HAO Lifeng*,JIANG Zewen,CAO Feng,et al.Research Progress of Cerium Oxide Thin Films Prepared by Electrodeposition[J].Plating & Finishing,2022,(11):76-84.[doi:10.3969/j.issn.1001-3849.2022.11.014]
二氧化铈电沉积的研究进展
- Title:
- Research Progress of Cerium Oxide Thin Films Prepared by Electrodeposition
- Keywords:
- CeO 2 ; direct current deposition ; simultaneous cathode and anode electrodeposition ; photo-assisted anodic electrodeposition ; mechanism ; research progress
- 分类号:
- TQ153.2
- 文献标志码:
- A
- 摘要:
- 二氧化铈属于面心立方晶体结构，四面体间隙位置由阴离子填充。由于其物理化学性能较为特殊，二氧化铈极易形成氧空位， CeO 2 薄膜作为镀锌钢板和铝合金的防腐涂层受到了广泛关注。论文对 CeO 2 电沉积工艺方法、沉积机理和成核生长方式进行回顾与总结，归纳了多种电沉积法，介绍和评述了碱化电沉积机理、三步反应机理和光助阳极电沉积的“空穴氧化”机理，以期对未来相关科研工作的开展提供良好的支持。
- Abstract:
- ： The cerium dioxide has a face-centered cubic crystal structure with tetrahedral interstitial positions filled by anions. Due to its special physical and chemical properties ， ceria is easy to form oxygen vacancies ， CeO 2 film has received extensive attention as an anticorrosive coating for galvanized steel sheets and aluminum alloys. The CeO 2 electrodeposition process ， deposition mechanism and nucleation growth mode were reviewed and summarized. A variety of electrodeposition methods were summarized and the alkaline electrodeposition mechanism ， three-step reaction mechanism ， and “ hole oxidation ” mechanism for photo-assisted anode electrodeposition were introduced and commented in order to provide good reference for the development of related scientific researches in the future.
参考文献/References:
[1] He Q, Li A L, Guo Y C, et al. Tribological properties of nanometer cerium oxide as additives in lithium grease[J]. Journal of Rare Earths, 2018, 36(2): 209-214.
[2] Kumar A, Babu S, Dasgupta A, et al. Enhancing the dual magnetic and optical properties of co-doped cerium oxide nanostructures[J]. RSC Advances, 2015, 5(125): 103465-103473.
[3] Tuller H L. Ionic conduction in nanocrystalline materials[J]. Solid State Ionics, 2000, 131(1): 143-157.
[4] Tsunekawa S, Sahara R, Kawazoe Y, et al. Origin of the blue shift in ultraviolet absorption spectra of nanocrystalline CeO 2- x particles[J]. Materials Transactions, JIM, 2000, 41(8): 1104-1107.
[5] Trovarelli A, De Leitenburg C, Boaro M, et al. The utilization of ceria in industrial catalysis[J]. Catalysis Today, 1999, 50(2): 353-367.
[6] Zhou F, Zhao X M, Xu H, et al. CeO 2 spherical crystallites: synthesis, formation mechanism, size control, and electrochemical property study[J]. Journal of Physical Chemistry C, 2007, 111(4): 1651-1657.
[7] Chen H I, Chang H Y. Synthesis and characterization of nanocrystalline cerium oxide powders by two-stage non-isothermal precipitation[J]. Solid State Communications, 2005, 133(9): 593-598.
[8] Cho Y J, Jang H M, Lee K S, et al. Direct growth of cerium oxide nanorods on diverse substrates for superhydrophobicity and corrosion resistance[J]. Applied Surface Science, 2015, 340: 96-101.
[9] Ishizaki T, Masuda Y, Sakamoto M. Corrosion resistance and durability of superhydrophobic surface formed on magnesium alloy coated with nanostructured cerium oxide film and fluoroalkylsilane molecules in corrosive NaCl aqueous solution[J]. Langmuir, 2011, 27(8): 4780-4788.
[10] Ma L, Wang, X Wang, J, et al. Graphene oxide-cerium oxide hybrids for enhancement of mechanical properties and corrosion resistance of epoxy coatings[J]. Journal of Materials Science, 2021, 56(16): 10108-10123.
[11] Ivanov Vladimir K, Shcherbakov A B, Usatenko A V . Structure-sensitive properties and biomedical applications of nanodispersed cerium dioxide[J]. Russian Chemical Reviews, 2009, 78(9): 855-871.
