HAO Lifeng*,JIANG Zewen,ZHANG Zheyang,et al.Progress in Environmental Protection Paint Remover[J].Plating & Finishing,2020,(10):33-41.[doi:10.3969/j.issn.1001-3849.2020.10.0070]
环保型脱漆剂研究进展
- Title:
- Progress in Environmental Protection Paint Remover
- 文献标志码:
- A
- 摘要:
- 针对目前脱漆剂存在的毒性大、污染严重等问题,环境友好且绿色环保型脱漆剂的研发工作受到关注。各类脱漆剂在解决环境问题方面已初见成效,并得到了良好的社会效益。本文综述了环保脱漆剂的主要分类和脱漆效果,介绍了脱漆剂的研究进展和研究手段,从宏观和微观上解释了脱漆机理,并对脱漆剂未来的发展趋势进行了展望。
- Abstract:
- In view of the problems existing in domestic paint remover, such as high toxicity and serious pollution, the research and development of environmentally friendly and green paint remover has attracted much attention. All kinds of paint remover have achieved initial results in solving environmental problems, and good social benefits have been obtained. In this paper, the main classification and effect of environmental protection paint remover are reviewed. The research progress and research methods are introduced. The mechanisms of paint removal are explained macroscopically and microscopically, and the development trend of paint remover in the future is prospected.
参考文献/References:
[1] 董颖女, 王毛毛, 熊青昀, 等. 环境友好型脱漆剂的研究进展[J]. 电镀与精饰, 2014, 36(10): 22-24.
Dong Y N, Wang M M, Xiong Q Y, et al. Research progress in environmental-friendly paint stripper[J]. Plating & Finishing, 2014, 36(10): 22-24 (in Chinese).
[2] 李伟溢. 脱漆剂的研究进展[J]. 电镀与涂饰, 2004, 23(2): 37-40.
Li W Y. Progress of study on paint strippers[J]. Electroplating & Finishing, 2004, 23(2): 37-40 (in Chinese).
[3] 杨军, 尹文华, 杨小利. 飞机脱漆剂的组成分析[J]. 合成材料老化与应用, 2019, 48(4): 30-33.
Yang J, Yi W H, Yang X L. Compositions analysis of an aircraft paint stripper[J]. Synthetic Materials Aging and Application, 2019, 48(4): 30-33 (in Chinese).
[4] Hans H B. Paint stripping with nontoxic chemicals[J]. Metal Finishing. 1995, 93(4): 34-35, 37.
[5] 张金娜, 李江波, 蒋桂高, 等. 苯甲醇水基中性脱漆剂的研究及应用[J]. 电镀与涂饰, 2012, 31(7): 64-67.
Zhang J N, Li J B, Jiang G G, et al. Research and application of benzyl alcohol water based neutral paint stripper[J]. Electroplating & Finishing, 2012, 31(7): 64-67 (in Chinese).
[6] 侯伟, 何宗文, 何宗俊. 水性脱漆剂的制备及性能[J]. 材料保护, 2017, 50(8): 60-62.
Hou W, He Z W, He Z J. Synthesis of water-based paint stripper and property analysis[J]. Material Protection, 2017, 50(8): 60-62 (in Chinese).
[7] 李咏. 一种无水脱漆剂的研制[J]. 航空维修与工程, 2017, (2): 39-40.
Li Y. Study on an anhydrous paint remover[J]. Aviation Maintenance and Engineering, 2017, (2): 39-40 (in Chinese).
[8] 李莹, 仉新功, 李伟鹏, 等. 圆柱型电泳挂具挂点自动脱漆装置和低腐蚀快速脱漆剂的研究[J]. 电镀与精饰, 2017, 39(3): 25-28.
Li Y, Zhang X G, Li W P, et al. Study on automatic paint stripping device used for hanging point of cylindrical rack in electrophoresis painting and low corrosive fast paint remover[J]. Plating & Finishing, 2017, 39(3): 25-28 (in Chinese).
[9] 武志富, 梁柳青, 陈振兴. 不同类型及配方脱漆剂脱漆效果的比较[J]. 吉首大学学报(自然科学版), 2017, 38(2): 63-65.
Wu Z F, Liang L Q, Chen Z X. Comparison of the depainting effects of different paint removers [J]. Journal of Jishou University (Natural Science Edition), 2017, 38(2): 63-65 (in Chinese).
