ZHANG Qing,TAN Jun*,ZHAO Haichao,et al.Study on Dispersive Stability of Co-Ni Plating Solution Containing Cr3C2 Nano-Particles[J].Plating & Finishing,2020,(1):1-6.[doi:10.3969/j.issn.1001-3849.2020.01.001]
纳米Cr3C2颗粒在Co-Ni复合镀液中的分散稳定性研究
- Title:
- Study on Dispersive Stability of Co-Ni Plating Solution Containing Cr3C2 Nano-Particles
- 文献标志码:
- A
- 摘要:
- 采用超声破碎法制备了含纳米Cr3C2颗粒的钴镍镀液,研究了未加分散剂,以非离子型高分子分散剂改性和以阴离子分散剂改性三种情况下的镀液性能。通过激光粒度仪、镀层中颗粒复合量等测试方法对纳米Cr3C2颗粒钴镍镀液的稳定性进行了表征。结果表明,含纳米Cr3C2颗粒钴镍镀液通过阿拉伯树胶高分子型分散剂改性后,镀液的稳定性最佳,当阿拉伯树胶添加量为0.3 g/L,超声时间为0.5 h时,所得纳米Cr3C2颗粒钴镍镀液的稳定性最好。
- Abstract:
- Cobalt-nickel plating bath containing Cr3C2 nano-particles was prepared by ultrasonication. The properties of the plating bath without dispersant, modified by non-ionic macromolecule dispersant and modified by anionic dispersant were studied. The stability of Co-Ni plating solution containing Cr3C2 nano-particles was characterized by the method of laser particle size analysis and particle composite amount. The results indicate that the Co-Ni plating solution containing Cr3C2 nano-particles modified by gum arabic polymer dispersant has optimal dispersion stability. When the amount of gum arabic is 0.3 g/L and the ultrasonic time is 0.5 h, the Co-Ni plating solution containing Cr3C2 nano-particles has the best stability.
参考文献/References:
[1] Wang J, Zhou G, Chen C, et al. Acute Toxicity and biodistribution of different sized titanium dioxide particles in mice after oral administration[J]. Toxicol Lett, 2007, 168(2): 176-185.
[2] Wang J, Fan Y, Gao Y, et al. TiO2 nanoparticles translocation and potential toxicological effect in rats after intraarticular injection[J]. Biomaterials, 2009, 30(27): 4590-4600.
[3] 李萌, 张小平, 周存龙, 等. 镍基纳米复合镀层的研究现状[J]. 电镀与精饰, 2016, 38(11): 24-28.
[4] 张文, 李保松, 环宇星, 等. Ni-W/SiC纳米复合镀层的制备与其耐蚀性[J]. 腐蚀与防护, 2017, 38(4): 247-251.
[5] 王琳, 路金林, 刘坤, 等. 电沉积方式对Ni-SiC纳米复合镀层性能的影响[J]. 表面技术, 2017, 46(6): 180-184.
[6] 李风生, 崔平, 杨毅, 等. 微纳米粉体后处理技术及应用[M]. 北京: 国防工业出版社, 2005: 12-14.
[7] 崔洪梅, 刘宏, 王继扬, 等. 纳米粉体的团聚与分散[J]. 机械工程材料, 2004, 28(8): 38-41.
[8] 王文芳, 吴玉程, 郑玉春, 等. 纳米SiO2/Cu复合镀层的制备和组织性能研究[J]. 材料保护, 2004, 37(2): 15-16.
[9] 苏永堂, 成旦红, 张庆, 等. 银-纳米SiO2脉冲复合电镀工艺条件的优化与性能研究[J]. 电镀与涂饰, 2005, 24(10): 5-7.
[10] 李峰, 夏法锋, 高媛媛, 等. 超声电沉积在制备纳米复合镀层中的研究进展[J]. 材料导报, 2016, 30(3): 125-127.
[11] 汪笑鹤. 代硬铬纳米电刷镀镍钴合金镀层的制备及性能研究[D]. 装甲兵工程学院, 2014.
[12] 卢志宇, 郑涛, 张磊. 镍-磷-纳米二氧化钛化学复合镀制备工艺影响探究[J]. 电子测试, 2014(11):150-152.
[13] Kartal M, Uysal M, Gul H, et al. Effect of surfactant concentration in the electrolyte on the tribological properties of nickel-tungsten carbide composite coatings produced by pulse electro co-deposition[J]. Applied Surface Science, 2015, 354: 328-336.
[14] 亓新华, 王红娟. 纳米微粒在镀液中的分散与稳定[J]. 材料保护, 2006, 39(1): 31-35.
[15] 许崇海, 肖光春, 张荣波, 等. Al2O3和ZrO2纳米粉体悬浮液稳定性研究[J]. 稀有金属材料与工程, 2008, 37(s1): 607-610.
备注/Memo
收稿日期: 2019-06-18;修回日期: 2019-07-27
通信作者: 谭俊, email: tanjuncn@sina.com