Yan Xinyu,Long Fei,Li Xuan,et al.The influence of heat treatment on microstructure and hydrogen evolution properties of electrodeposited Ni-S alloy?/html>[J].Plating & Finishing,2024,(7):8-14.[doi:10.3969/j.issn.1001-3849.2024.07.002]
热处理对电沉积Ni-S合金微观组织和析氢性能的影响
- Title:
- The influence of heat treatment on microstructure and hydrogen evolution properties of electrodeposited Ni-S alloy?/html>
- Keywords:
- electrodeposition ; Ni-S alloy ; heat treatment ; crystallization behavior ; electrocatalysis
- 分类号:
- TQ153.2
- 文献标志码:
- A
- 摘要:
- 电解水制氢是目前最有望替代矿石燃料制氢的技术，低成本且高效的析氢电极是限制电解水制氢大规模应用的瓶颈问题，而 Ni-S 合金具有易制备和高活性等优点，作为电解水的阴极材料具有极大的潜力。通过电沉积法在泡沫镍表面制备了非晶 Ni-S 合金，研究了 Ni-S 合金的晶化行为对其析氢性能的影响，热处理促使非晶 Ni-S 合金镀层再结晶转变为以 Ni 3 S 2 和 Ni 为主的结晶层，电化学分析结果表明热处理减少非晶 Ni-S 合金镀层的析氢活性位点，增大氢气从 Ni-S 合金表面脱附难度，显著削弱 Ni-S/NF 电极的电化学析氢性能。
- Abstract:
- ： Water-eletrolytic hydrogen production is the most promising technology to replace the hydrogen production from fossil fuel ， the hydrogen evolution electrode with low cost and high efficiency is the bottleneck problem limiting the large-scale application of water electrolysis for hydrogen production ， Ni-S alloy exhibits the great potential as a cathode material for water electrolysis due to its easy preparation and high activity. Herein ， the amorphous Ni-S alloy coating was prepared on the surface of nickel foam via electrodeposition ， and the influence of crystallization behavior on the hydrogen evolution activity of Ni-S alloy was investigated in this work. Heat treatment promoted the recrystallization of the amorphous Ni-S alloy coating into crystalline layer mainly composed of Ni 3 S 2 and Ni phases ， the electrochemical analysis revealed that heat treatment reduced the number of active sites on the amorphous Ni-S alloy coating for hydrogen evolution reaction ， and increased the difficulty of hydrogen desorption from the surface of the Ni-S alloy ， thus ， the electrochemical hydrogen evolution performance of the Ni-S/NF electrode was significantly weakened.
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备注/Memo
收稿日期： 2023-09-10 修回日期： 2023-09-23 作者简介： 严欣昱（ 1999 ―），男，硕士研究生， email ： jvdd944357@sjtu.edu.cn 通信作者： 周潼， email ： tongzhou@alumni.sjtu.edu.cn 基金项目： 国家自然科学基金资助项目（ Nos.52301095 ， 51971140 ）；国家重点研发计 \ 划项目（ 2021YFC3101201 ）