Ding Yi * Liu Hanyu Zhang Xiaolin Feng Xiao Chen Feng Deng Bomeng.Feasibility study of boric acid-sulfuric acid sulfuric acid tartaric acid-sulfuric acid instead of chromic acid anodic oxidation[J].Plating & Finishing,2024,(11):43-48.
硼硫酸、硫酸、酒石酸替代铬酸阳极氧化的可行性研究
- Title:
- Feasibility study of boric acid-sulfuric acid sulfuric acid tartaric acid-sulfuric acid instead of chromic acid anodic oxidation
- 关键词:
- 铝合金; 硼酸 - 硫酸阳极氧化; 铬酸阳极氧化; 替代
- Keywords:
- aluminum alloy ; boronic-sulfuric acid anodizing ; chromic acid anodizing ; replacing
- 分类号:
- TQ153.6
- 文献标志码:
- A
- 摘要:
- 铝合金因其重量低、良好的强度、刚度和塑性等特点，广泛用于航空制造产业。铝合金基体在使用前会设计一个较为复杂的组合防护方案来提高耐蚀性，通常使用的方案是阳极氧化加漆层防护。随着航空制造业向高端化和绿色化发展，常用的铬酸阳极氧化因六价铬的毒性被替代的声音越发强烈。本文从发明历史，性能，环保影响、使用成本几个维度，综合比较了铬酸、硼酸 - 硫酸、硫酸、酒石酸 - 硫酸阳极氧化的工艺，研究显示硼酸 - 硫酸阳极氧化在耐蚀性、疲劳极限、绿色环保、使用成本均有可替代铬酸阳极氧化的优势。
- Abstract:
- ： Aluminum alloys are widely used in the aviation manufacturing industry due to their low weight ， good strength ， stiffness ， and plasticity. Before use ， an aluminum alloy substrate is designed with a complex combination protection scheme to improve corrosion resistance. The commonly used scheme is anodizing with a paint layer for protection. With the development of high-end and green aviation manufacturing industry ， the voice of commonly used chromic acid anodizing being replaced due to the toxicity of hexavalent Cr has become increasingly strong. This article comprehensively compares the processes of chromic acid ， boric acid sulfuric acid ， sulfuric acid ， and tartaric acid sulfuric acid anodizing from the dimensions of invention history ， performance ， environmental impact ， and usage cost. The research shows that boric acid sulfuric acid anodizing has advantages in corrosion resistance ， fatigue limit ， green environmental protection ， and cost of use ， which can replace chromic acid anodizing.
参考文献/References:
[1] Lee W, Park S J. Porous anodic aluminum oxide: Anodization and templated synthesis of functional nanostructures[J]. Chemical Reviews, 2014, 114(15): 7487-556.
[2] 陈晶 , 成阳 , 陈东琛 , 等 . 铝及铝合金阳极氧化的发展现状 [J]. 江西化工 , 2019, 4: 44-46.
[3] Becker M. Chromate-free chemical conversion coatings for aluminum alloys [J]. Corrosion Reviews, 2019, 37(4): 321-342.
[4] Matykina E, Arrabal R, Mohedano M, et al. Recent advances in energy efficient PEO processing of aluminium alloys [J]. Transactions of Nonferrous Metals Society of China, 2017, 27(7): 1439-1454.
[5] 郭鹤桐 , 王为 . 铝阳极氧化的回顾与展望 [J]. 材料保护 , 2000, 33(1): 43-45.
[6] 刘兵 , 彭超群 , 王日初 , 等 . 大飞机用铝合金的研究现状及展望 [J]. 中国有色金属学报 , 2010, 20(9): 1705-1715.
[7] Martínez-Viademonte M P, Abrahami S T, Hack T, et al. A review on anodizing of aerospace aluminum alloys for corrosion protection [J]. Coatings, 2020, 10(11): 1106.
[8] 陈小丽 , 麻彦龙 , 黄伟九 , 等 . 环保型铝合金阳极氧化表面处理研究进展 [J]. 材料导报 , 2015, 29(7): 107-112.
