XU Chao,WANG Miaoyu,ZHOU Jianbo,et al.Study on Electrodeposition Process of Ni-Mo-Fe-La Alloy Hydrogen Evolution Electrode[J].Plating & Finishing,2020,(8):7-12.[doi:10.3969/j.issn.1001-3849.2020.08.0020]
电沉积Ni-Mo-Fe-La合金析氢电极的工艺研究
- Title:
- Study on Electrodeposition Process of Ni-Mo-Fe-La Alloy Hydrogen Evolution Electrode
- 关键词:
- Ni-Mo-Fe-La合金; 电沉积; 析氢过电位; 电催化活性
- Keywords:
- Ni-Mo-Fe-La alloy electrodeposition hydrogen evolution overpotential electrocatalytic activity
- 文献标志码:
- A
- 摘要:
- 采用电沉积法制备了La掺杂的Ni-Mo-Fe-La合金，并探究了氯化镧浓度、钼酸钠浓度、电流密度、沉积时间等工艺参数对Ni-Mo-Fe-La合金析氢性能的影响，并与Ni-Mo-Fe合金的析氢性能进行了对比。结果表明，在最佳工艺条件下，电沉积法制备的Ni-Mo-Fe-La合金具有优于Ni-Mo-Fe合金的催化析氢活性。Ni-Mo-Fe-La合金具有较大的比表面积与交换电流密度、较小的表观活化能与析氢反应电化学阻抗，且耐腐蚀性能较强。扫描电镜结果显示Ni-Mo-Fe-La电极表面由许多细小颗粒组成，电极表面致密且粗糙。
- Abstract:
- The Ni-Mo-Fe-La alloy was prepared by electrodeposition method, the effects of electrodeposition process parameters, such as the concentration of lanthanum chloride and sodium molybdate, current density and electrodeposition time on the hydrogen evolution performance of the Ni-Mo-Fe-La alloy were investigated, and compared with the hydrogen evolution performance of Ni-Mo-Fe alloy. The results showed that the Ni-Mo-Fe-La alloy prepared under the optimum conditions had better hydrogen evolution catalytic activity than Ni-Mo-Fe alloy. The Ni-Mo-Fe-La alloy electrode had higher specific surface area and exchange current density, lower apparent activation energy and electrochemical impedance of hydrogen evolution reaction, and higher corrosion resistance. The SEM results indicated that the Ni-Mo-Fe-La alloy was composed of many smaller particles, which had a compact and rough surface.
参考文献/References:
[1] 王星懿, 王玉, 盛敏奇. 钴-钨/多孔铜镀层的电沉积与析氢性能[J]. 电镀与涂饰, 2019, 17: 942-947.
Wang X Y, Wang Y. Sheng M Q. Electrodeposition and hydrogen evolution property of cobalt-tungsten/porous copper coating [J]. Electroplating and Finishing, 2019, 17: 942-947(in Chinese).
[2] 梁馨元, 施筱萱, 赵悦君. 电催化析氢反应及析氢催化剂研究进展[J]. 化工管理, 2019, 7:68-69.
Liang X Y, Shi Y X, Zhao Y J. Development of electrocatalytic hydrogen evolution reaction and catalyst [J]. Chemical Enterprise Management, 2019, 7:68-69(in Chinese).
[3] Sun J S, Wen Z, Han L P, et al. Nonprecious intermetallic Al7Cu4Ni nanocrystals seamlessly integrated in free standing bimodal nanoporous copper for efficient hydrogen evolution catalysis [J]. Advanced Functional Materials, 2018, 14: 1706127-1706133.
[4] 周琦, 冯基伟, 李志洋, 等. 纳米多孔 Ni-Co 电极的制备及其电催化析氢性能[J]. 兰州理工大学学报, 2018, 44 (6): 1-5.
