂的研究进展[J]. 表面技术, 2011, 39(2): 87-89.
Li H L, Zhang S L, Yang Y P. Research and development of environmentally friendly phosphating accelerator[J]. Surface Technology, 2011, 39(2): 87-89 (in Chinese).
[30] Kong G, Liu L Y, Lu J T, et al. Corrosion behavior of lanthanumbased conversion coating modified with citric acid on hot dip galvanized steel in aerated 1 M NaCl solution[J]. Corrosion Science, 2011, 53(4): 1621-1624.
[31] 戴崇良, 李智, 张强国, 等. 镀锌钢板钙改性磷化膜生长机理的研究[J]. 电镀与环保, 2007, 27(6): 26-29.
Dai C L, Li Z, Zhang Q G, et al. Film forming mechanism of calcium-modified phosphating coating on galvanized steel[J]. Electroplating & Pollution Control, 2007, 27(6): 26-29 (in Chinese).
备注/Memo
收稿日期: 2021-04-20;修回日期: 2021-05-26
作者简介: 肖革(1966—),男,本科,总监,email:xiaoge@mstzh.com
通信作者: 朱立群,email:zhulq@buaa.edu.cn
基金项目: 上海机器人产业研发与转化功能平台2020年度开放课题