Sun Wei*,Yang Hui,Xu Xiufeng,et al.Effects of accelerating agents on morphology and corrosion resistance of zinc-calcium phosphating films on building structural steel[J].Plating & Finishing,2023,(4):8-12.[doi:10.3969/j.issn.1001-3849.2023.04.002]
促进剂对建筑结构钢锌钙系磷化膜形貌和耐蚀性的影响
- Title:
- Effects of accelerating agents on morphology and corrosion resistance of zinc-calcium phosphating films on building structural steel
- Keywords:
- accelerating agents ; zinc-calcium phosphating films ; morphology ; composition ; corrosion resistance
- 分类号:
- TB43
- 文献标志码:
- A
- 摘要:
- 在含硝酸盐的基础磷化液中分别添加钼酸钠、硝酸镧以及它们的组合作为促进剂,在建筑结构钢表面制备出不同锌钙系磷化膜。研究了促进剂对不同磷化膜的形貌、成分和耐蚀性的影响。结果表明:钼酸钠、硝酸镧以及它们的组合作为促进剂都可以使磷化膜结晶致密化,进而提高磷化膜的耐蚀性。尤其是钼酸钠和硝酸镧的组合作为促进剂,可以明显改善磷化膜的形貌,获得的磷化膜具有良好的耐蚀性,其容抗弧半径最大,电荷转移电阻和低频时的阻抗值分别达到 2.476 k Ω ·cm 2 、 2.147 k Ω ·cm 2 ,表面的液滴变色时间达到 165 s 。硝酸镧作为促进剂不会对磷化膜的成分产生影响,而钼酸钠以及钼酸钠和硝酸镧的组合作为促进剂对磷化膜的成分有一定影响。使用含钼酸钠和硝酸镧的基础液获得的锌钙系磷化膜更适用于建筑结构钢防腐蚀保护。
- Abstract:
- : Different zinc-calcium phosphating films were prepared on the surface of building structural steel by adding sodium molybdate , lanthanum nitrate and their combination as accelerating agents to the basic phosphating solution containing nitrate. The effect of accelerating agents on the morphology , composition and corrosion resistance of different phosphating films was studied. The results showed that sodium molybdate , lanthanum nitrate and their combination as accelerating agents could promote crystallization densification and thus improve the corrosion resistance of phosphating films. Especially the combination of sodium molybdate and lanthanum nitrate as accelerating agents can obviously improve the morphology of phosphating films , and therefore the phosphating film has good corrosion resistance. The capacitive reactance arc radius was the largest , the charge transfer resistance and impedance at low frequency reached 2.476 k Ω ·cm 2 and 2.147 k Ω ·cm 2 respectively , and the discoloration time of droplet on the surface of phosphating film reached 165 s. Lanthanum nitrate used as accelerating agents has no effect on the composition of phosphating film , while sodium molybdate and the combination of sodium molybdate and lanthanum nitrate used as accelerating agents have some effect on the composition of phosphating film. The zinc-calcium phosphating film obtained using the basic phosphating solution con taining nitrate sodium molybdate and lanthanum nitrate was more suitable for anti-corrosion protection of building structural steel.
参考文献/References:
[1] 张巧云 , 陈泽民 , 张天金 . 硫酸羟胺作为促进剂时磷化的成膜机理及所得膜层的性能 [J]. 电镀与涂饰 , 2018, 37(23): 1075-1079.
[2] 齐三 . 用于金属冷塑性变形的新型环保磷化工艺及其应用研究 [D]. 合肥 : 合肥工业大学 , 2016.
[3] 张明明 , 张涵 , 张圣麟 . 三种促进剂对磷化膜耐蚀性的影响 [J]. 腐蚀与防护 , 2019, 40(3): 200-204.
[4] Xu Y D, Qi S, Wang L, et al. Effects of hydroxylamine sulfate and sodium nitrite on microstructure and friction behavior of zinc phosphating coating on high carbon steel[J]. Chinese Journal of Chemical Physics, 2015, 28(2): 197-202.
[5] 候萍萍 . 锌钙系常温磷化液的研究 [D]. 济南 : 山东大学 , 2008.
[6] Lwolek P, Dychton K, Pytel M. Orthophosphoric acid solutions of sodium orthovanadate, sodium tungstate, and sodium molybdate as potential corrosion inhibitors of the Al 2 Cu intermetallic phase[J]. Journal of Solid State Electrochemistry, 2019(23): 3019-3029.
[7] 李现涛 , 魏雨 . 钼酸钠在常温磷化中的作用 [J]. 材料保护 , 2009, 42(2): 35-36.
[8] Kuang J. Phosphatization coating-forming mechanism based on green phosphating accelerator rare earth nitrate[J]. Advanced Materials Research, 2013(838-841): 2806-2810.
[9] 郭国才 , 莫振宇 , 吴清源 , 等 . 稀土铈对中温锌系磷化的影响 [J]. 电镀与环保 , 2018, 38(4): 37-41.
[10] 董方 , 闫瑞军 , 杨宗佳 , 等 . 稀土铈对 22MnCrNiMo 钢耐腐蚀性能的影响 [J]. 中国冶金 , 2019, 29(1): 30-37.
[11] Wang Z H, Zhang J M, Li Y, et al. Corrosion resistance enhancement of micro-arc oxidation ceramic layer by Mg-Al-Co layered double hydroxide coating[J]. Transactions of the Indian Ceramic Society, 2020, 79(2): 59-66.
[12] Hussein M A, Adesina A Y, Kumar A M, et al. Mechanical, in-vitro corrosion, and tribological characteristics of TiN coating produced by cathodic arc physical vapor deposition on Ti 20 Nb 13 Zr alloy for biomedical applications[J]. Thin Solid Films, 2020(709): 138-183.
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备注/Memo
收稿日期: 2020-08-23 修回日期: 2020-09-16 作者简介 : 孙伟( 1981 —),女,硕士,副教授,主要研究方向:建筑结构材料,表面技术等, email : sun_huang0619@126.com 基金项目: 青岛黄海学院校级科研项目( 2020KJ04 )