[1]孙 伟*,许 霞,张伟华.建筑结构钢锌钙系磷化膜的结构与耐蚀性研究[J].电镀与精饰,2022,(10):60-64.[doi:10.3969/j.issn.1001-3849.2022.10.010]
　SUN Wei*,XU Xia,ZHANG Weihua.Investigation on Structure and Corrosion Resistance of Zinc-Calcium Phosphating Films on Building Structural Steel[J].Plating & Finishing,2022,(10):60-64.[doi:10.3969/j.issn.1001-3849.2022.10.010]
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建筑结构钢锌钙系磷化膜的结构与耐蚀性研究
()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2022年10
页码:
60-64
栏目:
出版日期:
2022-10-17

文章信息/Info

Title:
Investigation on Structure and Corrosion Resistance of Zinc-Calcium Phosphating Films on Building Structural Steel
作者:
（青岛黄海学院，山东 青岛 266427）
Author(s):
( Qingdao Huanghai University Qingdao 266427 China )
关键词:
耐蚀性; 锌钙系磷化膜; 建筑结构钢; 磷化时间
Keywords:
corrosion resistance ;  zinc-calcium phosphating films ;  building structural steel ;  phosphating time
分类号:
TB43
DOI:
10.3969/j.issn.1001-3849.2022.10.010
文献标志码:
A
摘要:
研究了磷化时间对建筑结构钢表面锌钙系磷化膜的厚度、化学成分和耐蚀性的影响，并对锌钙系磷化膜的物相结构进行了分析。结果表明：随着磷化时间延长，磷化膜厚度逐渐增加，但达到一定限度后基本不变。在不同磷化时间下获得的 6 种磷化膜的化学成分均为 Zn 、 Ca 、 P 、 O 和 Fe 元素， Zn 、 Ca 和 P 的质量分数随着磷化时间延长均呈现先升高后下降的趋势，而 Fe 的质量分数显著下降后基本不变。 6 种磷化膜的耐蚀性存在一定差异。磷化 24 min 获得的磷化膜厚度达到 8.1 μ m ， Zn 、 Ca 和 P 的质量分数均达到最高，分别为 34.78 % 、 7.74 % 、 17.15 % ，电荷转移电阻和低频区的阻抗值分别达到 1937 Ω ·cm 2 、 1157 Ω ·cm 2 。该磷化膜的主要物相为 CaZn 2 （ PO 4 ） 2 ·2H 2 O ，耐蚀性相对较好。
Abstract:
： The effect of phosphating time on the thickness ， chemical components and corrosion r esistance of zinc-calcium phosphating films on the surface of building steel was studied ， and the phase structure of zinc-calcium phosphating film was also analyzed. The results showed that with the extension of phosphating time ， the thickness of phosphating films increased gradually ， but it remained nearly unchanged after reaching a certain limit. The chemical components of six phosphating films obtained at different phosphating time were all composed of Zn ， Ca ， P ， O and Fe. The mass fraction of Zn ， Ca and P all showed a trend of first increasing and then decreasing with the extension of phosphating time ， while the mass fraction of Fe remained nearly unchanged after a significant decrease. There was a significant difference between the corrosion resistance of six phosphating films. The thickness of phosphating film obtained by phosphating for 24 min reached 8.1 μ m ， and the mass fraction of Zn ， Ca and P reached 34.78 % ， 7.74 % and 17.15 % respectively. The charge transfer resistance and low f requency area impedance value reached 1937 Ω ·cm 2 and 1157 Ω ·cm 2 ， respectively. The main phase of the phosphating film was CaZn 2 （ PO 4 ） 2 ·2H 2 O ， and its corrosion resistance was relatively good.

参考文献/References:



[1] Soha A G.Enhancing corrosion resistance of galvanized steel by phosphating and silicate post-sealing[J]. International Journal of Electrochemical Science, 2018, 13(3):2688-2704.

[2] 姚知深 , 牛宗伟 , 刘斌 , 等 . 超声振动对 65 钢电解磷化膜表面形貌与耐蚀性的影响 [J]. 电镀与精饰 , 2019, 41(9): 24-28.

[3] 孙伟 , 范晓鹏 , 张伟华 . 磷化时间对建筑结构用钢板表面锌 - 锰系磷化膜性能的影响 [J]. 电镀与环保 , 2020, 40(1): 37-39.

[4] 胡国辉 . 金属磷化工艺技术 [M]. 北京 : 国防工业出版社 , 2009.

[5] 孟园月 . 合金钢表面锰系磷化膜成膜机理及性能研究 [D]. 沈阳 : 沈阳工业大学 , 2016.

[6] Chen J, Lan X N, Wang C.The formation mechanism and corrosion resistance of a composite phosphate conversion film on AM60 alloy[J]. Materials, 2018, 11(3):402-412.

[7] Xu J L, Xiao Q F, Tong Y X, et al. Microstructure, corrosion resistance and formation mechanism of alumina micro-arc oxidation coatings on sintered NdFeB permanent magnets[J]. Surface and Coatings Technology, 2017(309): 621-627.

[8] 张天翼 , 柳伟 , 范玥铭 . 海洋大气环境 Cu/Ni 协同作用对低合金钢耐蚀性影响 [J]. 中国腐蚀与防护学报 , 2019, 39(6): 511-518.

[9] 邹忠利 , 王北平 , 马金福 , 等 . AZ31B 镁合金氧化石墨烯掺杂钇盐转化膜耐蚀性研究 [J]. 表面技术 , 2018, 47(2): 164-170.

[10] 何保军 , 徐小宁 , 张国鹏 , 等 . 阳极氧化电流密度对热浸镀铝 45 钢耐蚀性能影响 [J]. 特种铸造及有色合金 , 2019, 39(10): 1151-1155.

[11] Mukhopadhyay A, Barman T K, Sahoo P. Corrosion resistance of electroless Ni-B-W-Mo coatings using electrochemical impedance spectroscopy[J]. Portugaliae Electrochimica Acta, 2019, 37(3): 193-203.

[12] Fernandez F, Alberro M, Garikano X, et al. Evaluation of the corrosion resistance of Ni(P)Cr coatings for bipolar plates by electrochemical impedance spectroscopy[J]. International Journal of Hydrogen Energy, 2020, 45(40): 20632-20646.

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备注/Memo

备注/Memo:
收稿日期： 2020-08-16 修回日期： 2020-09-16 * 通信作者： 孙伟（ 1981 —），女，硕士，副教授，主要研究方向：建筑结构材料，表面技术等。 email ： sun_huang0619@126.com 基金项目： 青岛黄海学院校级科研项目（ 2020KJ04 ）?/html>
更新日期/Last Update: 2022-11-10