[1]韩冒益,陈子阳,孙天逸,等.doi: 10.3969/j.issn.1001-3849.2025.12.013镁合金表面类水滑石膜的制备及功能化改性研究进展[J].电镀与精饰,2025,(12):97-106.
　Han Maoyi,Chen Ziyang,Sun Tianyi,et al.Research progress on preparation and functional modification of hydrotalcite-like films on magnesium alloy surface[J].Plating & Finishing,2025,(12):97-106.
点击复制

doi: 10.3969/j.issn.1001-3849.2025.12.013镁合金表面类水滑石膜的制备及功能化改性研究进展()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年12
页码:
97-106
栏目:
出版日期:
2025-12-31

文章信息/Info

Title:
Research progress on preparation and functional modification of hydrotalcite-like films on magnesium alloy surface
作者:
韩冒益1; 陈子阳1; 孙天逸1; 汪永民1; 郏永强1;  2*
(1. 南京工程学院 材料科学与工程学院,江苏 南京 211167 ;2. 江苏省先进结构材料与应用技术重点实验室,江苏 南京 211167)
Author(s):
Han Maoyi1;  Chen Ziyang1;  Sun Tianyi1;  Wang Yongmin1;  Jia Yongqiang1;  2*
(1. School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing 211167, China; 2. Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing 211167, China)
关键词:
镁合金; 类水滑石膜; 制备方法; 功能化改性
Keywords:
magnesium alloy;  hydrotalcite-like films;  preparation methods;  functional modification
分类号:
TG174.44；TQ153
文献标志码:
A
摘要:
类水滑石膜(LDH)具有优异的离子交换特性，被广泛用于汽车工业、航空航天、3C、生物医疗器械用镁合金的腐蚀防护。本文总结了近年来镁合金表面类水滑石膜的制备方法，主要包括浸泡法、电沉积法、共沉淀法、尿素法、水热法等。介绍了各种方法制备类水滑石膜的效率、膜层质量、成本等方面的优缺点，并综述了镁合金LDH膜层在服役要求下的功能化改性研究进展，包括自愈合膜层、生物膜层及超疏水膜层，总结了镁合金功能化LDH膜层结构变化、改性机理及研究应用领域，展望了未来镁合金功能性LDH膜层的研究方向。
Abstract:
Hydrotalcite-like layered double hydroxide (LDH) films exhibit outstanding ion exchange properties and are extensively employed for the corrosion protection of magnesium alloys. These alloys are crucial in applications within the automotive industry, aerospace, consumer electronics (3C), and biomedical device sectors. In this paper, the preparation methods of hydrotalcite-like film on magnesium alloy surface in recent years are summarized, including immersion method, electrodeposition method, co-precipitation method, urea method and hydrothermal method. The advantages and disadvantages of each method in preparation efficiency, film quality and cost are introduced. An evaluation of the respective advantages and limitations of these approaches is presented. Additionally, the study examines the progress in functional modifications of magnesium alloy layered double hydroxide (LDH) films to meet the demands of service environments, with a focus on the development of self-healing, bioactive and superhydrophobic films. The structural changes, modification mechanism and research application fields of functional LDH films on magnesium alloys were summarized, and the research direction of functional LDH films on magnesium alloys in the future was prospected

参考文献/References:

