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[1]宋 浩 *,方 圆,石云光,等.镀锡板边部漆膜附着力影响因素研究[J].电镀与精饰,2022,(11):47-52.[doi:10.3969/j.issn.1001-3849.2022.11.009]
　SONG Hao *,FANG Yuan,SHI Yunguang,et al.Study of Influence Factors on the Edge Lacquer Adhesion of Tinplate[J].Plating & Finishing,2022,(11):47-52.[doi:10.3969/j.issn.1001-3849.2022.11.009]
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镀锡板边部漆膜附着力影响因素研究

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG] 卷: 期数: 2022年11 页码: 47-52 栏目: 出版日期: 2022-11-15
Title:
Study of Influence Factors on the Edge Lacquer Adhesion of Tinplate
作者:
（1.首钢集团有限公司技术研究院，北京 100043； 2.绿色可循环钢铁流程北京市重点实验室，北京 100043； 3.首钢京唐钢铁联合有限公司，河北 唐山 063200）
Author(s):
( 1.Shougang Research Institute of Technology Shougang Group Beijing 100043 China 2.Beijing key Laboratory of Green Recyclable Process for Iron & Steel Production Technology Beijing 100043 China 3.Shougang Jingtang United Iron & Steel Co. Ltd. Tangshan 063200 China )
关键词:
镀锡板; 漆膜附着力; 钝化电量; 边缘效应
Keywords:
tinplate ;  lacquer adhesion ;  passivation charge ;  edge effect
分类号:
TG174
DOI:
10.3969/j.issn.1001-3849.2022.11.009
文献标志码:
A
摘要:
针对镀锡板边部漆膜附着力性能不良的问题，通过白光干涉仪、电化学工作站、附着力螺旋测试仪及 X 射线光电子能谱分析，研究了镀锡板边部表面形貌、锡含量和钝化膜对镀锡板边部漆膜附着力的影响，研究结果表明：镀锡板边部的表面形貌、锡含量和钝化膜与中部存在明显差异。镀锡板边部 2 cm 处的锡含量是中部的 1.48 倍，边部锡含量的增加导致了边部粗糙度的下降。镀锡板边部 2 cm 处钝化膜的铬含量是中部的 1.22 倍， 随钝化膜锡含量的增加，镀锡板的漆膜附着力性能呈现明显的下降趋势。随钝化电量升高，边部 2 cm 处附着力变差，在钝化膜与锡层间发生断裂导致了漆膜脱落。
Abstract:
： To the problem of poor lacquer adhesion on the edge of the tinplate ， the effect of surface morphology ， tin content and passivation film on the edge lacquer adhesion were studied by white light interferometer ， electrochemical workstation ， adhesion spiral tester and X-ray photoelectron spectroscopy analysis. The research results show that the surface morphology ， tin content and passivation film on the edge of the tinplate are significantly different from those on the middle. The tin content at 2 cm of the edge is 1.48 times that of the middle. The increase of tin content in the edge part leads to a decrease in the roughness. The passivation film content at 2 cm of the edge part is 1.22 times that of the middle part. With the increase of passivation film content on the surface ， the lacquer adhesion shows a significant downward trend. With the increase of the passivation charge ， the proportion of metal chromium decreases ， the bridging force of metal chromium decreases ， and the fracture between the passivation film and the tin layer causes the lacquer film to fall off.

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备注/Memo

收稿日期： 2022-02-28 修回日期： 2022-03-20 作者简介： 宋浩（ 1988 —），男，硕士，中级工程师， email ： songhao19880405@163.com?/html>

更新日期/Last Update: 2022-11-12