PDF下载 分享
[1]李秋艺.建筑结构钢表面锌系复合磷化膜的制备及耐蚀性研究[J].电镀与精饰,2021,(4):16-19.[doi:10.3969/j.issn.1001-3849.2021.04.004]
　LI Qiuyi.Preparation and Corrosion Resistance of Zinc Composite Phosphating Film on Surface of Building Structural Steel[J].Plating & Finishing,2021,(4):16-19.[doi:10.3969/j.issn.1001-3849.2021.04.004]
点击复制

建筑结构钢表面锌系复合磷化膜的制备及耐蚀性研究

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG] 卷: 期数: 2021年4 页码: 16-19 栏目: 出版日期: 2021-04-15
Title:
Preparation and Corrosion Resistance of Zinc Composite Phosphating Film on Surface of Building Structural Steel
作者:
李秋艺
福州外语外贸学院 理工学院，福建 福州 350202
Author(s):
LI Qiuyi
College of Science and Technology， Fuzhou University of International Studies and Trade，Fuzhou 350202， China
关键词:
耐蚀性; 锌系复合磷化膜; 纯锌系磷化膜; 建筑结构钢
Keywords:
corrosion resistance zinc composite phosphating film zinc phosphating film bulding structural steel
DOI:
10.3969/j.issn.1001-3849.2021.04.004
文献标志码:
A
摘要:
将纳米SiO2颗粒添加到磷化液中，在建筑结构钢表面制备出锌系复合磷化膜，并与纯锌系磷化膜进行了比对。结果表明：两种磷化膜都完全覆盖了基体，且都呈断层状形貌，锌系复合磷化膜的晶粒空隙被纳米SiO2颗粒填补，其含量约为7.54%。两种磷化膜的耐蚀性都好于建筑结构钢，且锌系复合磷化膜的耐蚀性最好。纳米SiO2颗粒在一定程度上填补了晶粒空隙，有效阻碍了腐蚀介质通过晶粒空隙渗透和扩散，从而保证锌系复合磷化膜具有较好的耐蚀性，使建筑钢构件能更好的满足防腐蚀要求。
Abstract:
Zinc composite phosphating film was prepared on the surface of building structural steel from the phosphating solution containing nano-SiO2 particles, and the comparison test was carried out with the pure zinc-based phosphating film. The results showed that two kinds of phosphating films completely covered the matrix and presented fault-like morphology. The grain voids of zinc composite phosphating film were filled by nano-SiO2 particles, and the content was about 7.54%. The corrosion resistances of two kinds of phosphating films were better than that of building structural steel, and zinc composite phosphating film showed the best corrosion resistance. The grain gaps of zinc composite phosphating film were filled by nano-SiO2 particles, which effectively prevent the penetration and diffusion of corrosive media through the grain gaps, so as to ensure that zinc composite phosphating film having good corrosion resistance and can better meet the corrosion prevention requirements of building steel components.

参考文献/References:

[1] 陈雪婷.紧固件表面磷化工艺及耐蚀性研究[D]. 沈阳:沈阳工业大学,2016.
[2] Yuan H, Wang J, Chen J. Phosphate coating on stainless steel prepared in electrolyte with silica sol: zinc segregation, post-treatment and corrosion resistance[J]. The International Journal of Corrosion Processes and Corrosion Control, 2014, 49(3): 197-203.
[3] 孙海静,崔可秀.Mg-Gd-Y-Zr镁合金表面锰系磷化膜的制备工艺及性能研究[J]. 腐蚀科学与防护技术,2018,30(3):222-228.
Sun H J, Cui K X. Phosphate process and performance of manganese phosphate film on Mg-alloy Mg-Gd-Y-Zr[J]. Corrosion Science and Protection Technology, 2018, 30(3): 222-228.
[4] 张丽盆.浅谈钢铁磷化前处理对磷化膜性能的影响[J]. 中国新技术新产品,2019(1):100-101.
Zhang L P. Briefly discussion on the influence of steel phosphating pretreatment on properties of phosphating film[J]. China New Technologies and Progucts, 2019(1): 100-101.
[5] 李勇,陈小平,王向东,等.后处理工艺对磷化膜耐蚀性的影响[J]. 材料保护,2016,49(10):49-52.
Li Y, Chen X P, Wang X D, et al. Effect of post-treatment process on corrosion resistance of phosphating film [J]. Materials Protection, 2016, 49(10): 49-52.
[6] 张涵.镀锌钢板表面磷化膜的制备与性能研究[D]. 新乡:河南师范大学,2018.
[7] 高俊国,赵贺,李霞,等.纳米SiO2/低密度聚乙烯复合材料的陷阱特性与电击穿机制[J]. 复合材料学报,2019,36(4): 801-810.
Gao J G, Zhao H, Li X, et al. Trap characteristics and electric breakdown mechanism of SiO2/low density polyethylene nanocomposites [J]. Acta Materiae Compositae Sinica, 2019, 36(4): 801-810.
[8] Fan Y G, Li G N, Chen B, et al. Study on corrosion behavior of 16MnR in the circulating water system [J]. Applied Mechanics and Materials, 2013(457-458): 11-14.
[9] 王暾.电化学法快速评价无镀铜焊丝防锈性能的研究[J]. 热加工工艺,2017,46(23):47-49.
Wang T. Study on rapid evaluation of antirust property of non-copper coated wire by electrochemical method [J]. Hot Working Technology, 2017, 46(23): 47-49.