Zhou Q, Feng J W, Li Z Y, et al. Preparation of nan-oporous Ni-Co electrode and its performance of electrocatalytic hydrogen evolution [J]. Journal of Lanzhou University of Technology, 2018, 44 (6): 1-5(in Chinese).
[5] Arul R, Vasu K I. Transition metal-based cathodes for hydrogen evolution in alkaline solution:electrocatalysis on nickel-based ternary electrolytic codeposits [J]. Applied Electrochemistry, 1992, 22:471-477.
[6] Sanches L S, Domingues S H, Marino C E B, et al. Characterisation of electrochemically deposited Ni-Mo alloy coatings [J]. Electrochemistry Communications, 2004, 6(6):543-548.
[7] 刘淑兰, 覃奇贤. 电沉积Li-La合金上的阴极析氢行为[J]. 应用化学, 1995, 12（5）:115-116.
Liu S L, Qin Q X, Cheng D H, et al. Study on cathode hydrogen evolution behavior of electrode posited rare earth alloy Ni-La [J]. Chinese Journal of Applied Chemistry, 1995, 12(5):115-116(in Chinese).
[8] 高诚辉, 李凝. 电沉积非晶/纳米晶Ni-Mo-La合金电极的析氢性能[J]. 中国有色金属学报, 2011, 1(21):2820-2824.
Gao C H, Li N. Hydrogen evolution reaction activity of electrodeposited amorphous/nanocrystalline Ni-Mo-La alloy electrode [J]. The Chinese Journal of Nonferrous Metals, 2011, 1(21):2820-2824(in Chinese).
[9] 李凝, 高诚辉, 杨素珍. 稀土（La、Ce）铁组基非晶态合金的电化学性能[J]. 材料导报, 2008, 22(3):52-59.
Li N, Gao C H, Yang S Z. Research on electrochemical properties of Re (La, Ce)-M(Fe, Co, Ni) based amorphous alloys[J]. Materials Review, 2008, 22(3):52-59(in Chinese).
[10] 李凝, 高诚辉, 杨素珍. 镧对非晶/纳米晶Ni-Mo合金镀层结构及性能的影响[J]. 中国稀土学报, 2009, 27(2):253-256.
Li N, Gao C H, Yang S Z. Effects of lanthanum on microstructure and properties of amorphous/nanocrystalline Ni-Mo alloy coating[J]. Journal of the Chinese Rare Earth Society, 2009, 27(2):253-256(in Chinese).
[11] 李凝, 高诚辉. 非晶/纳米晶Ni-Mo-Ce合金镀层结构及其析氢催化性能[J]. 中国稀土学报, 2010, 28(4):442-446.
Li N, Gao C H. Microstructure and catalytic properties of amorphous/nanocrystalline Ni-Mo-Ce alloy for HER [J]. Journal of the Chinese Rare Earth Society, 2010, 28(4):442-446(in Chinese).
[12] 章磊, 宜天鹏. 稀土元素对化学镀Co-Ni-B合金电化学特性的影响[J]. 电镀与精饰, 2002, 21(3):21-31.
Zhang L, Yi T P. Effects of rare earth on electrochemical properties of electroless Co-Ni-B alloy coating [J]. Plating and Finishing, 2002, 21(3):21-31(in Chinese).
[13] Komagaka S, Hirota K, Suzuki H. Behavior of adsorbed hydrogen on Ni(III) surface with reemitted slow-position spectros-copy [J]. Applied Surface Science, 2008, 255(1):227-232.