[12] Chu D, Masuda Y, Ohji T, et al. Room-temperature synthesis and characterization of porous CeO 2 thin films[J]. Physica Status Solidi (A), 2012, 209(1): 139-142.
[13] Strandwitz N C, Stucky G D. Hollow microporous cerium oxide spheres templated by colloidal silica[J]. Chemistry of Materials, 2009, 21(19): 4577-4582.
[14] Yamaguchi I, Watanabe M, Shinagawa T, et al. Preparation of core/shell and hollow nanostructures of cerium oxide by electro deposition on a polystyrene sphere template[J]. ACS applied materials & interfaces, 2009, 1(5): 1070-1075.
[15] 魏东博 , 张平则 , 赵瑞博 , 等 . NiCrAlSi/CeO 2 掺杂 YSZ 热障涂层及其制备 方法 : 中国 , CN109207917B[P]. 2020-8-4.
[16] Yoshimura M, Suchanek W. In situ fabrication of morphology-controlled advanced ceramic materials by soft solution processing[J]. Solid State Ionics, 1997, 98(3): 197-208.
[17] Yoshimura M. Importance of soft solution processing for advanced inorganic materials[J]. Journal of Materials Research, 1998, 13(4): 796-802.
[18] Therese G H A, Kamath P V. Electrochemical synthesis of metal oxides and hydroxides[J]. Chemistry of Materials, 2000, 12(5): 1195-1204.
[19] Kamada K, Higashikawa K, Inada M, et al. Photoassisted anodic electrodeposition of ceria thin films[J]. The Journal of Physical Chemistry C, 2007, 111(39): 14508-14513.
[20] Yang Y, Yang Y, Du X, et al. Influences of the main anodic electroplating parameters on cerium oxide films[J]. Applied Surface Science, 2014, 305: 330-336.
[21] Yang Y, Yang Y, An C, et al. The composition-dependent color evolution of anodic electrodeposited cerium oxide thin film[J]. Journal of the Electrochemical Society, 2014, 161(12): 644-650.
[22] Hamlaoui Y, Pedraza F, Remazeilles C, et al. Cathodic electrodeposition of cerium-based oxides on carbon steel from concentrated cerium nitrate solutions Part I. electrochemical and analytical characterisation[J]. Materials Chemistry and Physics, 2009, 113(2): 650-657.
[23] ?ivkovi? Lj S, Popi? J P, Jegdi? B V, et al. Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: effect of deposition potential[J]. Surface and Coatings Technology, 2014, 240: 327-335.
[24] Teresa D G, Wang A Q. Anodic electrodeposition of cerium oxide thin films II. Mechanism studies[J]. Journal of the Electrochemical Society, 2003, 150 (9): C621-C624.
[25] James A F. Atlas of electrochemical equilibria in aqueous solutions[M]. New York: National Association of Corrosion, 1974.
[26] 杨洋 . 纳米结构 CeO 2 薄膜的阳极电沉积机制及其光辅助生长研究 [D]. 杭州 : 浙江大学 , 2015.
[27] 杨雨萌 . 纳米结构 CeO 2 薄膜的电沉积机制及其性能研究 [D]. 杭州 : 浙江大学 , 2018.
[28] Yang Y M, Du X Q, Yi C X, et al. Structural, optical and electrical properties of CeO 2 thin films simultaneously prepared by anodic and cathodic electrodeposition[J]. Applied Surface Science, 2018, 11(3): 208-223.
[29] 晋通正 , 杨雨萌 , 范圣慧 , 等 . 溶解氧及波长对光助阳极沉积 CeO 2 薄膜的影响 [J]. 电化学 , 2020, 26(6): 868-875.
[30] Li X H, Pletcher D, Walsh F C. Electrodeposited lead dioxide coatings[J]. Chemical Society Reviews, 2011, 40 (7): 3879-3894.
[31] Wang Q. Preparetion and properties of nano-CeO 2 /Zn composites[J]. Transactions of Nonferrous Metals Society of China, 2007, 17: 622-625.
[32] Que T L, Li J. Studies of the preparation of nanocomposites based on MoO 3 and its electrochemical performance[J]. Chemical Research and Application, 2012, 24 (7): 1069-1074.
[33] 杜重麟 . 纳米 CeO 2 对 Pb-WC-CeO 2 复合镀层结构及耐腐蚀性的影响 [J]. 化学研究与应用 , 2014, 26(7): 1089-1094.
[34] Nemes L, Patrick Ioan, Lekka M, et al. Influence of the electrodeposition current regime on the corrosion resistance of Zn-CeO 2 nanocomposite coatings[J]. Surface and Coatings Technology, 2014, 252: 102-107.