相似文献/References:

[1]宿 辉,栾柏瑞.AZ91D镁合金表面无铬无氟前处理工艺研究[J].电镀与精饰,2019,(1):10.[doi:10.3969/j.issn.1001-3849.2019.01.003]
　XU Hui,LUAN Bairui.Study on Chromium?Free and Fluorine?Free PretreatmentProcess of AZ91D Magnesium Alloy[J].Plating & Finishing,2019,(4):10.[doi:10.3969/j.issn.1001-3849.2019.01.003]
[2]徐美玲,亢淑梅,陈婷婷,等.添加氯化铈对镁合金Ni?P化学镀镀层性能影响[J].电镀与精饰,2019,(1):37.[doi:10.3969/j.issn.1001-3849.2019.01.008]
　XU Meiling,KANG Shumei,CHEN Tingting,et al.Properties of Electroless Plating Ni?P on Magnesium AlloySubstrate by Adding CeCl3[J].Plating & Finishing,2019,(4):37.[doi:10.3969/j.issn.1001-3849.2019.01.008]
[3]刘军松,刘定富,苏 琪,等.有机添加剂对电镀Zn-Ni-P合金的影响[J].电镀与精饰,2019,(7):6.[doi:10.3969/j.issn.1001-3849.2019.07.002]
　LIU Junsong,LIU Dingfu,SU Qi,et al.Effect of Organic Additives on Zn-Ni-P Alloy Electroplating[J].Plating & Finishing,2019,(4):6.[doi:10.3969/j.issn.1001-3849.2019.07.002]
[4]颜晨曦,宋娟娟,曹建平,等.全氢聚硅氮烷涂层制备及其性能[J].电镀与精饰,2019,(7):14.[doi:10.3969/j.issn.1001-3849.2019.07.004]
　YAN Chenxi,SONG Juanjuan,CAO Jianping,et al.Preparation and Properties of Perhydropolysilazane Coating[J].Plating & Finishing,2019,(4):14.[doi:10.3969/j.issn.1001-3849.2019.07.004]
[5]姚知深,牛宗伟*,刘 斌,等.超声振动对65钢电解磷化膜表面形貌与耐蚀性的影响[J].电镀与精饰,2019,(9):24.[doi:10.3969/j.issn.1001-3849.2019.09.005]
　YAO Zhishen,NIU Zongwei*,LIU Bin,et al.Effect of Ultrasonic Vibration on Surface Morphology and Corrosion Resistance of 65 Steel Electrolytic Phosphating Film[J].Plating & Finishing,2019,(4):24.[doi:10.3969/j.issn.1001-3849.2019.09.005]
[6]李佳霖,郝建军,牟世辉.Fe2+对镁合金电化学磷化改性研究[J].电镀与精饰,2019,(10):1.[doi:10.3969/j.issn.1001-3849.2019.10.001]
　LI Jialin,HAO Jianjun,MOU Shihui.Study on Electrochemical Phosphating Modification of Magnesium Alloy by Fe2+[J].Plating & Finishing,2019,(4):1.[doi:10.3969/j.issn.1001-3849.2019.10.001]
[7]雷同鑫,鞠 辉,张长科,等.电镀Ni-W-P合金在钻杆接头上的应用[J].电镀与精饰,2019,(10):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
　LEI Tongxin,JU Hui,ZHANG Changke,et al.Application of Ni-W-P Alloy Prepared by Electroplating to Tool Joints[J].Plating & Finishing,2019,(4):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
[8]贾启华,许晓娟*.沉积时间对镁合金化学镀镍的影响[J].电镀与精饰,2019,(12):1.[doi:10.3969/j.issn.1001-3849.2019.12.001]
　JIA Qihua,XU Xiaojuan*.Effect of Deposition Time on Direct Electroless Plating of Magnesium Alloys[J].Plating & Finishing,2019,(4):1.[doi:10.3969/j.issn.1001-3849.2019.12.001]
[9]李 博*,赵金航,肖细军.电镀锌-镍合金替代镀镉、镀镉-钛工艺研究[J].电镀与精饰,2020,(3):43.[doi:10.3969/j.issn.1001-3849.2020.03.009]
　LI Bo*,ZHAO Jinhang,XIAO Xijun.Process Research on Electroplating of Zinc-Nickel Alloy Instead of Cadmium Plating and Cadmium-Titanium Plating[J].Plating & Finishing,2020,(4):43.[doi:10.3969/j.issn.1001-3849.2020.03.009]
[10]黄章崎,石海明,朱惠文,等.可溶性镍阳极对电镀镍性能的影响[J].电镀与精饰,2020,(6):1.[doi:10.3969/j.issn.1001-3849.2020.06.0010]
　HUANG Zhangqi,SHI Haiming,ZHU Huiwen,et al.Effect of Soluble Nickel Anode on the Performance of Electroplated Nickel[J].Plating & Finishing,2020,(4):1.[doi:10.3969/j.issn.1001-3849.2020.06.0010]
[11]张 翔?,李秋艺.SiO2颗粒分散液浓度对建筑结构钢锌系复合磷化膜耐蚀性的影响[J].电镀与精饰,2020,(12):10.[doi:10.3969/j.issn.1001-3849.2020.12.0030]
　ZHANG Xiang,LI Qiuyi.Effect of Concentration of SiO2 Particles Dispersion Solution on Corrosion Resistance of Zinc Composite Phosphating Film on Surface of Building Structural Steel[J].Plating & Finishing,2020,(4):10.[doi:10.3969/j.issn.1001-3849.2020.12.0030]

备注/Memo

收稿日期：2020-06-08；修回日期： 2020-06-18
作者简介： 李秋艺，硕士，讲师，E-mail：qiu_20teacher@sina.com
基金项目： 福建省教育厅中青年教师教育科研项目（JAT190908）

更新日期/Last Update: 2021-04-10