[1].Wang X, Jing C, Chen Y X, et al. Active corrosion protec-tion of super-hydrophobic corrosion inhibitor intercalated Mg-Al layered double hydroxide coating on AZ31 magnesium alloy[J]. Journal of Magnesium and Alloys, 2020, 8(1): 291-300.
[2].Zhang J M, Li J C, Hou A R, et al. Investigating the microstructures and properties of Mg‐Al LDH film-coated Mg-Li alloy: Effect of hydrothermal temperature[J]. International Journal of Applied Ceramic Technology, 2022, 19(6): 3062-3071.
[3].Del O R, Mohedano M, Matykina E, et al. Permanganate loaded Ca-Al-LDH coating for active corrosion protection of 2024-T3 alloy[J]. Corrosion Science, 2022, 198: 110144.
[4].Cao Y, Zheng D, Li X, et al. Enhanced corrosion resistance of superhydrophobic layered double hydroxide films with long-term stability on Al substrate[J]. ACS Applied Materials and Interfaces, 2018, 10(17): 15150-15162.
[5].Zhang X C, Yin Z J, Buhe B, et al. Effect of temperature on corrosion resistance of layered double hydroxides conversion coatings on magnesium alloys based on a closed-cycle system[J]. Metals, 2021, 11(10): 1658-1670.
[6].Lin J K, Uan J Y, Wu C P, et al. Direct growth of oriented Mg-Fe layered double hydroxide (LDH) on pure Mg substrates and in vitro corrosion and cell adhesion testing of LDH-coated Mg samples[J]. Journal of Materials Chemistry, 2011, 21(13): 5011-5020.
[7].Li Z Z, Ba Z X, Wang T, et al. Fabrication and characterization of Mg-Mn hydrotalcite films on pure Mg substrates[J]. Materials Research Express, 2019, 6(11): 116440-116448.
[8].Tan J K E, Balan P, Birbilis N, et al. Corrosion-resistant Mg(OH)2/Mg-Fe layered double hydroxide (LDH) composite films on magnesium alloy WE43[J]. Journal of the Taiwan Institute of Chemical Engineers, 2022, 131: 104169.
[9].Ba Z X, Kuang J, Ding Y P, et al. Influence of working current density on formation and corrosion resistance of super-hydrophobic coating on ZK60 magnesium alloy[J]. Rare Metal Materials and Engineering, 2022, 51(6): 1942-1948.
[10].Zhang F, Liu Z G, Zeng R C, et al. Corrosion resistance of Mg-Al-LDH coating on magnesium alloy AZ31[J]. Surface and Coatings Technology, 2014, 258: 1152-1158.
[11].Guo L, Zhang F, Lu J, et al. A comparison of corrosion inhibition of magnesium aluminum and zinc aluminum vanadate intercalated layered double hydroxides on magnesium alloys[J]. Frontiers of Materials Science, 2018, 12(2): 198-206.
[12].Wu H S, Zhang L Y, Zhang Y C, et al. Corrosion behavior of Mg-Al LDH film in-situ assembled with graphene on Mg alloy pre-sprayed Al layer[J]. Journal of Alloys and Compounds, 2020, 834: 155107.
[13].Zeng R, Liu Z, Zhang F, et al. Corrosion resistance of in-situ Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy by one-step formation[J]. Transactions of Nonferrous Metals Society of China, 2015, 25(6): 1917-1925.
[14].Intasa-Ard S G, Ogawa M. Homogeneous precipitation of Mg/Al layered double hydroxide from concentrated metal salt solution under hydrothermal conditions[J]. Journal of Solid State Chemistry, 2023, 317: 123664.
[15].Wu L, Yang D N, Zhang G, et al. Fabrication and characterization of Mg-M layered double hydroxide films on anodized magnesium alloy AZ31[J]. Applied Surface Science, 2018, 431: 177-186.
