Liu Yuanhai,Yin Fenglei,Mu Xianlian,et al.Preparation and corrosion resistance of Ni/Ag/Rh composite coatings on copper surface[J].Plating & Finishing,2024,(1):79-83.[doi:10.3969/j.issn.1001-3849.2024.01.012]
铜表面镍/银/铑复合镀层的制备及其耐腐蚀性研究?/div>
- Title:
- Preparation and corrosion resistance of Ni/Ag/Rh composite coatings on copper surface
- Keywords:
- composite coating ; Rh coating ; corrosion resistance ; electrodeposition
- 分类号:
- TQ153.1
- 文献标志码:
- A
- 摘要:
- 采用化学镀和电沉积的方法在紫铜片上制备了镍 / 银 / 铑复合镀层。使用光学显微镜和扫描电子显微镜（ SEM ）观察镍 / 银 / 铑复合镀层的微观结构；通过 X 射线能谱分析（ EDS ）检查镀层的化学组成；采用 X 射线衍射仪器（ XRD ）表征镀层的相结构和晶体结构；利用酸性盐雾实验测试了不同镍镀层厚度的镍 / 银 / 铑复合镀层在盐雾环境下的耐蚀性能。结果表明：各镀层之间结合紧密，镀层表面平整无孔隙；在其它条件相同的情况下，镍镀层厚的复合镀层的耐蚀性优于镍镀层薄的复合镀层。
- Abstract:
- ： Ni/Ag/Rh composite coatings were prepared on copper sheets by means of electroless plating and electrodeposition. The microstructure of Ni/Ag/Rh composite coating was observed by optical microscope and scanning electron microscope （ SEM ） . The chemical composition of the coating was checked by energy-dispersive X-ray spectroscopy （ EDS ） . The phase structure and crystal structure of the coating was characterized by X-ray diffraction instrument （ XRD ） . The corrosion resistance of Ni/Ag/Rh composite coatings with different nickel coating thicknesses in salt spray environments was tested using acidic salt spray experiments. The results show that the bonding between the coatings is tight ， and the surface of the coatings is flat without pores. Under the same other conditions ， the corrosion resistance of composite coatings with thick nickel coatings is better than that of composite coatings with thin nickel coatings.
参考文献/References:
[1] Weisberg A M. Rhodium plating[J]. Metal Finishing, 1999, 97(1): 292-296.
[2] 李一冉 , 姚力筝 , 董梓凝 , 等 . " 铑 " 有所 " 铱 "[J]. 大学化学 , 2021, 36(10): 23-27.
[3] 唐萌圣 . 电沉积贵金属铑 [J]. 材料保护 , 1998, 31(4): 19.
[4] Golvano-Escobal I, Surinach S, Baró M D, et al. Electrodeposition of sizeable and compositionally tunable rhodium-iron nanoparticles and their activity toward hydrogen evolution reaction[J]. Electrochimica Acta, 2016, 194: 263-275.
[5] Sathe B R. High aspect ratio rhodium nanostructures for tunable electrocatalytic performance[J]. Physical Chemistry Chemical Physics, 2013, 15(20): 7866-7872.
[6] 肖耀坤 , 钟美娥 , 张峰 , 等 . 铑电镀工艺的研究现状与展望 [J]. 材料保护 , 2005, 38(2): 37-40.
[7] 杨富国 . 不锈钢件镀铑工艺 [J]. 表面技术 , 2000, 29(6): 48-49.
[8] Abys J A, Dullaghan C A, Epstein P, et al. Rhodium sulfate compounds and rhodium plating: U.S. Patent 6,241,870[P]. 2001-6-5.
[9] Angus H C. Electrodeposition of rhodium and ruthenium for slip-ring surfaces[J]. Transactions of the IMF, 2017, 43(1): 135-142.
[10] Son S H, Lee H K, Park S C. Kinetics of rhodium electrodeposition for semiconductor interconnect applications[J]. Surface and Interface Analysis, 2010, 42(6‐7): 1244-1246.
[11] Wu W P, Liu J W, Zhang Y, et al. The influence of current density and bath temperature on electrodeposition of rhodium film from sulfate-phosphate aqueous solutions[J]. Journal of Applied Electrochemistry, 2019, 49(10): 1043-1054.
[12] 肖耀坤 , 张峰 , 王旭辉 , 等 . 不同基材上装饰性镀铑的电化学行为及镀层性能 [J]. 中国有色金属学报 , 2005, 15(2): 305-309.
[13] 孙金虎 , 李辉 , 钟庆东 , 等 . 镍 / 铜 / 锌多层镀层的制备及其耐蚀性 [J]. 腐蚀与防护 , 2017, 38(12): 928-932.
[14] 王建兴 , 黄少军 , 唐伦圆 , 等 . 镍 - 钴 / 镍 / 镍 - 钴镀层的制备及电化学性能 [J]. 材料保护 , 2012, 45(9): 17-20.
