Zhu Zhiyuan,Zhou Qi*,Xu Bin,et al.Study on the properties of Ni/Cr decorative electroplated deposits on carbon constructional steel[J].Plating & Finishing,2024,(4):10-17.[doi:10.3969/j.issn.1001-3849.2024.04.002]
碳素钢电镀Ni/Cr装饰性镀层性能的研究
- Title:
- Study on the properties of Ni/Cr decorative electroplated deposits on carbon constructional steel
- Keywords:
- electroplating ; double layer nickel ; porosity
- 分类号:
- TQ153.1
- 文献标志码:
- A
- 摘要:
- 碳素钢上电镀装饰性双层镍套铬的孔隙率、形貌、粗糙度、抗拉强度以及钝化性能决定产品的质量。用贴滤纸法测镀层的孔隙率，用形状测量激光显微系统测镀层的表面粗糙度和三维形貌，同时，测试了镀层的抗拉强度和电化学阻抗谱。结果显示： 60 # 和 55 # 两种碳素钢镀单层半光亮镍后直达基体铁的孔隙率都最多，平均数为 16.82 个· cm -2 ；除氢后相对于未除氢的镀铬层， 60 # 钢样品直达基体铁的孔隙率下降了 0.19 个· cm -2 ，而 55 # 钢样品的孔隙率增加了 1.46 个· cm -2 。 60 # 和 55 # 钢的单层镍表面粗糙度最高，分别为 0.460 μ m 和 0.523 μ m ，双层镍上镀铬后 60 # 钢样品的表面粗糙度降低了 0.036 μ m ，而 55 # 钢样品的表面粗糙度增加了 0.016 μ m ，除氢降低了铬镀层的粗糙度。镀铬镀层碳素钢抗拉强度最小，除氢不仅能提高镀铬后的抗拉强度，而且增加了 60 # 钢镀层的钝化性能。
- Abstract:
- ： The porosity ， morphology ， roughness ， tensile strength and passivation properties of the decorative double-layer Ni/Cr plated on carbon steel determine the quality of the product. The porosity of the coating was measured by the weting filter paper method ， the surface roughness and three-dimensional morphology of the coating were measured by the laser microscopy system ， and the tensile strength and electrochemical impedance spectrum of the coating were tested. The results showed that carbon steels 60 # and 55 # had the highest porosity of 16.82 pcs/cm 2 after being plated with a single layer of semi-bright nickel. Compared to the chrome-plated after hydrogen removal ， the porosity of 60 # steel sample decreased by 0.19 pcs/cm 2 ， while the porosity of the 55 # steel increased by 1.46 pcs/cm 2 . The single-layer nickel surface roughness of 60 # and 55 # steel was 0.460 μ m and 0.523 μ m ， respectively. The surface roughness of 60 # steel sample decreased by 0.036 μ m after chrome plating ， while the surface roughness of 55 # steel sample increased by 0.016 μ m ， hydrogen removal process decreased roughness of chrome plating. The tensile strength of carbon steel after chrome plating is the smallest ， and can not only im prove the tensile strength after chromium plating ， but also increase the passivation performance of the plating on 60 # steel.
参考文献/References:
[1] 王宗雄 , 彭海泉 , 王超 , 等 . 多层镀镍工艺及相关配方 [J]. 电镀与涂饰 , 2015, 34(16): 940-952.
[2] 袁诗璞 . 几种多层电镀工艺的讨论 [J]. 电镀与涂饰 , 2013, 32(6): 13-15.
[3] 王瑞祥 . 适用于摩托车零件的多层镍电镀工艺 [J]. 电镀与涂饰 , 1995(3): 12-15.
[4] 吴双成 . 多层镍电位差减小的原因和控制 [J]. 电镀与涂饰 , 2020, 39(19): 1324-1327.
[5] Pathak S, Guinard M, Vernooij G M, et al. Influence of lower current densities on the residual stress and structure of thick nickel electrodeposits[J]. Surface & Coatings Technology, 2011, 205: 3651-3657.
[6] Nasirpouri F, Sanaeian M R, Samardak A S, et al. An investigation on the effect of surface morphology and crystalline texture on corrosion behavior, structural and magnetic properties of electrodeposited nanocrystalline nickel films[J]. Applied Surface Science, 2014, 292(C): 795-805.
