ZHU Jinhai*,JIANG Fazheng,WANG Keqi.Effect of Additives on Corrosion Resistance of Conversion Coating on 6063 Aluminum Profiles[J].Plating & Finishing,2022,(10):17-23.[doi:10.3969/j.issn.1001-3849.2022.10.003]
添加剂对建筑6063铝型材表面转化膜耐蚀性能的影响
- Title:
- Effect of Additives on Corrosion Resistance of Conversion Coating on 6063 Aluminum Profiles
- Keywords:
- additives ; 6063 aluminum alloy ; conversion film ; film thickness ; corrosion resistance
- 分类号:
- U463.343
- 文献标志码:
- A
- 摘要:
- 为了提升建筑铝型材的耐蚀性能，采用转化膜处理法在 6063 铝型材表面制备了 Ce-Mn 转化膜，对比分析了无添加剂和加入硼酸、硫酸锆、氟化钠、氟化氢、氟硼酸钠和氟锆酸钠作为添加剂时转化膜的成膜速度和耐蚀性能，并探讨了添加剂的作用机理。结果表明：当添加剂为氟化钠和氟硼酸钠时，形成黄色转化膜的时间为 8 min ，优于无添加剂时黄色转化膜形成时间（ 16 min ）。 Ce-Mn 转化液中加入添加剂后得到的转化膜对耐点滴时间和耐浸泡时间的影响趋势相同，即氟化钠、氟化氢和氟硼酸钠的添加可以起到减缓剂的作用。点滴试验、浸泡试验、极化曲线和电化学阻抗谱测试结果相吻合，即添加剂为氟化钠、氟硼酸钠和氟化氢时可以提升转化膜的耐腐蚀性，这主要与 6063 铝合金表面形成了 Mn 和 Ce 的氧化物和氢氧化物，阻碍了腐蚀介质与铝合金基体发生反应有关。 6063 铝合金 Ce-Mn 转化液中适宜的添加剂为氟化钠。
- Abstract:
- ： In order to improve the corrosion resistance of architectural aluminum profiles ， Ce-Mn conversion film was prepared on 6063 aluminum profile by conversion coating method. The film forming speed and corrosion resistance of the conversion films without additives and with boric acid ， zirconium sulfate ， sodium fluoride ， hydrogen fluoride ， sodium fluoborate and sodium fluozirconate as additives were compared and analyzed ， and the action mechanism of additives was also discussed. The results showed that when the additives were sodium fluoride and sodium fluoborate ， the formation time of yellow conversion film was 8 min ， which was better than that of the yellow conversion film without additives （ 16 min ） . The effect of additives on the drip resistance time and soaking resistance time was same ， and the addition of sodium fluoride ， hydrogen fluoride and sodium fluoborate can act as a mitigating agent. The results of drip test ， immersion test ， polarization curve and electrochemical i mpedance spectroscopy were consistent ， and the corrosion resistance of the conversion film can be improved when the additives were sodium fluoride ， sodium fluoborate and hydrogen fluoride. This was mainly related to the formation of Mn and Ce oxides and hydroxides on the surface of 6063 aluminum alloy ， which hindered the reaction between the corrosion medium and the aluminum alloy matrix. The results showed that the suitable additive for Ce-Mn conversion solution on 6063 aluminum alloy was sodium fluoride.
参考文献/References:
[1] 梁广 , 朱胜 , 王文宇 , 等 . 铝合金腐蚀防护技术研究现状及发展趋势 [J]. 材料导报 , 2020, 34(S2): 1429-1436.
[2] 潘杰 , 李焰 . 变形铝合金表面锆基化学转化膜的研究现状 [J]. 化工进展 , 2020, 39(11): 4503-4515.
[3] 徐松 , 刘会彬 , 尚洪帅 . 稀土 Ce 盐在铝合金表面成膜工艺中的研究进展 [J]. 天津化工 , 2021, 35(2): 1-3.
[4] 沈杰 , 唐强 , 李萌 , 等 . 建筑铝型材的表面电镀与性能研究 [J]. 真空科学与技术学报 , 2021, 41(1): 100-106.
[5] 陆岑 , 张凯 , 穆松林 , 等 . 6063 铝合金碱性铈 - 钼化学转化工艺及膜层组织结构 [J]. 电镀与涂饰 , 2020, 39(23): 1638-1642.
