[1]马冬威*,谭永星,邹 翔,等.doi: 10.3969/j.issn.1001-3849.2025.05.004工艺参数对Q235钢板锌系磷化膜微观形貌和耐蚀性的影响[J].电镀与精饰,2025,(05):24-29.
 Ma Dongwei*,Tan Yongxing,Zou Xiang,et al.Effects of parameters on the morphology and corrosion resistance of zinc based phosphating film on Q235 steel plates[J].Plating & Finishing,2025,(05):24-29.
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doi: 10.3969/j.issn.1001-3849.2025.05.004工艺参数对Q235钢板锌系磷化膜微观形貌和耐蚀性的影响()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年05
页码:
24-29
栏目:
出版日期:
2025-05-31

文章信息/Info

Title:
Effects of parameters on the morphology and corrosion resistance of zinc based phosphating film on Q235 steel plates
作者:
马冬威1*谭永星1邹 翔2胡志华1饶晓晓1
(1. 湖北汽车工业学院 汽车材料学院,湖北 十堰 442002 ;2. 湛江德利车辆部件有限公司,广东 湛江 524003)
Author(s):
Ma Dongwei1* Tan Yongxing1 Zou Xiang2 Hu Zhihua1 Rao Xiaoxiao1
(1. School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442002, China; 2. Zhanjiang Deni Vehicle Parts Co., Ltd., Zhanjiang 524003, China)
关键词:
Q235钢板工艺参数锌系磷化膜微观形貌耐腐蚀性能
Keywords:
Q235 steel plate process parameters zinc based phosphating film morphology corrosion resistance
分类号:
TG174.4
文献标志码:
A
摘要:
为提高商用车低碳钢板零部件的表面耐蚀性能,以Q235钢板为基体,采用不同磷化时间和磷化温度,在其表面制备出锌系磷化膜。通过扫描电镜、测厚仪、硫酸铜点滴试验、电化学工作站等测试方法,研究了磷化工艺参数对磷化膜微观形貌、膜厚及耐腐蚀性能的影响。结果表明,磷化工艺参数对磷化膜形貌及性能均有明显影响。当磷化温度为50 ℃,磷化时间为10 min时,基体表面可以获得均匀致密的磷化膜,膜厚为3 ?m,耐硫酸铜点滴时间为30 s,磷化膜自腐蚀电位较高且自腐蚀电流密度最小,优于其它工艺参数。
Abstract:
To improve the surface corrosion resistance of low-carbon steel plate components for commercial vehicles, a zinc based phosphating film was prepared on the surface of Q235 steel plate with different times and temperatures. The influence of phosphating process parameters on the microstructure, film thickness, and corrosion resistance of the phosphating film were studied using SEM, thickness gauge, performing bronze sulfate pitting test, electrochemical workstation and other test methods. The results show that the phosphating process parameters have a significant impact on the morphology and properties of the phosphating film. When the phosphating temperature is 50 ℃ and phosphating time is 10 minutes, the uniform and dense phosphating film can be obtained on the surface of substrate, and the film thickness is 3 ?m. The dripping time of copper sulfate is 30 s, and the self corrosion potential of phosphating film is high and the self corrosion current density is the minimum, which is superior to other process parameters

参考文献/References:

[1].蓝荣福. 车身磷化膜异常原因分析及措施探讨[J]. 涂料工业, 2019, 49(8): 69-74.
[2].张丽盆. 浅谈钢铁磷化前处理对磷化膜性能的影响[J]. 中国新技术新产品, 2019(1): 100-101.
[3].Thomas R, Alphin J J, Unock A, et al. A detailed study on the enhanced anti-corrosion properties of nano silicon dioxide additive influencing calcium modified zinc phosphate coating on mild steel[J]. International Journal of Surface Science and Engineering, 2022, 16(3): 207-225.
[4].王利艳, 咸庆军. 建筑结构用Q235钢超声波辅助锌-锰系磷化处理及耐蚀性研究[J]. 电镀与精饰, 2023, 45(8): 26-33.
[5].Foulad I M, Amadeh A. Effect of phosphating time and temperature on microstructure and corrosion behavior of magnesium phosphate coating[J]. Electrochimica Acta, 2013, 106(9): 1-12.
[6].赵利民, 王树凤. 磷化温度对齿轮钢表面锰系复合磷化膜性能的影响[J]. 电镀与精饰, 2021, 43(6): 10-14.
[7].Shetty A R, Chitharanjan H A. Ultrasound induced multilayer Ni-Co alloy coatings for better corrosion protection[J]. Surface and Coatings Technology, 2017, 322: 99-107.
[8].马冬威, 史秋月, 袁国民, 等. 工艺参数对38MnVS钢锰系磷化膜表面形貌和耐蚀性的影响[J]. 表面技术, 2017, 46(8): 221-225.
[9].Xie Y H, Chen M Z, Xie D L, et al. A fast, low temperature zinc phosphate coating on steel accelerated by graphene oxide[J]. Corrosion Science, 2017(128): 1-8.
[10].Abdel-Gawad S A, Sadik M A, Shoeib M A. Enhancing corrosion resistance of galvanized steel by phosphating and silicate post-sealing[J]. International Journal of Electrochemical Science, 2018, 13(3): 2688-2704.
[11].陈俊超, 张林海. 工艺参数对Q345钢锌系磷化膜耐腐蚀性能的影响[J]. 电镀与精饰, 2022, 42(8): 18-21.
[12].Sheila S F, Belén D, Raúl F, et al. A comprehensive structural and electrochemical study on the performance of Mn-phosphate layers[J]. Surface and Coatings Technology, 2024, 476: 130260.
[13].李继伟, 杨振宇, 翟欢乐. 钢结构连接螺栓锰系磷化及磷化膜的耐蚀性[J]. 电镀与精饰, 2022, 44(1): 50-56.
[14].崔学军, 刘春海, 李明田, 等. 工艺参数对AZ31镁合金磷化膜耐蚀性能及表面形貌的影响[J]. 中国腐蚀与防护学报, 2012, 32(6): 507-512.
[15].周艳丽. 电器件支架低温锌系磷化工艺研究[J]. 电镀与精饰, 2021, 43(4): 20-24.
[16].刘迎新, 余取民, 王开丽. 免水洗常温锰系磷化膜的制备与性能[J]. 腐蚀与防护, 2015, 36(12): 1153-1155.
[17].Li T, Wang S F, Liu H T, et al. Improved corrosion resistance of Mg alloy by a green phosphating: insights intopreactivation, temperature, and growth mechanism[J]. Journal of Materials Science, 2021, 56(1): 828-843.
[18].胡莲跃, 秦小强, 梁爽, 等. 磷化液中磷化渣的控制及磷化渣对磷化膜的影响[J]. 现代涂料与涂装, 2014, 17(8): 4-9.
[19].杨喜珠, 杨 刚. 提高磷化膜质量的除磷化渣技术研究[J]. 上海涂料, 2010, 48(8): 24-26.
[20].沟引宁, 苏勇要, 谭祖君, 等. Na2SiO3浓度对复合阳极氧化膜性能的影响[J]. 重庆理工大学学报(自然科学), 2017, 31(4): 45-49.
[21].张艳, 李倩, 张媛. 904L不锈钢在5g/L H2SO4溶液中的腐蚀行为[J]. 沈阳工业大学学报, 2015, 37(2): 236-240.

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更新日期/Last Update: 2025-05-19