[7] Cheng W, Ge W,Yang Q, et al. Study on the corrosion properties of nanocrystalline nickel electrodepositied by reverse pulse current[J]. Applied Surface Science, 2013, 276: 604-608.
[8] Qin L Y, Lian J S, Jiang Q. Effect of grain size on corrosion behavior of electrodeposited bulk nanocrystalline Ni[J]. Transactions of Nonferrous Metals Society of China, 2010, 20(1): 82-89.
[9] Gu C D, Lian J S, He J T, et al. High corrosion-resistance nanocrystalline Ni coating on AZ91D magnesium alloy[J]. Surface & Coatings Technology, 2005, 200(18): 5413-5418.
[10] 曹鑫帅 , 陈云瑞 , 白亚慧 , 等 . 封闭工艺对薄镍耐蚀性的影响 [J]. 电镀与精饰 , 2021, 43(10): 36-40.
[11] 周永令 , 李金学 . 双层镍工艺在我厂的应用 [J]. 电镀与精饰 , 1987(3): 3 5-37.
[12] Rofagha R, Langer R, El-Sherik A M, et al.A comparison of the corrosion behaviour of nanocrystalline and normal crystalline nickel[J]. MRS Proceedings, 1991, 238: 751-751.
[13] 邝少林 , 范小平 , 杨暖辉 , 等 . 高耐蚀性多层镍体系及其在摩托车上的应用 (Ⅰ) ─ 多层镍电镀工艺 [J]. 电镀与涂饰 , 1995(3): 8-11.
[14] Edigaryan A A, Lubnin E N, Lyakhov B F, et al. Hydrogen content in chromium and multilayer nickel-chromium coatings deposited by periodic current[J]. Protection of Metals, 2003, 39(5): 405-410.
[15] Macnaughtan D J, Hothersall A W. The causes and prevention of pitting in electrodeposited nickel[J]. Transactions of the IMF, 2017, 4(1): 9-24.
[16] 赵金航 , 陈文举 . 影响镀铬层孔隙率的因素和解决措施 [J]. 新技术新工艺 , 2021(10): 41-43.
[17] Brenska J A, Lapinski J, Pletcher D, et al. Porosity of nickel electrodeposits on mild steel using electrochemical impedance spectroscopy[J]. Transactions of the IMF, 2012, 90(3): 156-160.
[18] Wang D G, Li F H, Shi Y, et al. Optimization of the preparation parameters of high-strength nickel layers by electrodeposition on mild steel substrates[J]. Materials, 2021, 14(18): 5461-5461.
[19] Yu Z M, Zhu Y K, Niu Y S, et al. Preparation and adhesion performance of multilayered Ni coatings deposited by ultrasonic-assisted electroplating[J]. Journal of Adhesion Science and Technology, 2013, 27(2): 136-142.
[20] 关山 , 张琦 , 吴隽贤 , 等 . 有机添加剂对镀铬阴极过程动力学的影响 [J]. 电镀与环保 , 2000(5): 6-8.
[21] 常季 , 陈吉 , 黄澳 . 热处理对 Ni-P 镀层耐硫酸露点腐蚀性能的影响 [J]. 金属热处理 , 2017, 42(2): 175-179.
[22] 贾卫平 , 姚井龙 , 雍帆 . 热处理对 Ni-TiN 纳米复合镀层结构和性能的影响 [J]. 表面技术 , 2017, 46(7): 110-116.
[23] 殷丽燕 . 采用电化学方法测量镀铬板表面金属铬和氧化铬的研究 [J]. 辽宁科技学院学报 , 2014, 16(4): 30-32.
[24] 李秀军 , 韦晓 , 薛彦鹏 . 镀铬板表面初始腐蚀机制的研究 [J]. 电镀与涂饰 , 2021,40(5): 369-376.
[25] 王心悦 , 王吉会 , 高志明 , 等 . 热处理对电沉积纳米晶铬镀层微观结构及耐蚀性的影响 [J]. 表面技术 , 2019, 48(12): 59-67.
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备注/Memo
收稿日期： 2023-03-22 修回日期： 2023-09-12 作者简介： 朱志远（ 1999 —），男，硕士研究生， email ： 2408899727@qq.com * 通信作者： 周琦（ 1970 —），女，博士，副教授，研究方向为电镀、涂装、涂料和电化学加工， email ： 18909829862@163.com 基金项目： 辽宁省重点研发计划项目（ 2020JH2/10100011 ）?/html>