[6] 刘海山 , 姚兴芳 , 廖建 . 建筑用 6061 铝型材的表面改性与性能研究 [J]. 铸造技术 , 2016, 37(5): 929-932.
[7] Yi A, Li W F, Du J, et al. Effects of Mn 2+ on the chrome‐free colored Ti/Zr‐based conversion coating on 6063 aluminum alloy[J]. Surface & Interface Analysis, 2015, 47(9): 863-870.
[8] 于宏飞 , 邵博 , 张悦 , 等 . 2A12 铝合金锆基转化膜的制备及性能研究 [J]. 中国腐蚀与防护学报 , 2021, 41(1): 101-109.
[9] 廖忠淼 , 陈龙 , 祝闻 , 等 . 铝合金上低温钛锆转化膜快速成膜工艺 [J]. 电镀与涂饰 , 2020, 39(13): 855-861.
[10] 穆松林 , 张明康 , 李文芳 , 等 . 6063 铝合金碱性钼酸盐化学转化工艺及膜层性能 [J]. 电镀与涂饰 , 2016, 35(24): 1301-1306.
[11] 李海丰 , 张文泉 . 铸铝件表面几种环保转化膜的耐蚀性 [J]. 电镀与涂饰 , 2019, 38(21): 1182-1185.
[12] 赵林 , 于强 , 杜文朝 , 等 . 铝合金表面锆盐转化膜的成分与电化学性能研究 [J]. 热加工工艺 , 2017, 46(16): 133-135.
[13] 张书弟 , 杜鹏飞 , 李礼 , 等 . 铝合金 Ce-Mn 转化膜的制备工艺研究 [J]. 电镀与环保 , 2017, 37(2): 32-35.
[14] 宋富强 , 杨玉萍 , 王芳 , 等 . 6061 铝合金表面硅烷 - 镧盐杂化膜制备工艺参数的正交优化 [J]. 材料保护 , 2017, 50(5): 59-63.
[15] Zhang J J, Dong H, Wen FL, et al. Study of the Ce-Mn conversion coating on 6061 aluminium alloy[J]. Advanced Materials Research, 2011, 189-193: 838-841.
[16] 唐俊 , 杨天恩 , 熊计 , 等 . Mn 2+ 浓度对 6063 铝合金表面锆基转化膜组织和耐蚀性的影响 [J]. 轻合金加工技术 , 2016, 44(4): 39-44.
[17] 郭莉梅 . 表面改性对建筑装饰用 6063 合金组织与性能的影响 [J]. 铸造技术 , 2018, 39(3): 704-706.
[18] Zhang J J, Li W F, Du J, et al. Investigation of the Ce-Mn conversion coating on 6063 aluminium alloy[J]. Chinese Science Bulletin, 2010, 55(29): 3345-3349.
[19] Zhan W, Qian X, Gui B, et al. Preparation and corrosion resistance of titanium-zirconium-cerium based conversion coating on 6061 aluminum alloy[J]. Materials and Corrosion, 2019, 71(3): 172-178.
[20] Milos?ev I, Frankel G S. Review-conversion coatings based on zirconium and/or titanium[J]. Journal of the Electrochemical Society, 2018, 165(3): 127-144.
