Zhang Hongjun,Zhang Huailei.Effect of copper plating process on corrosion resistance of sliver coating Li Shanguang1,2,3*, Li Xiaozheng1,2,3, Lu Yajuan1,2,3, Shen Xiao1,2,3,[J].Plating & Finishing,2025,(04):78-82.
doi: 10.3969/j.issn.1001-3849.2025.04.012镀铜工艺对银镀层耐蚀性能的影响
- Title:
- Effect of copper plating process on corrosion resistance of sliver coating Li Shanguang1,2,3*, Li Xiaozheng1,2,3, Lu Yajuan1,2,3, Shen Xiao1,2,3,
- Keywords:
- aluminum alloy; corrosion resistance; density reduction
- 分类号:
- TM206
- 文献标志码:
- A
- 摘要:
- 针对高压电器用铝合金类零部件在服役过程中易发生腐蚀的现象,采用电镀工艺在6063铝合金表面制备银镀层,对中间铜镀层、预镀银层的表面微观形貌、耐蚀性进行观察和分析,研究镀铜工艺对镀层耐蚀性能的影响。结果表明,镀层致密度与耐蚀性能呈正比;低浓度镀铜溶液条件下,镀层致密度及耐蚀性能得到了提升;镀液中的杂质会影响镀层沉积的致密度,导致耐蚀性能降低;镀液添加剂对镀层致密度及耐蚀性能无明显改变。
- Abstract:
- In response to the corrosion phenomenon of aluminum alloy components used in high-voltage electrical appliances during service, a silver coating was prepared on the surface of 6063 aluminum alloy using electroplating technology. The surface microstructure and corrosion resistance of the intermediate copper and silver coatings were observed and analyzed, and the influence of copper plating technology on the corrosion resistance of the coating was studied. The results indicate that the density of the coating is directly proportional to its corrosion resistance. Under low concentration copper plating solution conditions, the density and corrosion resistance of the coating have been improved. Impurities in the plating solution affect the density of the deposited coating and reduce its corrosion resistance. The additive in the plating solution has no significant effect on the density and corrosion resistance of the coating
参考文献/References:
[1].郑克勤. 刀闸触头材料在电流下的腐蚀行为及银--石墨烯耐蚀涂层的研究[D]. 广东: 华南理工大学, 2019.
[2].郝留成, 廉继英, 周瑛, 等. 6063铝合金材料镀银层脱落原因及其解决途径[J]. 铸造技术, 2009, 30(10): 1350-1352.
[3].吴明孝, 刘涛, 杨威, 等. 开关柜梅花触头触片镀银层性能研究与分析[J]. 兵器材料科学与工程, 2022, 45(4): 80-84.
[4].陈川, 陈宜斌, 王宝凤, 等. 搅拌速率对银-石墨复合镀层耐蚀性和耐磨性的影响[J]. 腐蚀与防护, 2016, 37(11): 869-872.
[5].李宝增, 张颖杰, 刘畅, 等. 酸洗工艺对铝合金镀银质量的影响[J]. 电镀与精饰, 2015, 37(10): 28-31.
[6].马利民. 铸铝导体镀银工艺改进[J]. 高压电器, 2007, 43(5): 396-397.
[7].陈勿初. 高压电器铝合金镀银工艺[J]. 电镀与涂饰, 2011, 30(1): 22-23.
[8].王天鹏, 聂晓波, 孙明成, 等. 某沿海变电站HGIS套管接线端子镀银层腐蚀剥落的原因[J]. 腐蚀与防护, 2022, 43(5): 68-73.
[9].杨志远. 变电站设备导体材料腐蚀行为及防护技术研究[D]. 保定: 华北电力大学, 2018.
[10].王朝铭, 许赵武. 脉冲与直流电镀银层的耐蚀性试验[J]. 材料保护, 1998, 31(3): 35-36.
[11].付明. 铝及铝合金零件镀银前化学浸锌的工艺研究[J]. 材料保护, 2007, 40(1): 32-34.
[12].张祖军, 王勇. 铝合金化学镀Ni-P/Ni-B双层复合镀层及其性能研究[J]. 材料导报, 2006, 20(2): 342-344.
[13].敖辽辉. 毫米波铝合金腔体的整体化学氧化及其焊接处局部电镀银的处理效果[J]. 材料保护, 2015, 48(5): 60-61.
[14].陈康, 郭崇武. 高耐蚀性三价铬黑铬镀层制备工艺[J]. 电镀与涂饰, 2020, 39(3): 144-145.
[15].刘春敬, 袁军平, 黄宇亨. 银合金镀覆氮化锆薄膜的颜色及耐蚀性研究[J]. 电镀与涂饰, 2014, 33(3): 111-114.
[16].刘凯, 沈喜训, 马祥, 等. 氧化石墨烯强化银镀层的耐蚀性和耐磨性研究[J]. 电镀与精饰, 2024, 46(5): 11-19.
[17].陈晓丽, 沈晓, 张颖杰, 等. 6063铝合金镀银前处理工艺[J]. 电镀与涂饰, 2012, 31(10): 35-37.
[18].姚恩静. 铝及铝合金电刷镀银[J]. 电镀与精饰, 2001, 23(5): 32-34.
[19].胡云, 赵洪图. 锌-镍合金电镀工艺及镀层耐蚀性研究[J]. 电镀与环保, 2018, 38(6): 21-23.
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