[16].Zheng B, Ou J, Li H Y, et al. Preparation of phosphate ion-doped Zn-Fe-layered double hydroxide with corrosion resistance and inducing Ca-P deposition on AZ31 Mg alloy[J]. Journal of Materials Research, 2022, 37(3): 763-772.
[17].Chen J, Fang L, Wu F, et al. Comparison of corrosion resistance of MgAl-LDH and ZnAl-LDH films intercalated with organic anions ASP on AZ31 Mg alloys[J]. Transactions of Nonferrous Metals Society of China, 2020, 30(9): 2424-2434.
[18].Yu A D, Song Y L, Wang N, et al. Study on the corrosion and self-healing behavior of different anion-intercalated layered double hydroxides coatings on Mg alloy surfaces[J]. Surfaces and Interfaces, 2024: 105680.
[19].Li J, He N, Li J Y, et al. A silicate-loaded MgAl LDH self-healing coating on biomedical Mg alloys for corrosion retardation and cytocompatibility enhancement[J]. Surface and Coatings Technology, 2022, 439: 128442.
[20].Dai X, Wu L, Ci W, et al. Dual self-healing effects of salicylate intercalated MgAlY-LDHs film in-situ grown on the micro-arc oxidation coating on AZ31 alloys[J]. Corrosion Science, 2023, 220: 111285.
[21].Jiao Z J, Zhou Y, Dai X W, et al. A bimodified MgAlCe-LDHs@GO self-healing anti-corrosion coating based on the micro arc oxidation coating of AZ31 magnesium alloy[J]. Corrosion Science, 2025, 248: 112805.
[22].Wu J H, Wu L, Wu M Y, et al. Corrosion inhibitors for corrosion resistance and self-healing of PEO/MgAlLa layered double hydroxides coating on Mg-Gd-Y-Zn alloy[J]. Surface and Coatings Technology, 2024, 496: 131524.
[23].Wu J H, Wu L, Yao W H, et al. Self-healing PEO/MgAlLa LDHs-MXene composite coating loaded with 4-aminophenol for corrosion protection of Mg-Gd-Y-Zn LPSO Mg alloy[J]. Electrochimica Acta, 2024, 491: 144358.
[24].Gnedenkov A S, Sinebryukhov S L, Nomerovskii A D, et al. Design of self-healing PEO-based protective layers containing in-situ grown LDH loaded with inhibitor on the MA8 magnesium alloy[J]. Journal of Magnesium and Alloys, 2023, 11(10): 3688-3709.
[25].Tang Y, Wu F, Fang L, et al. Effect of deposition sequence of MgAl-LDH and SiO2@PDMS layers on the corrosion resistance of robustsuperhydrophobic/self-healing multi-functional coatings on magnesium alloy[J]. Progress in Organic Coatings, 2023, 174: 107299.
[26].Song J F, She J, Chen D L, et al. Latest research advances on magnesium and magnesium alloys worldwide[J]. Journal of Magnesium and Alloys, 2020, 8(1): 1-41.
[27].刘奇峰, 蓝丽招. 铝、镁合金压铸件在汽车工业中的应用及发展[J]. 汽车文摘, 2024(2): 50-55.
[28].腐蚀与防护之友. 镁合金的发展及应用[EB/OL]. https://corrdata.org.cn/dhTJDAOHANG /xinxiziyuan/ kepuqikan/ 2019-09-19/3548.html, 2019-09-19.
[29].Peng F, Wang D H, Tian Y X, et al. Sealing the pores of PEO coating with Mg-Al layered double hydroxide: Enhanced corrosion resistance, cytocompatibility and drug delivery ability[J]. Scientific Reports, 2017, 7(1): 1-12.
[30].Peng F, Wang D H, Zhang D D, et al. PEO/Mg-Zn-Al LDH composite coating on Mg alloy as a Zn/Mg Ion-release platform with multifunctions: Enhanced corrosion resistance, osteogenic, and antibacterial activities[J]. ACS Biomaterials Science and Engineering, 2018, 4(12): 4112-4121.
[31].Xue K, Zhang D D, Du H H, et al. Electrostatically assembled Zn2+-GO-LDH hybrid coating on Mg alloy with excellent anticorrosion and antibacterial properties[J]. Materials Letters, 2024, 371: 136941.
