GAO Tianrui,LAN Zhuoyue,LYU Jinfang*,et al.Research Status of Valuable Metals Recovery from Electroplating Sludge[J].Plating & Finishing,2021,(11):42-47.[doi:10.3969/j.issn.1001-3849.2021.11.008]
电镀污泥中有价金属综合回收技术研究现状
- Title:
- Research Status of Valuable Metals Recovery from Electroplating Sludge
- 文献标志码:
- A
- 摘要:
- 随着我国经济的快速发展，电镀行业取得了巨大的进步，但同时也伴随着大量电镀废水的产生。电镀废水在处理过程中产生了大量固体危险废物—电镀污泥。该类污泥如果处理不当，则会引起二次环境污染，并对人体健康造成严重威胁。此外，由于污泥中含有大量有价金属，具有一定的回收价值，因此高效回收污泥中有价金属已成为目前的研究热点。本文全面阐述了电镀污泥中的有价金属的回收技术的研究现状，旨在为研究污泥资源化利用的企业和学者提供参考，结合自身实际生产和研究情况，提高污泥中有价金属的综合利用率。
- Abstract:
- With the rapid development of Chinas economy, electroplating industries have also made great progress. But it is also accompanied by a large number of electroplating wastewater. Electroplating wastewater produces a lot of solid hazardous waste-electroplating sludge in the treatment process. If not handled properly, it is going to cause secondary pollution and serious harm to human health. In addition, the reason why efficient recovery of valuable metals in sludge has become the focus of scholars is the sludge contains a large number of valuable metals and has a certain recovery value. In this paper, the research status of the recovery technologies of valuable metals in electroplating sludge is summarized. The purpose is to provide reference for the companies and scholars who study the resource utilization of sludge and to improve the comprehensive utilization radio of valuable metals in sludge combined with their own actual production situation.
参考文献/References:
[1] 张丰如, 陈志云, 蔡惠玲,等. 电镀污泥萃取处理技术[J]. 山东化工, 2019, 48(12):197.
Zhang F R, Chen Z Y, Cai H L, et al. Extraction technology of electroplating sludge [J]. Shandong Chemical Industry, 2019, 48(12):197 (in Chinese).
[2] 俞绍贺. 电镀污泥中重金属的回收及固化处置[J]. 资源再生, 2019, 6:44-45,49.
Yu S H. Recovery and solidification of heavy metals from electroplating sludge [J]. Resource Regeneration, 2019, 6:44-45,49(in Chinese).
[3] Magalhaes J, Silva J, Castro F, et al. Physical and chemical characterisation of metal finishing industrial wastes[J]. Journal of Environmental Management, 2005, 75(2):157-166.
[4] Espinosa D C R, Tenorio J A S. Thermal behavior of chromium electroplating sludge[J]. Waste Management, 2001, 21(4):405-410.
[5] Barquilha C E R, Cossich E S, Célia R G T, et al. Biosorption of nickel and copper ions from synthetic solution and electroplating effluent using fixed bed column of immobilized brown algae[J]. Journal of Water Process Engineering, 2019, 32:100904.
[6] 易龙生, 冯泽平, 汪洲, 等. 电镀污泥资源化处理技术综述[J]. 电镀与精饰, 2014, 36(12):16-20.
Yi L S, Feng Z P Wang Z, et al. Review of electroplating sludge resource treatment technology [J]. Electroplating & Finishing, 2014, 36(12):16-20.(in Chinese)
[7] 张仲仪. 电镀工业园区危险废物的回收与处置[J]. 电镀与精饰, 2009, 8:44-46.
Zhang Z Y. Recycling and disposal of hazardous waste in electroplating industrial park [J]. Electroplating & Finishing, 2009, 8:44-46.(in Chinese)
[8] Feng Y, Yang S, Xia L, et al. In-situ ion exchange electrocatalysis biological coupling (i-IEEBC) for simultaneously enhanced degradation of organic pollutants and heavy metals in electroplating wastewater[J]. Journal of Hazardous Materials, 2019, 364:562-570.
[9] 刘智峰, 田文瑞. 湿法回收电镀污泥中重金属的研究现状[J]. 电镀与精饰, 2012, 7:14-19.
Liu Z F, Tian W R. Research status of heavy metals recovery from electroplating sludge by wet process [J]. Electroplating & Finishing, 2012, 7:14-19.(in Chinese)
[10] 张海亮, 梁冬云, 刘勇. 电镀污泥处理现状及进展[J]. 再生资源与循环经济, 2017, 10(7): 25-30.
Zhang H L, Liang D Y, Liu Y. Current situation and progress of electroplating sludge treatment[J]. Renewable Resources and Circular Economy, 2017, 10(7): 25-30(in Chinese).