[10] 董颖女, 王毛毛, 熊青昀, 等. 一种新型乳液型脱漆剂[J]. 电镀与精饰, 2015, 37(6): 23-2 7.
Dong Y N, Wang M M, Xiong Q Y, et al. A new type of emulsion paint stripper[J]. Plating & Finishing, 2015, 37(6): 23-27 (in Chinese).
[11] Mónica V C, Lilian C N, Magda Carolina S C, et al. High chromosomal instability in workers occupationally exposed to solvents and paint removers[J]. Molecular Cytogenetics, 2016, 9: 46.
[12] Macisaac J, Harrison R, Krishnaswami J, et al. Fatalities due to dichloromethane in paint strippers: a continuing problem[J]. American Journal of Industrial Medicine, 2013, 56(8): 907-910.
[13] 水立军. 镁合金脱漆剂的研制[J]. 上海涂料, 2010, 48(12): 10-12.
Shui L J. Preparation of magnesium alloy paint removers[J]. Shanghai Coatings, 2010, 48(12): 10-12 (in Chinese).
[14] 周雅, 许海东, 刘佳慧, 等. 脱漆剂脱漆速度的主要影响因素分析[J]. 材料保护, 2010, 43(11): 40-42, 49.
Zhou Y, Xu H D, Liu J H, et al. Analysis of main influencing factors of paint removal rate[J]. Material Protection, 2010, 43(11): 40-42, 49 (in Chinese).
[15] 黄娇, 闫俊廷, 赵春英, 等. 一种新型镁合金脱漆剂的研制[J]. 电镀与精饰, 2011, 33(10): 43-46.
Huang J, Yan J T, Zhao C Y, et al. Preparation of a new paint stripper for magnesium alloy[J]. Plating & Finishing, 2011, 33(10): 43-46 (in Chinese).
[16] 周雅. 苯甲醇(醛)型脱漆剂使用性能研究[J]. 材料保护, 2002, (5): 50-51.
Zhou Y. Application properties of benzyl alcohol/ benzaldehyde water-solubility paint stripper[J]. Material Protection, 2002, (5): 50-51 (in Chinese).
[17] 于国胜, 马延泉. 新型低毒脱漆剂的制法[P]. CN88105200, 1989-09-13.
[18] 张翼, 傅杰, 邵德忠, 等. 一种漆包线脱漆剂及其制备方法和使用方法[P]. CN105566995B, 2019-04-26.
[19] 王成林, 孙岚. 适用于难脱除漆膜的强力水基脱漆剂[J]. 现代涂料与涂装, 2016, 19(10): 11-13.
Wang C L, Sun L. High-efficiency and water-based paint remover for difficult to remove paint film[J]. Modern Paint and Finishing. 2016, 19(10): 11-13 (in Chinese).
[20] 何静. 碱溶液法脱除聚酯漆包线漆膜及其工程应用[D]. 杭州: 浙江大学, 2016.
[21] 黄学卫, 梁志杰, 黄琪. 环氧富锌底漆漆膜脱漆剂的研制[J]. 中国表面工程, 2005, 1: 34-38.
Huang X W, Liang Z J, Huang Q. Study on the paint remover of zinc rich epoxy primer coating[J]. China Surface Engineering, 2005, 1: 34-38 (in Chinese).
[22] 孙杰, 赵武强, 孟锦宏, 等. 低毒低挥发性脱漆剂的研制[J]. 电镀与涂饰, 2008, 27(4): 52-54.
Sun J, Zhao W Q, Meng J H, et al. Preparation of a low toxicity and volatility paint stripper[J]. Electroplating & Finishing, 2008, 27(4): 52-54 (in Chinese).
[23] 黄学卫, 李金寿, 鲍苏宁, 等.一种船舶专用的环保型脱漆剂及其制备方法[P]. CN105255249A, 2016-01-20.
[24] 徐鹏, 黄绘, 唐楷, 等. 汽车涂装脱漆剂性能的改善研究[J]. 现代涂装, 2018, 21(3): 59-62.
Xu P, Huang H, Tang K, et al. Study on improvement of paint remover performance used for automobile painting[J]. Modern Finishing, 2018, 21(3): 59-62 (in Chinese).