[32].Zhang D, Cheng S, Tan J, et al. Black Mn-containing layered double hydroxide coated magnesium alloy for osteosarcoma therapy, bacteria killing, and bone regenera-tion[J]. Bioactive Materials, 2022, 17: 394-405.
[33].Zhang D D, Zhou J L, Peng F, et al. Mg-Fe LDH sealed PEO coating on magnesium for biodegradation control, antibacteria and osteogenesis[J]. Journal of Materials Science and Technology, 2022, 105: 57-67.
[34].Wang Q G, Liao C T, Liu B, et al. Enhanced corrosion resistance, antibacterial properties and osteogenesis by Cu ion optimized MgAl-layered double hydroxide on Mg alloy[J]. Journal of Magnesium and Alloys, 2024, 12(10): 4174-4190.
[35].Ostrowski N J, Lee B, Roy A, et al. Biodegradable poly(lactide-co-glycolide) coatings on magnesium alloys for orthopedic applications[J]. Journal of Materials Science: Materials in Medicine, 2013, 24(1): 85-96.
[36].Shukor F, Hassan A, Islam M S, et al. Effect of ammonium polyphosphate on flame retardancy, thermal stability and mechanical properties of alkali treated kenaf fiber filled PLA biocomposites[J]. Materials & Design, 2014, 54: 425-429.
[37].Zeng R C, Li X, Liu Z, et al. Corrosion resistance of Zn-Al layered double hydroxide/ poly(lactic acid) composite coating on magnesium alloy AZ31[J]. Frontiers of Materials Science, 2015, 9(4): 355-365.
[38].He N, Li J, Li W J, et al. Poly(lactic acid) coating with a silane transition layer on MgAl LDH-coated biomedical Mg alloys for enhanced corrosion and cytocompatibility[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 661: 130947.
[39].Wu W, Sun X, Zhu C, et al. Biocorrosion resistance and biocompatibility of Mg-Al layered double hydroxide/poly-L-glutamic acid hybrid coating on magnesium alloy AZ31[J]. Progress in Organic Coatings, 2020, 147: 105746-105758.
[40].Peng F, Li H, Wang D H, et al. Enhanced corrosion resistance and biocompatibility of magnesium alloy by Mg-Al layered double hydroxide[J]. ACS Applied Materials and Interfaces, 2016, 8(51): 35033-35044.
[41].Zhang H F, Yin L, Liu X W, et al. Wetting behavior and drag reduction of superhydrophobic layered double hydroxides films on aluminum[J]. Applied Surface Science, 2016, 380: 178-184.
[42].Zhang G, Tang A T, Wu L, et al. In-situ grown super-or hydrophobic Mg-Al layered double hydroxides films on the anodized magnesium alloy to improve corrosion properties[J]. Surface and Coatings Technology, 2019, 366: 238-247.
[43].刘敬春, 赵子晔, 赵建国, 等. AZ31B镁合金表面电化学沉积LDH涂层及其耐腐蚀性能研究[J]. 电镀与精饰, 2024, 46(7): 22-31.
[44].Kuang J, Ba Z X, Li Z Z, et al. Fabrication of a superhydrophobic Mg-Mn layered double hydroxides coating on pure magnesium and its corrosion resistance[J]. Surface and Coatings Technology, 2019, 361: 75-82.
[45].Kuang J, Ba Z X, Li Z Z, et al. The study on corrosion resistance of superhydrophobic coatings on magnesium[J]. Applied surface science, 2020, 501: 144137.
[46].Huang M Y, Lu G M, Pu J B, et al. Superhydrophobic and smart MgAl-LDH anti-corrosion coating on AZ31 Mg surface[J]. Journal of Industrial and Engineering Chemistry, 2021, 103: 154-164.
[47].张兆裕, 黄予, 王燕, 等.电场辅助镁锰超疏水类水滑石膜的制备及耐蚀性研究[J]. 铸造技术, 2023, 44(5): 449-455.
[48].谷立东, 李子昕, 尚晓晴, 等. 镁合金半固态注射成型技术的发展现状与应用前景[J/OL]. 汽车工艺与材料, 2025-03-18, 10.19710/J.cnki.1003-8817.20240381.