相似文献/References:
[1]刘 玮,安成强*,郝建军,等.钼酸钠对AZ91D镁合金钒/锆复合转化膜性能的影响[J].电镀与精饰,2019,(8):10.[doi:10.3969/j.issn.1001-3849.2019.08.003]
LIU Wei,AN Chengqiang*,HAO Jianjun,et al.Effect of Na2MoO4 on Properties of Vanadium/Zirconate Conversion Coating on AZ91D Magnesium Alloy[J].Plating & Finishing,2019,(10):10.[doi:10.3969/j.issn.1001-3849.2019.08.003]
[2]徐振邦,陆振涛,柯喜敏,等.铝合金电子元器件的表面涂层与耐蚀性能研究[J].电镀与精饰,2019,(10):9.[doi:10.3969/j.issn.1001-3849.2019.10.003]
XU Zhenbang,LU Zhentao,KE Ximin,et al.Study on Surface Coating and Corrosion Resistance of Aluminum Alloy Electronic Components[J].Plating & Finishing,2019,(10):9.[doi:10.3969/j.issn.1001-3849.2019.10.003]
[3]张玉清,陈同彩?,王春霞,等.添加剂对无氰镀镉工艺性能的影响[J].电镀与精饰,2021,(8):16.[doi:10.3969/j.issn.1001-3849.2021.08.004]
ZHANG Yuqing,CHEN Tongcai,WANG Chunxia,et al.Effect of Additives on the Performance of Cyanide-Free Cadmium Plating[J].Plating & Finishing,2021,(10):16.[doi:10.3969/j.issn.1001-3849.2021.08.004]
[4]周苗淼,张 雨,沈喜训,等.芯片电镀铜添加剂的研究进展[J].电镀与精饰,2022,(2):60.[doi:10.3969/j.issn.1001-3849.2022.02.013]
ZHOU Miaomiao,ZHANG Yu,SHEN Xixun,et al.Research Progress of the Copper Electroplating Additives in Chip Manufacturing[J].Plating & Finishing,2022,(10):60.[doi:10.3969/j.issn.1001-3849.2022.02.013]
[5]邱 媛*,元 泉,杨志业,等.添加剂对HEDP镀铜溶液性能的影响[J].电镀与精饰,2022,(5):33.[doi:10.3969/j.issn.1001-3849.2022.05.006]
QIU Yuan*,YUAN Quan,YANG Zhiye,et al.Effects of Additive on the Properties of HEDP Copper Plating Solution[J].Plating & Finishing,2022,(10):33.[doi:10.3969/j.issn.1001-3849.2022.05.006]
[6]向 静,阮海波*,王 翀,等.添加剂竞争吸附机理研究及通孔电镀应用[J].电镀与精饰,2022,(11):85.[doi:10.3969/j.issn.1001-3849.2022.11.015]
XIANG Jing,RUAN Haibo*,WANG Chong,et al.Study on Competitive Adsorption Mechanism of Additives and Its Application of Though Holes Plating[J].Plating & Finishing,2022,(10):85.[doi:10.3969/j.issn.1001-3849.2022.11.015]
[7]程庆,李宁,潘钦敏*,等.电解铜箔添加剂的研究进展及应用现状[J].电镀与精饰,2022,(12):69.[doi:10.3969/j.issn.1001-3849.2022.12.010]
CHENG Qing,LI Ning,PAN Qinmin*,et al.Research Progress and Application Status of Electrolytic Copper Foil Additives[J].Plating & Finishing,2022,(10):69.[doi:10.3969/j.issn.1001-3849.2022.12.010]
[8]代超熠,唐先忠,何 为,等.电解铜箔添加剂的研究进展[J].电镀与精饰,2024,(2):79.[doi:10.3969/j.issn.1001-3849.2024.02.011]
Tang Yao,hen Yuanming *.Research progress of electrolytic copper foil additives[J].Plating & Finishing,2024,(10):79.[doi:10.3969/j.issn.1001-3849.2024.02.011]
[9]张锦园,张 杰,白忠波,等.硫酸钛-钨酸钠复合添加剂对电解铜箔后处理形貌及抗剥离强度的影响[J].电镀与精饰,2024,(5):101.[doi:10.3969/j.issn.1001-3849.2024.05.014]
Zhang Jinyuan,Zhang Jie,Bai Zhongbo,et al.Effect of titanium sulfate and sodium tungstate composite additive on morphology and performance of electrolytic copper foil posttreatment?/html>[J].Plating & Finishing,2024,(10):101.[doi:10.3969/j.issn.1001-3849.2024.05.014]
[10]赵 超,王帅星*,王辉庭,等.2060铝锂合金化学铣切工艺优化及表面质量改善[J].电镀与精饰,2024,(7):38.[doi:10.3969/j.issn.1001-3849.2024.07.006]
Zhao Chao,Wang Shuaixing*,Wang Huiting,et al.Optimization of chemical milling process and improvement of surface quality for 2060 aluminum-lithium alloy[J].Plating & Finishing,2024,(10):38.[doi:10.3969/j.issn.1001-3849.2024.07.006]
备注/Memo
收稿日期： 2021-09-06 修回日期： 2021-10-25 作者简介： 朱金海（ 1980 —），男，硕士，副教授， email ： 13507788005@139.com 基金项目： 2021 年度广西高校中青年教师基础能力提升项目（ 2021KY1419 ）；国家自然科学基金（ 51201017 ）； 广西科学研究与技术开发计划（桂科合 14125008-1-17 ）