[25] Duan N, Gao Y W, Zhang T, et al. Study on water-based paint stripper for tinplate[J]. Advanced Materials Research, 2013, 690-693: 2071-2075.
[26] 区燕婷, 余倩, 高泉, 等. 一种新型环保无毒脱漆剂及其制备方法[P]. CN104804515A, 2015-07-29.
[27] 王欢, 张俊杰, 李红霞. 乳液型金属脱漆剂的研制[J]. 河北联合大学学报(自然科学版), 2013, 35(2): 90-93.
Wang H, Zhang J J, Li H X. Development of emulsion type metal paint remover[J]. Journal of Hebei United University (Natural Science Edition), 2013, 35(2): 90-93 (in Chinese).
[28] Young C N, Claytona C R, Yesinowski J P, et al. Physicochemical investigation of chemical paint removers: Interactions of methylene chloride with polyurethane coatings[J]. Progress in Organic Coatings, 2014, 77(1): 232-241.
[29] Young C N, Claytona C R, Wynne J H, et al. Physicochemical investigation of chemical paint removers. II: Role and mechanism of phenol in the removal of polyurethane coatings[J]. Progress in Organic Coatings, 2015, 88: 212-219.
[30] Huang Z D, Zhou J H, Hu C F, et al. Role and mechanism of formic acid in stripping of paint comprising epoxy primer and polyurethane topcoat[J]. Journal of Coatings Technology and Research, 2018, 15(2): 385-394.
[31] 刘大壮, 王兆勤. 溶度参数及其在涂料工业中的应用[M]. 北京: 海洋出版社, 2008.
[32] 杨高产, 习早红, 陈炳耀, 等. 环境友好型脱漆剂的制备[J]. 中国涂料, 2011, 26(10): 55-59.
Yang G C, Xi Z H, Chen B Y, et al. Preparation of an environment-friendly de-painting agent[J]. China Coatings, 2011, 26(10): 55-59 (in Chinese).
[33] 王海庆, 李丽, 庄光山. 涂料与涂装技术[M]. 北京: 化学工业出版社, 2012.
[34] 郑顺兴. 涂料与涂装科学技术基础[M]. 北京: 化学工业出版社, 2007.
[35] 熊金平, 张海兵, 左禹. 高效脱漆剂的制备和腐蚀性研究[J]. 电镀与涂饰, 2006, 25(8): 32-34.
Xiong J P, Zhang H B, Zuo Y. Preparation of high-efficiency paint remover and its corrosion property[J]. Electroplating & Finishing, 2006, 25(8): 32-34 (in Chinese).
[36] 徐绍魁, 侯秀红, 张玉梅, 等. 溶胀对超高分子量聚乙烯隔膜性能的影响[J]. 塑料, 2016, 45(5): 100-102, 113.
Xu S K, Hou X H, Zhang Y M, et al. Effect of ultra-high molecular weight polyethylene swelling on properties of separator[J]. Plastics, 2016, 45(5): 100-102, 113 (in Chinese).
[37] 王金梅, 陈革新, 洪戈浪, 等. 拉链头用水性高效脱漆剂的制备及应用[J]. 电镀与涂饰, 2017, 36(22): 1211-1214.
Wang J M, Chen G X, Hong G L, et al. Preparation and application of waterborne high-efficient paint stripper for zipper head[J]. Electroplating & Finishing, 2017, 36(22): 1211-1214 (in Chinese).
[38] 段宁, 胡艳麟, 张银凤. DBE脱漆剂的脱漆性能研究[J]. 当代化工, 2014, 43(3): 320-323.
Duan N, Hu Y L, Zhang Y F. The stripping performance of DEB paint stripper[J]. Contemporary Chemical Industry, 2014, 43(3): 320-323 (in Chinese).
[39] 葛娣. 食品罐用镀锡钢板的环保型脱漆剂研制[D]. 武汉: 武汉科技大学, 2011.
[40] 董颖女. 一种新型乳液型脱漆剂[D]. 北京: 北京化工大学, 2015.
[41] 许海东. 用于飞机的水性脱漆剂的研究[D]. 南昌: 南昌航空航天大学, 2010.
[42] 刘意. 漆包线脱漆剂及其在聚酯中的微观传质研究[D]. 杭州: 浙江大学, 2015.