[35] Li B S, Zhang W W. Synthesis of Ni-Co-ZrO 2 nanocomposites doped with ceria particles via electrodeposition as highly protective coating[J]. Journal of Alloys and Compounds, 2020, 820: 153158-153170.
[36] Li B S, Zhang W W, Mei T Y, et al. Influence of zirconia and ceria nanoparticles on structure and properties of electrodeposited Ni-W nanocomposites[J]. Composite Structures, 2020, 235: 111773-111782.
[37] Yao Y W, Dong H S, Jiao L M, et al. Preparation and electrocatalytic property of PbO 2 -CeO 2 nanocomposite electrodes by pulse reverse electrodeposition methods[J]. Journal of the Electrochemical Society, 2016, 163(5): 179-184.
[38] Lo?c E, Juan C. Synthesis of Zn-ceria nanocomposite coatings from particle-free aqueous bath in a one electrodeposition step process[J]. Colloids and Interface Science Communications, 2018, 25: 31-35.
[39] Switzer J A. Electrochemical synthesis of ceramic films and powders[J]. American Ceramic Society Bulletin, 1987, 66: 1521-1525.
[40] Wang A Q, Golden T D. Anodic electrodeposition of cerium oxide thin films I. Formation of crystalline thin films[J]. Journal of the Electrochemical Society, 2003, 150(9): C616-C620.
[41] Lair V, Ringuedé A, Vermaut P, et al. Synthesis and characterization of cerium oxide by electrochemical methods[J]. Physica Status Solidi (C), 2008, 5(11): 3492-3495.
[42] Arenas M A, De Damborenea J J. Growth mechanisms of cerium layers on galvanised steel[J]. Electrochimica Acta, 2003, 48(24): 3693-3698.
[43] Stefanov P, Atanasova G, Stoychev D, et al. Electrochemical deposition of CeO 2 on ZrO 2 and Al 2 O 3 thin films formed on stainless steel[J]. Surface and Coatings Technology, 2004, 180: 446-449.
[44] Maria D, Virginie L, Philippe V, et al. Study of ceria thin films prepared via electrochemical deposition : role of selected electrochemical parameters on growth kinetics[J]. Thin Solid Films, 2019, 693: 137674.
[45] Kulp E A, Limmer S J, Bohannan E W, et al. Electrodeposition of nanometer-thick ceria films by oxidation of cerium (III)-acetate[J]. Solid State Ionics, 2007, 178 (11-12): 749-757.
[46] Kamada K, Higashikawa K, Inada M, et al. Photoassisted anodic electrodeposition of ceria thin films[J]. Journal of Physical Chemistry (C), 2007, 111(39): 14508-14513.
[47] Kamada K, Horiguchi K, Hyodo T, et al. Photochemical synthesis of monodispersed ceria nanocrystals in simple cerium nitrate solution without additives[J]. Crystal Growth & Design, 2011, 11: 1202-1207.
[48] 李强 , 辜敏 , 鲜晓红 . 铜电结晶的研究进展 [J]. 化学进展 , 2008, 20(4): 483-490.
[49] Armstrong R D, Harrison J A. Two-dimensional nucleation in electrocrystallization[J]. Journal of the Electrochemical Society, 1969, 116(3): 328-331.
[50] Fleischmann M, Thirsk H R. The potentiostatic study of the growth of deposits on electrodes[J]. Electrochimica Acta, 1959, 1(2-3): 146-160.
[51] Bewick A, Fleischmann M, Thirsk H R. Kinetics of the electrocrystallization of thin films of calomel[J]. Transactions of the Faraday Society, 1962, 58: 2200-2216.
[52] Astley D J, Harrison J A, Thirsk H R. Electrocrystallization of mercury, silver and palladium[J]. Transactions of the Faraday Society, 1968, 64: 192-201.
[53] Armstrong R D, Fleischmann M, Thirsk H R. The anodic behaviour of mercury in hydroxide ion solutions[J]. Journal of Electroanalytical Chemistry, 1966, 11(3): 208-223.
备注/Memo
收稿日期： 2021-12-20 修回日期： 2022-02-28 作者简介： 郝利峰（ 1977 —），男，博士，副教授， email ： 02578@zjhu.edu.c n 基金项目： 湖州市公益性应用研究项目（ 2020GZ04 ）； 2021 年浙江省大学生科技创新活动计划暨新苗人才计划（ 2021R431019 ）；浙江省教育厅 高等学校访问学者教师专业发展项目（ FX2020050 ）?/html>