[11] Li C, Xie F, Ma Y, et al. Multiple heavy metals extraction and recovery from hazardous electroplating sludge waste via ultrasonically enhanced two-stage acid leaching[J]. Journal of Hazardous Materials, 2010, 178(1-3):823-833.
[12] Huyen P T, Dang T D, Tung M T, et al. Electrochemical copper recovery from galvanic sludge[J]. Hydrometallurgy, 2016, 164:295-303.
[13] 岳琦, 刘三军, 姚文明, 等. 风化电镀污泥回收利用工艺研究[J]. 矿冶工程, 2017, 37(4): 86-88.
Yue Q, Liu S J, Wen M Y, et al. Study on the recycling technology of weathered electroplating sludge[J]. Mining and Metallurgy Engineering, 2017, 37(4): 86-88(in Chinese).
[14] 彭庆康, 刘定富, 郑智, 等. 电镀污泥中锌的浸出工艺研究[J]. 山东化工, 2015, 44(17): 177-179, 182.
Peng Q K, Liu D F, Zheng Z, et al. Study on leaching process of zinc from electroplating sludge[J]. Shandong Chemical Industry, 2015, 44(17): 177-179, 182(in Chinese).
[15] 刘伟, 朱昊辰, 徐伟, 等. 氨浸法选择性回收电镀污泥中铜,镍的研究[C]// 上海市化学化工学会, 2013.
Liu W, Zhu H C, Wei X, et al. Study on selective recovery of copper and nickel from electroplating sludge by ammonia leaching [C]// Shanghai Institute of Chemistry and Chemical Engineering, 2013(in Chinese).
[16] Cüneyt A, Arslan F. Recovery of copper, cobalt, and zinc from copper smelter and converter slags[J]. Hydrometallurgy, 2002, 67(1-3):1-7.
[17] Fábio A D A, Andréa M B, Viviane S D S, et al. Metals recovery from galvanic sludge by sulfate roasting and thiosulfate leaching[J]. Minerals Engineering, 2014, 60:1-7.
[18] 姚虹. 电镀污泥处置及资源化方法探究[J]. 中国资源综合利用, 2019, 37(10):78-80+106.
Yao H. research on electroplating sludge disposal and resource utilization methods[J]. Comprehensive Utilization of Resources in China, 2019, 37(10):76-80+106(in Chinese).
[19] 宁江. 电镀污泥酸浸无害化资源化研究[D]. 哈尔滨:哈尔滨工业大学, 2019.
[20] 易龙生, 赵立华, 许元洪, 等. 电镀污泥中铜的浸出和溶剂萃取回收研究[J]. 矿冶工程, 2019, 39(4): 115-118, 122.
Yi L S, Zhao L H, Xu Y H, et al. Study on leaching and solvent extraction recovery of copper from electroplating sludge[J]. Mining and Metallurgy Engineering, 2019, 39(4): 115-118, 122(in Chinese).
[21] Su R, Liang B, Guan J. Leaching effects of metal from electroplating sludge under phosphate participation in hydrochloric acid medium[J]. Procedia Environmental Sciences, 2016, 31:361-365.
[22] 王伍, 查正炯, 黄智源. 某电镀污泥硫酸浸出研究[J]. 广东化工, 2018, 45(22):24-25.
Wang W, Cha Z J, Huang Z Y. Study on sulfuric acid leaching of electroplating sludge[J]. Guangdong Chemical Industry, 2018, 45(22):24-25(in Chinese).
[23] 李强, 赵峰, 杨卜, 等. 电镀污泥多金属资源化利用研究[J]. 有色金属:冶炼部分, 2016, 4:63-65.
Li Q, Zhao F, Yang B, et al. Study on multi-metal resource utilization of electroplating sludge[J]. Nonferrous Metals: Smelting Section, 2016, 4:63-65(in Chinese).
[24] 易龙生 ,刘苗, 赵立华, 等. 电镀污泥氨浸渣中铬的回收[J]. 环境污染与防治, 2020, 42(3): 334-338.
Yi L S, Liu M, Zhao L H, et al. Recovery of chromium from ammonia leaching residue of electroplating sludge[J]. Environmental Pollution and Prevention, 2020, 42(3): 334-338(in Chinese).
[25] 池利昆, 王吉华. 氨浸法从含铜污泥中回收铜的研究[J]. 云南师范大学学报(自然科学版), 2012, 32(6): 67-70.
Chi L K, Wang J H. Study on copper recovery from copper-containing sludge by ammonia leaching[J]. Journal of Yunnan Normal University (Natural Science Edition), 2012, 32(6): 67-70(in Chinese).
[26] 王晓丹. 氨浸工艺在危险废物处理中的应用[J]. 中国有色冶金, 2019, 48(2):39-41,45.
Wang X D. Application of ammonia leaching process in hazardous waste treatment[J]. China Nonferrous Metallurgy, 2019, 48(2):39-41,45(in Chinese).