相似文献/References:
[1]蒋泽文,任蕙岚,何家伟,等.脱脂技术研究进展[J].电镀与精饰,2020,(11):29.[doi:10.3969/j.issn.1001-3849.2020.11.0070]
JIANG Zewen,REN Huilan,HE Jiawei,et al.Research Progress of Degreasing Technology[J].Plating & Finishing,2020,(10):29.[doi:10.3969/j.issn.1001-3849.2020.11.0070]
[2]李永迪,宫明江,于茂来,等.环保高效热镀锌合金钢丝技术研究[J].电镀与精饰,2021,(12):52.[doi:10.3969/j.issn.1001-3849.2021.12.011]
LI Yongdi,GONG Mingjiang,YU Maolai,et al.Environmental Protection and High-Efficiency Hot-Dip Zinc Alloy Steel Wire Technology Research[J].Plating & Finishing,2021,(10):52.[doi:10.3969/j.issn.1001-3849.2021.12.011]
[3]陆永亮*.绿色工艺技术在电镀锡产线的应用[J].电镀与精饰,2022,(3):64.[doi:10.3969/j.issn.1001-3849.2022.03.012]
LU Yongliang *.Application of Green Process in Tin Electroplating Production Line[J].Plating & Finishing,2022,(10):64.[doi:10.3969/j.issn.1001-3849.2022.03.012]
[4]洪子康,骆祎岚,罗 晗,等.细长窄深槽类带钩零件环保铬镀层的制备与表征[J].电镀与精饰,2023,(2):61.[doi:10.3969/j.issn.1001-3849.2023.02.010]
Hong Zikang,Luo Yilan,Luo Han,et al.Preparation and characterization of environmentally friendly chromium coating for slim narrow and deep groove parts with hook[J].Plating & Finishing,2023,(10):61.[doi:10.3969/j.issn.1001-3849.2023.02.010]
[5]周闻云*,郭 蓓,李冬冬,等. 钢材用缓蚀剂研究进展 [J].电镀与精饰,2023,(3):83.[doi:10.3969/j.issn.1001-3849.2023.03.012]
Zhou Wenyun*,Guo Bei,Li Dongdong,et al.Research progress of corrosion inhibitor for steel[J].Plating & Finishing,2023,(10):83.[doi:10.3969/j.issn.1001-3849.2023.03.012]
[6]范丽娜*,张晓林,陈 锋,等.铝合金铬酸阳极化在航空领域的环保替代工艺分析[J].电镀与精饰,2023,(8):81.[doi:10.3969/j.issn.1001-3849.2023.08.013]
Fan Lina*,Zhang Xiaolin,Chen Feng,et al.Analysis of environmental protection alternative process of chromic acid anodizing for aluminum alloy in aviation field[J].Plating & Finishing,2023,(10):81.[doi:10.3969/j.issn.1001-3849.2023.08.013]
[7]收稿日期: 0-0- 修回日期: 0-0-.一种铝及铝合金氰化镀银前处理酸洗工艺研究[J].电镀与精饰,2024,(11):30.
Study on pickling process for pre-treatment of cyanide silver plating of aluminum and aluminum alloys Li Xiaozheng 1 2 3 Wu Rumeng 1 2 3* Zhang Hongjun 1 2 3 Ma Yingchun 1 2 3 Wang Ting 1 2 3[J].Plating & Finishing,2024,(10):30.
[8]刘泽恩,马建强,王梅丰,等.doi: 10.3969/j.issn.1001-3849.2025.01.0122024-T3铝合金环境友好型脱氧工艺研究[J].电镀与精饰,2025,(01):73.
Liu Zeen,Ma Jianqiang,Wang Meifeng*,et al.Experimental study of environmental protection deoxidation process for 2024-T3 aluminum alloy[J].Plating & Finishing,2025,(10):73.
备注/Memo
收稿日期: 2019-12-31;修回日期: 2020-03-13
通信作者: 郝利峰,email:02578@zjhu.edu.cn
基金项目: 湖州市科技员特派项目(2019KT26);湖州市公益性应用研究项目(2020GZ04);浙江省教育厅一般科研项目(Y201941352);湖州师范学院校级科研项目(2018XJKJ59);湖州师范学院求真学院大学生创新创业训练科研项目(201902047)