[15] Aliofkhazraei M, Walsh F C, Zangari G, et al. Development of electrodeposited multilayer coatings: A review of fabrication, microstructure, properties and applications[J]. Applied Surface Science Advances, 2021, 6: 100141.
[16] Khadem M, Penkov O V, Yang H K, et al. Tribology of multilayer coatings for wear reduction: A review[J]. Friction, 2017, 5(3): 248-262.
[17] 顾卓明 , 黄婉娟 . 耐磨复合镀层工艺的研究 [J]. 表面技术 , 2002(2): 14-17.
[18] 徐欣 , 李庆明 , 刘兴民 , 等 . 镍 - 金刚石复合镀层的制备工艺及耐磨性比较 [J]. 金属功能材料 , 2022, 29(1): 100-105.
[19] 杨奎 . 工艺参数对电沉积 Ni-Fe-SiC 复合镀层耐磨、耐蚀性能的影响 [D]. 长春 : 长春工业大学 , 2022.
[20] 顾卓明 , 黄婉娟 , 王仁兵 . 多层复合镀层工艺与性能的研究 [J]. 机械工程材料 , 2002, 26(10): 26-29.
[21] 费敬银 , 刘江宏 , 梁国正 , 等 . 电沉积法制备组分调制 Zn-Ni 合金多层镀层 [J]. 腐蚀科学与防护技术 , 2006, 18(1): 24-27.
相似文献/References:
[1]沈岳军*,罗华江,王少营,等.温度对Ni-P/PTFE复合镀层性能的影响[J].电镀与精饰,2019,(8):1.[doi:10.3969/j.issn.1001-3849.2019.08.001]
SHEN Yuejun*,LUO Huajiang,WANG Shaoying,et al.Effect of Temperature on the Properties of Ni-P/PTFE Composite Coating[J].Plating & Finishing,2019,(1):1.[doi:10.3969/j.issn.1001-3849.2019.08.001]
[2]王晓丽,顾海,赵紫怡,等.电沉积金属基复合镀层制备研究进展[J].电镀与精饰,2021,(8):44.[doi:10.3969/j.issn.1001-3849.2021.08.010]
WANG Xiaoli,GU Hai,ZHAO Ziyi,et al.Research Progress of Fabricating Metal-Matrix Composite Coating by Electrodeposition[J].Plating & Finishing,2021,(1):44.[doi:10.3969/j.issn.1001-3849.2021.08.010]
[3]赵金国*,乔 勋,阎治安.热处理对Ni-P-BN（h）镀层硬度和自润滑性能的影响[J].电镀与精饰,2022,(1):63.[doi:10.3969/j.issn.1001-3849.2022.01.011]
ZHAO Jinguo*,QIAO Xun,YAN Zhian.Effect of Heat Treatment on Hardness and Self-Lubrication of Ni-P-BN(h) Composite Coating[J].Plating & Finishing,2022,(1):63.[doi:10.3969/j.issn.1001-3849.2022.01.011]
[4]孙 伟,张淑婷*,杜开平,等.汽油机活塞顶面镀层的设计与仿真研究[J].电镀与精饰,2023,(2):79.[doi:10.3969/j.issn.1001-3849.2023.02.013]
Sun Wei,Zhang Shuting*,Du Kaiping,et al.Design and simulation research of electroplated coating on piston top of gasoline engine[J].Plating & Finishing,2023,(1):79.[doi:10.3969/j.issn.1001-3849.2023.02.013]
[5]姚伦芳,杨 强,刘定富*.纳米Al2O3颗粒掺杂对化学镀Ni-Cu-P镀层耐蚀性的影响[J].电镀与精饰,2023,(11):27.[doi:10.3969/j.issn.1001-3849.2023.11.004]
Yao Lunfang,Yang Qiang,Liu Dingfu*.Effect of nano-Al 2 O 3 doping on corrosion resistance of electroless Ni-Cu-P coating[J].Plating & Finishing,2023,(1):27.[doi:10.3969/j.issn.1001-3849.2023.11.004]
[6]周 鑫,王晓丽*,皇 磊,等.喷射复合电沉积技术研究进展[J].电镀与精饰,2024,(1):55.[doi:10.3969/j.issn.1001-3849.2024.01.009]
Zhou Xin,Wang Xiaoli*,Huang Lei,et al.Research progress of jet composite electrodeposition technology[J].Plating & Finishing,2024,(1):55.[doi:10.3969/j.issn.1001-3849.2024.01.009]
备注/Memo
收稿日期： 2023-08-31 修回日期： 2023-09-26 作者简介： 刘元海（ 1981 ―），男，硕士，研究员， email ： liuyuanhai100@163.com * 通信作者： 徐涛涛， email ： xutaotao105@126.com?/html>