[9] 黄小文 , 王梅丰 , 李祥 , 等 . 环保型铝合金化学氧化工艺的研究进展 [J]. 腐蚀与防护 , 2022, 43(8): 75-79.
[10] 郑瑞庭 . 铝及其合金铬酸阳极氧化 [J]. 电镀与精饰 , 2003, 25(1): 13-15.
[11] 张金生 . 铝合金阳极氧化膜表面状态与粘接性能研究 [D]. 北京 : 北京化工大学 , 2007.
[12] 周赟 . 铝合金阳极氧化膜封闭工艺及膜性能的研究 [D]. 合肥 ; 合肥工业大学 , 2012.
[13] Dattilo A, Tamiro S, Romano C. Anodizing process, with low environmental impact, for a wood piece of aluminum or aluminum alloys: US, 20020078693 [P]. 2002.
[14] Ukaji Y, Soeta T. Acetogenin (polypriopionate) derived auxiliaries: Tartaric acid [J]. Comprehensive Chirality, 2012, 3: 176-201.
[15] Boldsaikhan E, Fukada S, Fujimoto M, et al. Refill friction stir spot welding of surface-treated aerospace aluminum alloys with faying-surface sealant [J]. Journal of Manufacturing Processes, 2019, 42:113-120.
[16] 张肖 , 葛文凯 . 铝板表面阳极化膜层裂纹研究 [J]. 化学与粘合 , 2024, 46(1): 30-34.
[17] Cirik E, Genel K. Effect of anodic oxidation on fatigue performance of 7075-T6 alloy [J]. Surface and Coatings Technology, 2008, 202(21): 5190-5201.
[18] Lee E, Jeong Y, Kim S. S N. Fatigue behavior of anodized 7050-T7451 produced in different electrolytes [J]. Metallurgical and Materials Transactions A, 2012, 43(6): 2002-2011.
[19] 蔡健平 , 李斌 , 刘明辉 , 等 . 阳极化对航空铝合金疲劳性能的影响 [J]. 航空材料学报 , 2007, 2: 25-28.
[20] 潘君拯 . 铝的阳极氧化处理 [M]. 上海 : 上海科学技术出版社 , 1956.
[21] 范丽娜 , 张晓林 , 陈锋 , 等 . 铝合金铬酸阳极化在航空领域的环保替代工艺分析 [J]. 电镀与精饰 , 2023, 45(8): 81-86.
相似文献/References:
[1]王艳伟.填充工序对铝合金壳体零件铬酸阳极化色差的影响[J].电镀与精饰,2019,(7):40.[doi:10.3969/j.issn.1001-3849.2019.07.009]
WANG Yanwei.Influence of Filling Process on Color Difference of Aluminum Alloy Shell after Chromic Acid Anodization[J].Plating & Finishing,2019,(11):40.[doi:10.3969/j.issn.1001-3849.2019.07.009]
[2]黄碧芳*,李远会,王 丽,等.铝合金磷钼酸亚铁转化体系工艺研究[J].电镀与精饰,2019,(9):29.[doi:10.3969/j.issn.1001-3849.2019.09.006]
HUANG Bifang*,LI Yuanhui,WANG Li,et al.Study on the Conversion Process of Ferrous Phosphomolybdate on Aluminum Alloy[J].Plating & Finishing,2019,(11):29.[doi:10.3969/j.issn.1001-3849.2019.09.006]
[3]元 泉,邱 媛*,刘 洋,等.铝合金漆层与氧化层激光清洗应用研究[J].电镀与精饰,2019,(12):25.[doi:10.3969/j.issn.1001-3849.2019.12.006]
YUAN Quan,QIU Yuan#,LIU Yang,et al.Research on Laser Cleaning Application for Coating and Oxide Layer of Aluminum Alloy[J].Plating & Finishing,2019,(11):25.[doi:10.3969/j.issn.1001-3849.2019.12.006]
