[1]张 璐,张中泉,余云丹,等.CoFe/ZrO2复合膜的电沉积及其析氧性能研究[J].电镀与精饰,2024,(1):9-14.[doi:10.3969/j.issn.1001-3849.2024.01.002]
　Zhang Lu,Zhang Zhongquan,Yu Yundan,et al.Electrodeposition of CoFe/ZrO 2 composite films and their oxygen evolution performance[J].Plating & Finishing,2024,(1):9-14.[doi:10.3969/j.issn.1001-3849.2024.01.002]
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CoFe/ZrO2复合膜的电沉积及其析氧性能研究
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《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2024年1
页码:
9-14
栏目:
出版日期:
2024-01-15

文章信息/Info

Title:
Electrodeposition of CoFe/ZrO 2 composite films and their oxygen evolution performance
作者:
（中国计量大学 材料与化学学院，浙江 杭州 310018）
Author(s):
（School of the Materials and Chemistry， China Jiliang University， Hangzhou 310018， China）
关键词:
电沉积; 复合膜; 镀液温度; 析氧反应
Keywords:
electrodeposition ;  composite films ;  bath temperature ;  oxygen evolution reaction
分类号:
TQ153.2
DOI:
10.3969/j.issn.1001-3849.2024.01.002
文献标志码:
A
摘要:
为降低电解水阳极析氧反应的过电位，采用电化学沉积技术制备了 CoFe/ZrO 2 复合膜。在碱性介质中，该复合膜表现出了优异的析氧反应（ OER ）活性，在电流密度 10 mA/cm?#1602下过电势仅为 1.56 V ，远低于 CoFe （ 1.694 V ），这主要是由于 CoFe/ZrO 2 复合膜具有足够暴露的活性位点和较高的电子转移能力。进一步的研究表明， CoFe/ZrO 2 复合膜可以在 1.58 V 过电位下稳定运行 12 h ，经 2000 圈循环伏安测试后， OER 活性曲线未存在明显差别，显示 CoFe/ZrO 2 复合膜具有良好稳定性。本文工作可为探索经济高效的 OER 催化电极膜材料开辟一条新途径，替代贵金属在可再生能源转换中应用。
Abstract:
： In order to reduce the overpotential of anodic oxygen evolution reaction during water electrolysis ， CoFe/ZrO 2 composite films were prepared using electrochemical deposition technology. The composite films exhibit excellent oxygen evolution reaction （ OER ） activity in alkaline media ， with an overpotential of only 1.56 V at a current density of 10 mA/cm 2 ， which is significantly lower than that of CoFe （ 1.694 V ） . This is mainly due to the sufficient exposed active sites and high electron transfer capacity of the CoFe/ZrO 2 composite film. Further studies have shown that the CoFe/ZrO 2 composite membrane can operate stably at an overpotential of 1.58 V for 12 h.After 2000 cycles of cyclic voltammetry testing ， there is no significant difference in the OER activity curves ， indicating that the CoFe/ZrO 2 composite membrane has good stability. The work may open up a new way to explore cost-effective OER catalytic electrode membrane materials to replace precious metals in the application of renewable energy conversion.

参考文献/References:



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备注/Memo

备注/Memo:
收稿日期： 2023-02-27 修回日期： 2023-03-21 作者简介： 张璐（ 1995 ―），男，硕士研究生， email ： zl154109739@163.com * 通信作者： 卫国英， email ： guoyingwei@cjlu.edu.cn 基金项目： 国家自然科学基金资助项目（ 52171083 ）
更新日期/Last Update: 2024-01-04