相似文献/References:

[1]徐美玲,亢淑梅,陈婷婷,等.添加氯化铈对镁合金Ni?P化学镀镀层性能影响[J].电镀与精饰,2019,(1):37.[doi:10.3969/j.issn.1001-3849.2019.01.008]
　XU Meiling,KANG Shumei,CHEN Tingting,et al.Properties of Electroless Plating Ni?P on Magnesium AlloySubstrate by Adding CeCl3[J].Plating & Finishing,2019,(12):37.[doi:10.3969/j.issn.1001-3849.2019.01.008]
[2]牟世辉,尹鸿鹍,代肇一.镀铜优化对AZ91D镁合金疏水膜性能的影响[J].电镀与精饰,2019,(6):29.[doi:10.3969/j.issn.1001-3849.2019.06.006]
　MU Shihui,YIN Hongkun,DAI Zhaoyi.Effect of Copper Plating Optimization on the Performance of AZ91D Magnesium Alloy Hydrophobic Membrane[J].Plating & Finishing,2019,(12):29.[doi:10.3969/j.issn.1001-3849.2019.06.006]
[3]刘 玮,安成强*,郝建军,等.钼酸钠对AZ91D镁合金钒/锆复合转化膜性能的影响[J].电镀与精饰,2019,(8):10.[doi:10.3969/j.issn.1001-3849.2019.08.003]
　LIU Wei,AN Chengqiang*,HAO Jianjun,et al.Effect of Na2MoO4 on Properties of Vanadium/Zirconate Conversion Coating on AZ91D Magnesium Alloy[J].Plating & Finishing,2019,(12):10.[doi:10.3969/j.issn.1001-3849.2019.08.003]
[4]李佳霖,郝建军,牟世辉.Fe2+对镁合金电化学磷化改性研究[J].电镀与精饰,2019,(10):1.[doi:10.3969/j.issn.1001-3849.2019.10.001]
　LI Jialin,HAO Jianjun,MOU Shihui.Study on Electrochemical Phosphating Modification of Magnesium Alloy by Fe2+[J].Plating & Finishing,2019,(12):1.[doi:10.3969/j.issn.1001-3849.2019.10.001]
[5]贾启华,许晓娟*.沉积时间对镁合金化学镀镍的影响[J].电镀与精饰,2019,(12):1.[doi:10.3969/j.issn.1001-3849.2019.12.001]
　JIA Qihua,XU Xiaojuan*.Effect of Deposition Time on Direct Electroless Plating of Magnesium Alloys[J].Plating & Finishing,2019,(12):1.[doi:10.3969/j.issn.1001-3849.2019.12.001]
[6]王 丽,顾 威,郭 荣,等.环保型无机缓蚀剂对AZ91D镁合金的缓蚀效果[J].电镀与精饰,2020,(4):18.[doi:10.3969/j.issn.1001-3849.2020.04.0040]
　WANG Li,GU Wei,GUO Rong,et al.Inhibition Effect of Environmental Protection Inorganic Corrosion Inhibitor on AZ91D Magnesium Alloy[J].Plating & Finishing,2020,(12):18.[doi:10.3969/j.issn.1001-3849.2020.04.0040]
[7]党在清*.镁合金复合镀层的制备及其结构与性能表征[J].电镀与精饰,2020,(11):16.[doi:10.3969/j.issn.1001-3849.2020.11.0040]
　DANG Zaiqing*.Study on the Structure and Properties of Composite Coating on Magnesium Alloy[J].Plating & Finishing,2020,(12):16.[doi:10.3969/j.issn.1001-3849.2020.11.0040]
[8]王晓奇*,曹 慧,雷 彪.镁合金表面电弧离子镀TiAlN薄膜的结构与性能研究[J].电镀与精饰,2021,(6):25.[doi:10.3969/j.issn.1001-3849.2021.06.006]
　WANG Xiaoqi*,CAO Hui,LEI Biao.Structure and Properties of TiAlN Films by Arc Ion Plating on Mg Alloys[J].Plating & Finishing,2021,(12):25.[doi:10.3969/j.issn.1001-3849.2021.06.006]
[9]牟世辉*,李鑫宇.恒电流作用下AZ91D镁合金磷化膜生长研究[J].电镀与精饰,2021,(9):1.[doi:10.3969/j.issn.1001-3849.2021.09.001]
　MU Shihui*,LI Xinyu.Growth of Phosphating Film on AZ91D Magnesium Alloy Under Constant Current[J].Plating & Finishing,2021,(12):1.[doi:10.3969/j.issn.1001-3849.2021.09.001]
[10]宋政伟*,丁莉峰,王沛霖,等.镁合金表面Ni-P/Cu-Zn超疏水复合涂层制备及耐蚀性研究[J].电镀与精饰,2021,(7):10.[doi:10.3969/j.issn.1001-3849.2021.07.002]
　SONG Zhengwei*,DING Lifeng,WANG Peilin,et al.Preparation and Corrosion Resistance of Ni-P/Cu-Zn Super-Hydrophobic Composite Coating on the Surface of Mg Alloy[J].Plating & Finishing,2021,(12):10.[doi:10.3969/j.issn.1001-3849.2021.07.002]

备注/Memo

备注/Memo:
关键词：镁合金；类水滑石膜；制备方法；功能化改性
更新日期/Last Update: 2025-12-18