相似文献/References:
[1]张冰怡,张莎莎*,姚正军,等.电沉积Ni-W纳米晶镀层制备与显微硬度研究[J].电镀与精饰,2019,(8):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
ZHANG Bingyi,ZHANG Shasha*,YAO Zhengjun,et al.Preparation and Microhardness of Electrodeposited Ni-W Nanocrystalline Coatings[J].Plating & Finishing,2019,(8):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
[2]雷同鑫,鞠 辉,张长科,等.电镀Ni-W-P合金在钻杆接头上的应用[J].电镀与精饰,2019,(10):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
LEI Tongxin,JU Hui,ZHANG Changke,et al.Application of Ni-W-P Alloy Prepared by Electroplating to Tool Joints[J].Plating & Finishing,2019,(8):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
[3]李晓峰*,孟 芳,董会超,等.电沉积法制备掺铋金属锌及其性能表征[J].电镀与精饰,2020,(1):12.[doi:10.3969/j.issn.1001-3849.2020.01.003]
LI Xiaofeng*,MENG Fang,DONG Huichao,et al.Electrodeposited Preparation of Bi-Doped Metal Zinc and Its Performance Characterization[J].Plating & Finishing,2020,(8):12.[doi:10.3969/j.issn.1001-3849.2020.01.003]
[4]张永霞,王 玫,方 华*,等.Co3O4/碳纳米管复合膜的超级电容器性能[J].电镀与精饰,2020,(2):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
ZHANG Yongxia,WANG Mei,FANG Hua*,et al.Co3O4/Carbon Nanotube Composite Film for Supercapacitor and Its Performances[J].Plating & Finishing,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
[5]侯珂珂,陈新华,张万强,等.电沉积法制备仿生超疏水滤网及其油水分离性能[J].电镀与精饰,2020,(4):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
HOU Keke,CHEN Xinhua,ZHANG Wanqiang,et al.Preparation of Biomimetic Superhydrophobic Filter Screen by Electrodeposition and the Oil-Water Separation Performance[J].Plating & Finishing,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
[6]肖成龙,梁世雍,于兆勤*.可控阵列微柱超疏水表面实验研究[J].电镀与精饰,2020,(7):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
XIAO Chenglong,LIANG Shiyong,YU Zhaoqin*.Experimental Study on Superhydrophobic Surface of Controllable Array Microcolumns[J].Plating & Finishing,2020,(8):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
[7]高 辉,刘伟杰*.2A12铝合金电沉积Ni-Co-MoS2复合镀层的耐磨性能研究[J].电镀与精饰,2020,(10):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
GAO Hui,LIU Weijie*.Research on Wear Resistance of Ni-Co-MoS2 Composite Coating Electrodeposited on 2A12 Aluminium Alloy[J].Plating & Finishing,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
[8]王 羽,刘励昀,杜荣斌*,等.添加剂MPS、DDAC、Cl-对铜箔电沉积的影响[J].电镀与精饰,2021,(5):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
WANG Yu,LIU Liyun,DU Rongbin*,et al.Effects of Additives MPS， DDAC and Cl- on the Copper Foil[J].Plating & Finishing,2021,(8):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
[9]杨惠良*.硫酸盐镀液中紫铜电沉积Ni-Co/WC复合镀层的工艺条件优化[J].电镀与精饰,2021,(6):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]
YANG Huiliang*.Optimization of Process Conditions for Electrodeposition of Ni-Co/WC Composite Coatings on Red Copper from Sulfate Bath[J].Plating & Finishing,2021,(8):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]
[10]孟香茗,宋振兴*,卜路霞,等.电沉积法制备纳米线阵列的研究进展[J].电镀与精饰,2021,(6):35.[doi:10.3969/j.issn.1001-3849.2021.06.008]
MENG Xiangming,SONG Zhenxing*,BU Luxia,et al.Research Progress of Producing Nanowire Arrays by Electrodeposition[J].Plating & Finishing,2021,(8):35.[doi:10.3969/j.issn.1001-3849.2021.06.008]
备注/Memo
收稿日期： 2020-04-13；修回日期： 2020-07-12
作者简介： 徐超（1986— ），女，硕士研究生，讲师，Email：hunanxuchao@163.com
通讯作者： 付薪菱，Email：328645049@163.com
基金项目： 湖南省教育厅科学研究项目（19C0221，18C1185）