PDF下载 分享
[1]孙 宇*,陈艺敏,石云光,等. 气雾阀用镀锡板表面黑点缺陷分析 [J].电镀与精饰,2023,(12):110-115.[doi:doi ： 10.3969/j.issn.1001-3849.2023.12.016]
　Sun Yu*,Chen Yimin,Shi Yunguang,et al.Black point defect analysis of tinplate for aerosol valve[J].Plating & Finishing,2023,(12):110-115.[doi:doi ： 10.3969/j.issn.1001-3849.2023.12.016]
点击复制

气雾阀用镀锡板表面黑点缺陷分析

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG] 卷: 期数: 2023年12 页码: 110-115 栏目: 出版日期: 2023-12-15
Title:
Black point defect analysis of tinplate for aerosol valve
作者:
（1.首钢京唐钢铁联合有限责任公司，河北 唐山 063200；
2.首钢集团有限公司技术研究院，北京 100043）
Author(s):
（1.Shougang Jingtang Iron & Steel United Co.， Ltd.， Tangshan 063200， China；
2.Shougang Research Institute of Technology， Beijing 100043， China）
关键词:
镀锡板; 气雾阀; 黑点; 锡层; 合金层
Keywords:
tinplate ;  mist valve ;  black spot ;  tin layer ;  alloy layer
分类号:
TG174
DOI:
doi ： 10.3969/j.issn.1001-3849.2023.12.016
文献标志码:
A
摘要:
采用电子显微镜配合能谱分析、镀锡板模拟气雾阀酒精浸泡实验和电化学实验，对气雾阀经过酒精浸泡后出现黑点缺陷的发生原因进行分析。实验结果表明，气雾阀在酒精中产生黑点缺陷的原因为气雾阀表面锡层会受到破坏而暴露出合金层。合金层与纯锡层同时暴露于酒精中组成电偶，发生了电化学腐蚀。
Abstract:
： The causes of black spot defects after alcohol immersion in aerosol valve were analyzed by means of electron microscope combined with energy spectrum analysis ， tinplate simulated aerosol valve alcohol immersion experiment and electrochemical experiment. The experimental results show that the reason for the black spot defect of the aerosol valve in alcohol is that the tin layer on the surface of the aerosol valve will be damaged and the alloy layer will be exposed. The alloy layer and the pure tin layer were exposed to alcohol at the same time to form a galvanic couple ， and electrochemical corrosion occurred.

参考文献/References:



[1] 王晓东 , 黄久贵 , 李建中 , 等 . 国内外镀锡板生产发展状况 [J]. 上海金属 , 2008, 30(4): 45-48.

[2] 徐瑞东 , 王军丽 , 薛方勤 , 等 . 锡合金镀层工艺的研究现状及展望 [J]. 电镀与涂饰 , 2003, 22(3): 44-50.

[3] Catalá R, Cabae?s J M, Bastidas J M. An impedance study on the corrosion properties of lacquered tinplate cans in contact with tuna and mussels in pickled sauce[J]. Corrosion Science, 1998, 40(9): 1455-1467.

[4] 冯叶琳 , 丁运虎 , 毛祖国 , 等 . 电气铜排镀锡层的防护性能研究 [J]. 材料保护 , 2021, 54(6): 112-116.

[5] Chen S, Xie L, Xue F. X-ray photoelectron spectroscopy investigation of commercial passivated tinplate surface layer[J]. Applied Surface Science, 2013, 276: 454-457.

[6] 周其良译 . 镀锡薄钢板 [M]. 北京 : 冶金工业出版社 , 1977.

[7] 全国包装标准化技术委员会 . GB/T 17447 — 2012[S]. 北京 : 中国标准出版社 , 2013.

[8] 黄久贵 . 冷轧板表面氧化膜对镀锡板性能的影响 [J]. 电镀与涂饰 , 2021, 40(23): 1798-1802.

[9] 石云光 , 方圆 , 宋浩 , 等 . 镀锡板在氯化钠溶液中的腐蚀行为研究 [J]. 材料保护 , 2019, 52(8): 69-73.

[10] Xia D H, Song S Z, Wang J H, et al. Corrosion behavior of tinplate in NaCl solution[J]. Transactions of Nonferrous Metals Society of China, 2012, 22(3): 717-724.