[27] 蓝子栋. 电镀污泥中重金属的回收与固化处理[J]. 企业技术开发, 2018, 37(11):96-98.
Lan Z D. Recovery and solidification of heavy metals in electroplating sludge[J]. Enterprise Technology Development, 2018, 37(11):96-98(in Chinese).
[28] Macchi G, Pagano M, Pettine M, et al. A bench study on chromium recovery from tannery sludge[J]. Water Research, 1991, 25(8):1019-1026.
[29] 郑智. 多金属电镀污泥中铬的回收利用[D]. 贵阳:贵州大学, 2016.
[30] 周雪. 电镀污泥的焙烧浸出实验研究[D]. 西安:西安建筑科技大学, 2015.
[31] 党晓娥, 刘安全, 吕军. 电镀污泥钠钙化焙烧过程金属的矿相转化及平衡分布[J]. 环境工程学报, 2018, 12(10): 2944-2951.
Dang X E, Liu A Q, Lv J. Mineral phase transformation and equilibrium distribution of metals during sodium calcification roasting of electroplating sludge [J]. Chinese Journal of Environmental Engineering, 2018, 12(10): 2944-2951(in Chinese).
[32] 郑顺. 氯盐体系电镀污泥中有价金属选择性提取工艺研究[D]. 江西理工大学, 2015.
[33] 陈娴, 程洁红, 周全法, 等. 火法-湿法联合工艺回收电镀污泥中的铜[J]. 环境工程, 2012, 30(2): 68-71.
Chen X, Cheng J H, Zhou Q F, et al. Recovery of copper from electroplating sludge by combined process of fire and wet process[J]. Environmental Engineering, 2012, 30(2): 68-71(in Chinese).
[34] 樊锐, 李才, 邵敏,等. 电镀污泥处置方法现状及发展趋势[J]. 天津化工, 2019, 33(1):4-6.
Fan R, Li C, Shao M, et al. Current situation and development trend of electroplating sludge disposal methods[J]. Tianjin Chemical Industry, 2019, 33(1):4-6.(in Chinese)
[35] Yue Y , Zhang J , Sun F , et al. Heavy metal leaching and distribution in glass products from the co-melting treatment of electroplating sludge and MSWI fly ash[J]. Journal of Environmental Management, 2019, 232(15):226-235.
[36] 宋珍珍. 含铜污泥的处理及综合利用方法[J]. 有色冶金节能, 2018, 34(6): 53-56.
Song Z Z. Treatment and comprehensive utilization of copper-containing sludge[J]. Energy Saving in Nonferrous Metallurgy, 2018, 34(6): 53-56(in Chinese).
[37] 廖昌华, 孙水裕, 张志. 焚烧温度对电镀污泥后续处理影响研究[J]. 再生资源研究, 2002, 5: 34-36.
Liao C H, Sun S Y, Zhang Z. Influence of incineration temperature on subsequent treatment of electroplating sludge[J]. Research on Renewable Resources, 2002, 5: 34-36(in Chinese).
[38] 彭桂群, 敖子强. 电镀污泥处理技术的研究进展[J]. 电镀与环保, 2018, 38(5):62-64.
Peng G Q, Ao Z Q. Research progress of electroplating sludge treatment technology[J]. Electroplating and Environmental Protection, 2018, 38(5):62-64(in Chinese).
[39] 王静, 叶海明. 含铜电镀污泥中铜的资源化回收技术[J]. 化学工程与装备, 2010, 163(8): 197-199, 205.
Wang J, Ye H M. Recycling technology of copper from electroplating sludge containing copper[J]. Chemical Engineering and Equipment, 2010, 163(8): 197-199, 205(in Chinese).
[40] 阳伦庄, 王邕舟. 密闭还原炉处理含铜电镀污泥的工艺设计[J]. 世界有色金属, 2019, 522(6):180-181.
Yang L Z, Wang Y Z. Process design of treating copper-containing electroplating sludge in closed reduction furnace[J]. World Nonferrous Metals, 2019, 522(6): 180-181(in Chinese).
[41] 济源豫光有色冶金设计研究院有限公司. 一种采用底吹熔池熔炼工艺处理电镀污泥的方法: CN201911312615. 7[P]. 2020-04-21.
Jiyuan Yuguang Nonferrous Metallurgy Design and Research Institute Co. Ltd. The invention relates to a method of treating electroplating sludge by bottom blowing melting pool smelting process: CN201911312615. 7[P]. 2020-04-21(in Chinese).
[42] 王春花. 电镀污泥资源化利用的研究进展[J]. 化工环保, 2012, 32(1):25-29.
Wang C H. Research progress of electroplating sludge resource utilization[J]. Chemical Environmental Protection, 2012, 32(1):25-29(in Chinese).
