[1]郑晓漫,朱业权,明 铄,等.doi: 10.3969/j.issn.1001-3849.2026.05.002低电流密度分级多孔NiFe/Ni@NM构筑及高效析氧[J].电镀与精饰,2026,(05):13-19.
　ZHENG Xiaoman,ZHU Yequa,MING Shuo,et al.Construction of hierarchical porous NiFe/Ni@NM at low current density for efficient oxygen evolution[J].Plating & Finishing,2026,(05):13-19.
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doi: 10.3969/j.issn.1001-3849.2026.05.002低电流密度分级多孔NiFe/Ni@NM构筑及高效析氧()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2026年05
页码:
13-19
栏目:
出版日期:
2026-05-31

文章信息/Info

Title:
Construction of hierarchical porous NiFe/Ni@NM at low current density for efficient oxygen evolution
作者:
郑晓漫; 朱业权; 明 铄; 李淮孜; 汪 玉; 王振卫
(上海应用技术大学 化工与能源技术学部,上海 201418)
Author(s):
ZHENG Xiaoman;  ZHU Yequa;  MING Shuo;  LI Huaizi;  WANG Yu;  WANG Zhenwei
(School of Chemical Engineering and Energy Technology, Shanghai Institute of Technology, Shanghai 201418, China)
关键词:
电沉积; 氢气泡模板; 多孔结构; 析氧反应
Keywords:
electrodeposition;  hydrogen bubble template;  porous structure;  oxygen evolution reaction
分类号:
TQ153 TG156.1
文献标志码:
A
摘要:
针对NiFe基粉体催化剂在高电流密度下易剥落且传质效率低的瓶颈问题，提出了一种低电流密度动态氢气泡模板电沉积与选择性刻蚀技术相结合的方法，构筑了分级多孔Ni基集流体(Ni@NM)作为自支撑基底，并在其表面电沉积了NiFe氢氧化物(NiFe/Ni@NM)。系统研究了NiFe膜层的电沉积电流密度对阳极析氧反应(OER)性能的影响。结果表明：在5 A?dm?2沉积电流密度下制备的、蜂窝状分级多孔纳米片阵列电极(NiFe/Ni@NM-5)表现出卓越的电催化性能，在100 mA?cm?2高电流密度下，可稳定运行100 h，性能无明显衰减。本研究揭示了NiFe/Ni@NM自支撑多孔电极在高效性、稳定性及经济可扩展性方面的显著优势，为低成本NiFe基OER催化剂的规模化应用提供了全新的材料设计理念和制备策略。
Abstract:
To solve the tendency to peel off and low mass transfer efficiency of NiFe-based powder catalysts at high current densities, a new method combining low-current-density dynamic hydrogen bubble template (DHBT) electrodeposition with selective etching was proposed. A hierarchical porous Ni-based Ni@NM current collector was fabricated as a self-supporting substrate, onto which NiFe hydroxide ( NiFe/Ni@NM) was deposited. The influence of NiFe deposition current density on oxygen evolution reaction (OER) performance was systematically investigated. Results show that the honeycomb-structured hierarchical porous nanosheet array electrode ( NiFe/Ni@NM-5) prepared at 5A?dm-2, which shows excellent stability for 100 h at 100 mA ?cm?2 without decay. It demonstrates that the NiFe/Ni@NM electrode has great advantages in higher efficiency, stronger stability and better scalability. It provides new design concepts and fabrication strategies for industrial-scale application of low-cost NiFe-based OER catalysts

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更新日期/Last Update: 2026-05-12