相似文献/References:

[1]许姣姣*.镀锡板铬酸钝化工艺研究[J].电镀与精饰,2021,(7):56.[doi:10.3969/j.issn.1001-3849.2021.07.011]
　XU Jiaojiao*.Process Research of Chromic acid Passivation on the Tinplate[J].Plating & Finishing,2021,(12):56.[doi:10.3969/j.issn.1001-3849.2021.07.011]
[2]宋 浩 *,方 圆,石云光,等.镀锡板边部漆膜附着力影响因素研究[J].电镀与精饰,2022,(11):47.[doi:10.3969/j.issn.1001-3849.2022.11.009]
　SONG Hao *,FANG Yuan,SHI Yunguang,et al.Study of Influence Factors on the Edge Lacquer Adhesion of Tinplate[J].Plating & Finishing,2022,(12):47.[doi:10.3969/j.issn.1001-3849.2022.11.009]
[3]周桂海*,王德智,胡宏卫.电感耦合等离子原子发射法测定镀锡板中钝化锆[J].电镀与精饰,2022,(11):95.[doi:10.3969/j.issn.1001-3849.2022.11.017]
　ZHOU Guihai*,WANG Dezhi,HU Hongwei.Determination of Passivated Zirconium of Tin Plate by Inductively Coupled Plasma Atomic Emission Spectrometry[J].Plating & Finishing,2022,(12):95.[doi:10.3969/j.issn.1001-3849.2022.11.017]
[4]宋浩,杨鸿建,吴明辉*,等.镀锡板硫化斑分析及控制工艺研究[J].电镀与精饰,2022,(12):54.[doi:10.3969/j.issn.1001-3849.2022.12.008]
　SONG Hao,YANG Hongjian,WU Minghui*,et al.Analysis and Control Technology of Sulfide Staining on Tinplate[J].Plating & Finishing,2022,(12):54.[doi:10.3969/j.issn.1001-3849.2022.12.008]
[5]万一群,齐韦*,沈鹏杰,等.基板表面形貌对镀锡板润湿能力影响的研究[J].电镀与精饰,2023,(4):38.[doi:10.3969/j.issn.1001-3849.2023.04.007]
　Wan Yiqun,Qi Wei*,Shen Pengjie,et al.Study on blackplate surface morphology effect on wettability for tinplate[J].Plating & Finishing,2023,(12):38.[doi:10.3969/j.issn.1001-3849.2023.04.007]
[6]吴明辉,王振文,石云光,等.镀锡板耐黑变性能影响因素研究[J].电镀与精饰,2023,(5):80.[doi:10.3969/j.issn.1001-3849.2023.05.011]
　Wu Minghui,Wang Zhenwen,Shi Yunguang,et al.Study on influencing factors of blackening resistance of tinplate[J].Plating & Finishing,2023,(12):80.[doi:10.3969/j.issn.1001-3849.2023.05.011]
[7]宋乙峰,王悦鼎,岳重祥*,等.表面膜层对镀锡板表面张力及印铁缩孔的影响[J].电镀与精饰,2023,(12):8.[doi:doi ： 10.3969/j.issn.1001-3849.2023.12.002]
　Song Yifeng,Wang Yueding,Yue Chongxiang*,et al.Effect of surface films on surface tension of tinplate and shrinkage hole during printing?/html>[J].Plating & Finishing,2023,(12):8.[doi:doi ： 10.3969/j.issn.1001-3849.2023.12.002]
[8]陈艺敏 *,孙 宇,常树林,等.不同工艺条件对低锡量镀锡板耐蚀性的影响莫志英?/span>[J].电镀与精饰,2024,(1):34.[doi:10.3969/j.issn.1001-3849.2024.01.006]
　Chen Yimin*,Sun Yu,Chang Shulin,et al.Effect of different process conditions on the corrosion resistance of low tin content tinplate[J].Plating & Finishing,2024,(12):34.[doi:10.3969/j.issn.1001-3849.2024.01.006]
[9]周桂海*,王德智.紫外分光光度法测定电镀锡板表面涂油量[J].电镀与精饰,2024,(7):116.[doi:10.3969/j.issn.1001-3849.2024.07.018]
　Zhou Guihai *,Wang Dezhi.Determination of surface oil on electrolytic tinplate by ultraviolet photometry[J].Plating & Finishing,2024,(12):116.[doi:10.3969/j.issn.1001-3849.2024.07.018]
[10]王爱红,杨鸿建,闫建升,等.doi: 10.3969/j.issn.1001-3849.2025.02.003 可溶性阳极高速镀锡机组锡层均匀性控制策略研究[J].电镀与精饰,2025,(02):17.
　Wang Aihong,Yang Hongjian,Yan Jiansheng,et al.Research on tin layer uniformity control strategy of soluble anode high speed tinning unit[J].Plating & Finishing,2025,(12):17.

备注/Memo

收稿日期： 2022-08-22 修回日期： 2023-09-11 * 通信作者： 孙宇（ 1987 — ），硕士研究生，工程师， email ： sunyusuper@126.com?/html>

更新日期/Last Update: 2023-12-13