[43] 谭中欣, 严建华, 蒋旭光, 等. 电镀污泥焚烧过程中的热分析以及重金属的迁移规律[J]. 环境科学, 2006, 5:998-1002.
Tan Z X, Yan J H, Jiang X G, et al. Thermal analysis and heavy metal migration during electroplating sludge incineration[J]. Environmental Science, 2006, 5: 998-1002(in Chinese).
[44] 刘刚, 蒋旭光, 池涌, 等. 危险废物电镀污泥热处置特性研究[J]. 环境科学学报, 2005, 10:1355-1360.
Liu G, Jiang X G, Chi Y, et al. Study on thermal treatment characteristics of hazardous waste electroplating sludge[J]. Chinese Journal of Environmental Sciences, 2005, 10:1355-1360(in Chinese).
[45] Rastegar S O, Mousavi S M, Shojaosadati S A. Cr and Ni recovery during bioleaching of dewatered metal-plating sludge using acidithiobacillus ferrooxidans[J]. Bioresource Technology, 2014, 167:61-68.
[46] 施燕, 张太平, 李木桂, 等. 利用硫杆菌淋滤电镀污泥中的重金属[J]. 生态环境, 2008, 17(5):1787-1791.
Shi Y, Zhang T P, Li M G, et al. Leaching heavy metals from electroplating sludge by thiobacillus[J]. Ecology and Environment, 2008, 17(5): 1787-1791(in Chinese).
[47] 黎明. 固体废物污染控制与资源化[A]. 云南铜业(集团)有限公司、云南省有色金属学会. 第七届冶炼技术论文发布会论文集[C]. 云南铜业(集团)有限公司、云南省有色金属学会:云南省科学技术协会, 2015:10.
Leon L M. Solid Waste Pollution Control and Recycling [A]. Yunnan Copper (Group) Co., Ltd., Yunnan Nonferrous Metals Society. Proceedings of the Seventh Smelting Technology Paper Conference [C]. Yunnan Copper (Group) Co., Ltd., Yunnan Nonferrous Metals Society: Yunnan Science and Technology Association, 2015:10(in Chinese).
[48] Ye J, Yin H, Mai B, et al. Biosorption of chromium from aqueous solution and electroplating wastewater using mixture of Candida lipolytica and dewatered sewage sludge[J]. Bioresource Technology, 2010, 101(11):3893-3902.
[49] 李福德. 微生物治理电镀废水方法[J]. 电镀与精饰, 2002, 24(2):35-37.
Li F D. Microbial treatment of electroplating wastewater[J]. Electroplating and Finishing, 2002, 24(2):35-37(in Chinese).
[50] 钟雪虎,焦芬,覃文庆,等. 电镀污泥处理与处置方法概述[J]. 电镀与涂饰, 2017, 36(17): 948-953.
Zhong X H, Jiao F, Qin W Q, et al. Overview of electroplating sludge treatment and disposal methods[J]. Electroplating and Finishing, 2017, 36(17): 948-953(in Chinese).
[51] 张在海, 张双龙. 电镀污泥超高温古细菌清洁资源化处理工业应用[J]. 矿产综合利用, 2019, 220(6): 123-128.
Zhang Z H, Zhang S L. Industrial application of ultra-high temperature archaea clean resource treatment of electroplating sludge[J]. Comprehensive Utilization of Mineral Resources, 2019, 220(6): 123-128(in Chinese).
[52] 毕文龙. 嗜酸性硫杆菌和黑曲霉处理回收电镀污泥重金属的研究[D]. 南京农业大学, 2014.
相似文献/References:
[1]周 超,李 勇,薛向欣.利用吡啶类离子液体萃取分离电镀污泥中的Cr6+与Fe3+[J].电镀与精饰,2019,(1):41.[doi:10.3969/j.issn.1001-3849.2019.01.009]
ZHOU Chao,LI Yong,XUE Xiangxin.Extraction Separation of Cr6+ and Fe3+ from Electroplating Sludge Using Pyridine Ionic Liquids[J].Plating & Finishing,2019,(11):41.[doi:10.3969/j.issn.1001-3849.2019.01.009]
[2]韩文静,张晓光.电镀污泥中镍的提取回收利用研究进展[J].电镀与精饰,2022,(11):100.[doi:10.3969/j.issn.1001-3849.2022.11.018]
HAN Wenjing,ZHANG Xiaoguang.Research Progress on Extraction and Recycling of Nickel from Electroplating Sludge[J].Plating & Finishing,2022,(11):100.[doi:10.3969/j.issn.1001-3849.2022.11.018]
备注/Memo
收稿日期： 2020-12-13；修回日期： 2021-01-16
*通信作者： 吕晋芳，jflv2017@126.com。
基金项目： 国家自然科学基金青年项目（No.51904129）；云南省教育厅科学研究