[1]万金侠*,仲玉侠.混凝土结构中钢筋磷化处理及磷化膜的耐蚀性能[J].电镀与精饰,2021,(7):60.[doi:10.3969/j.issn.1001-3849.2021.07.012]
　WAN Jinxia*,ZHONG Yuxia.Phosphating Treatment of Reinforcement for Concrete Structure and Corrosion Resistance of Phosphating Film[J].Plating & Finishing,2021,(7):60.[doi:10.3969/j.issn.1001-3849.2021.07.012]
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混凝土结构中钢筋磷化处理及磷化膜的耐蚀性能()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2021年7
页码:
60
栏目:
出版日期:
2021-07-15

文章信息/Info

Title:
Phosphating Treatment of Reinforcement for Concrete Structure and Corrosion Resistance of Phosphating Film
作者:
万金侠1*; 仲玉侠2
1. 吉林铁道职业技术学院 铁道工程学院，吉林 吉林 132200；2. 北华大学，吉林 吉林 132013
Author(s):
WAN Jinxia1*;  ZHONG Yuxia2
1.Railway Engineering College， Jinlin Railway Technology College， Jilin 132200， China；　2.Beihua University， Jilin 132013， China
关键词:
耐蚀性能; 磷化处理; 钢筋; 锌-锰系磷化膜
Keywords:
corrosion resistance phosphating treatment reinforcement zinc-manganese phosphating film
DOI:
10.3969/j.issn.1001-3849.2021.07.012
文献标志码:
A
摘要:
为了减缓钢筋锈蚀从而保证混凝土结构稳固，采用中温锌-锰系磷化工艺对钢筋进行磷化处理。表征了磷化钢筋腐蚀前后的外观，同时研究了温度对磷化膜的微观形貌和耐蚀性能的影响。结果表明：磷化钢筋腐蚀前后的外观有所不同，磷化膜覆盖性良好。温度对磷化膜的微观形貌和耐腐蚀性能有较大影响，温度较低时（56 ℃）形成的磷化膜很薄且不完整，耐蚀性能较差，对裸钢筋起不到有效防护。而温度太高（75 ℃）时形成的磷化膜较粗糙，耐蚀性能下降。63 ℃条件下形成的磷化膜完整且较致密，对裸钢筋起到良好的防护效果，磷化处理后的钢筋腐蚀程度较轻。
Abstract:
In order to reduce the corrosion of reinforcement and ensure the stability of concrete structure, the reinforcement was treated by medium-temperature zinc-manganese phosphating process. The appearance of phosphated reinforcement before and after corrosion was characterized, and the effect of temperature on the micromorphology and corrosion resistance of phosphating film was studied. The results showed that the appearance of phosphated reinforcement was different before and after corrosion, and the phosphating film has good spreadability. Temperature has great influence on the micromorphology and corrosion resistance of phosphating film. The phosphating film prepared at low temperature （56 ℃） was very thin and incomplete and with poor corrosion resistance, which has no obvious protection effect on bare reinforcement. However, when the temperature was too high （75 ℃）, the phosphating film was rough and its corrosion resistance was decreased. The phosphating film formed at 63 ℃ was complete and compact and it has better protection effect on bare reinforcement, so the corrosion degree of the reinforcement after phosphating treatment at 63 ℃ was slightly.

参考文献/References:

[1] 陈诗超. 混凝土结构中钢筋的腐蚀与防护探讨[J]. 全面腐蚀控制, 2019, 33(9): 100-101.
Chen S C. Discussion on corrosion and protection of reinforcement in concrete structure[J]. Total Corrosion Control, 2019, 33(9): 100-101 (in Chinese).
[2] 曹云青. 预氧化处理对铁基表面硅烷化的影响[D]. 杭州: 浙江大学, 2019.
[3] Chen J, Yang H Y, Xu G Q, et al. Phosphating passivation of vacuum evaporated Al/NdFeB magnets boosting high anti-corrosion performances[J]. Surface and Coatings Technology, 2020, (399): 115-126.
[4] Liu D. Enhanced corrosion resistance and photocatalytic properties of Bi2O3/phosphate composite film prepared on AZ91D magnesium alloy by phosphating[J]. International Journal of Electrochemical Science,2019, (14):1434-1450.
[5] 李源晋, 路新瀛. 带轧皮钢筋的三种表面转化膜及其耐蚀性[J]. 四川建材, 2015, 41(1): 1-2.
Li Y J, Lu X Y. Corrosion resistance of three surface conversion films on rolled steel bar[J]. Sichuan Building Materials, 2015, 41(1): 1-2 (in Chinese).
[6] 白智豪. 中温钢筋拉拔磷化液的研制[J]. 天津化工,2012, 26(6): 36-38.
Bai Z H. The development of medium temperature rebar drawing phosphating liquid[J]. Tianjin Chemical Industry, 2012, 26(6): 36-38 (in Chinese).
[7] 齐雯涵, 刘军, 邓永刚, 等. 混凝土结构中Q235钢表面磷酸锌涂层的制备和腐蚀研究[J]. 沈阳理工大学学报, 2019, 38(3): 2-6.
Qi W H, Liu J, Deng Y G, et al. Preparation of zinc phosphate conversion coatings on Q235 steel for concrete and their corrosion response[J]. Journal of Shenyang Ligong University, 2019, 38(3): 2-6 (in Chinese).
[8] 随林林, 刘芳, 陈晓蕊, 等. 纳米SiO2-氧化石墨烯/环氧涂层的制备及其防腐蚀性能[J]. 复合材料学报, 2018, 35(7): 1716-1724.
Sui L L,Liu F,Chen X R, et al. Preparation and corrosion resistance of nano SiO2-graphene oxide/epoxy composite coating[J]. Acta Materiae Compositae Sinica, 2018, 35(7): 1716-1724 (in Chinese).
[9] Sun S,Zhang Y P,Yu X T,et al. Study on phosphating technology by use of ultrasonic wave at room temperature for sintered NdFeB magnet[J]. Rare Metal Materials and Engineering,2012, (41): 260-262.
[10] 郑延武, 吴心平. 磷化温度对汽车用冷轧钢板锌-锰磷化膜性能的影响[J]. 电镀与环保, 2020, 40(2): 25-27.
Zheng Y W,Wu X P. Influence of phosphating temperature on properties of Zn-Mn phosphating film on surface of cold-rolled steel plate for automobile[J]. Electroplating & Pollution Control, 2020, 40(2): 25-27 (in Chinese).
[11] Beheshti M, Ismail M C, Kakooei S, et al. Influence of deposition temperature on the corrosion resistance of electrodeposited zinc-nickel alloy coatings [J]. Materialwiss and Werkstofftech, 2018, (49): 472-482.
[12] 刘玮, 安成强, 郝建军, 等. 钼酸钠对AZ91D镁合金钒/锆复合转化膜性能的影响[J]. 电镀与精饰, 2019, 41(8): 10-13.
Liu W, An C Q, Hao J J, et al. Effect of Na2MoO4 on properties of vanadium/zirconate conversion coating on AZ91D magnesium alloy[J]. Plating & Finishing, 2019,41(8): 10-13 (in Chinese).

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备注/Memo

备注/Memo:
收稿日期： 2020-12-04；修回日期： 2021-01-20
通信作者： 万金侠， jilin_edu1981@126.com
基金项目： 铁道部科技研究开发计划课题（2011G012-A）
更新日期/Last Update: 2021-07-10