[4]季 伟,孟繁东,潘科宇,等.铝合金表面油污清洗剂的制备及其腐蚀性研究[J].电镀与精饰,2021,(2):38.[doi:10.3969/j.issn.1001-3849.2021.02.0080]
JI Wei,MENG Fandong,PAN Keyu,et al.季 伟1，孟繁东1，潘科宇1，王文军1，潘明华1，韩怡秋2，邵明亮2，刘 东3，周 勇3*[J].Plating & Finishing,2021,(11):38.[doi:10.3969/j.issn.1001-3849.2021.02.0080]
[5]张子聪,郝建军*,赵荣兴.铝合金复合石墨烯薄膜的制备及腐蚀性能研究[J].电镀与精饰,2021,(7):15.[doi:10.3969/j.issn.1001-3849.2021.07.003]
ZHANG Zicong,HAO Jianjun*,ZHAO Rongxing.Study on Preparation and Corrosion Performance of Aluminum Alloy Composite Graphene Film[J].Plating & Finishing,2021,(11):15.[doi:10.3969/j.issn.1001-3849.2021.07.003]
[6]刘奋照*.几种铝合金材料在汽车防冻液中的腐蚀行为[J].电镀与精饰,2021,(9):59.[doi:10.3969/j.issn.1001-3849.2021.09.010]
LIU Fenzhao*.Corrosion Behavior of Several Aluminum Alloy in Automobile Antifreeze[J].Plating & Finishing,2021,(11):59.[doi:10.3969/j.issn.1001-3849.2021.09.010]
[7]刘 静,马小昭,王帅星.绝缘保护用铬酸阳极氧化工艺研究[J].电镀与精饰,2022,(6):41.[doi:10.3969/j.issn.1001-3849.2022.06.009]
LIU Jing,MA Xiaozhao,WANG Shuaixing.Research on Chromic Acid Anodizing Technique for Insulation Protection[J].Plating & Finishing,2022,(11):41.[doi:10.3969/j.issn.1001-3849.2022.06.009]
[8]李志强,魏红阳,陈东初*,等.电源参数对铝合金表面复合氧化膜的多彩电解着色的影响规律研究[J].电镀与精饰,2022,(6):52.[doi:10.3969/j.issn.1001-3849.2022.06.011]
LI Zhiqiang,WEI Hongyang,CHEN Dongchu*,et al.Effects of Power Parameters on Electrolytic Colouring of Colorful Composite Oxide Film on Aluminum Alloy Surface[J].Plating & Finishing,2022,(11):52.[doi:10.3969/j.issn.1001-3849.2022.06.011]
[9]李廷取 *,刘祥玲,刘文异. 不同占空比对6061铝合金微弧氧化着色及性能的影响研究 [J].电镀与精饰,2022,(9):20.[doi:10.3969/j.issn.1001-3849.2022.09.004]
LI Tingqu *,LIU Xiangling,LIU Wenyi.Study on Microarc Oxidation Coloring and Properties of 6061 Aluminum Alloy with Different Duty Ratios[J].Plating & Finishing,2022,(11):20.[doi:10.3969/j.issn.1001-3849.2022.09.004]
[10]刘巧娣*,邓国军. 硫酸阳极化膜层出现白色粉末问题原因分析 [J].电镀与精饰,2022,(10):88.[doi:10.3969/j.issn.1001-3849.2022.10.015]
LIU Qiaodi*,DENG Guojun.Cause Analysis of White Powder in Sulfuric Acid Anodized Film[J].Plating & Finishing,2022,(11):88.[doi:10.3969/j.issn.1001-3849.2022.10.015]
备注/Memo
收稿日期： 2024-03-25 修回日期： 2024-05-28 作者简介： 丁一（ 1993 —），男，硕士，工程师，主要从事铝合金表面处理， email ： 371797308@qq.com 硼酸 - 硫酸、硫酸、酒石酸 - 硫酸替代铬酸阳极氧化的可行性研究 丁 一 1* ，刘涵予 2 ，张晓林 1 ，冯 晓 1 ，陈 锋 1 ，邓伯孟 1 （ 1. 中航成飞民用飞机有限责任公司， 四川 成都 610000 ； 2. 中国人民解放军 93147 部队，四川 成都 610000 ）