Zhang Yanjia,Ling Huiqin*,Hang Tao,et al.The influence of poly-2-sulfur-2-propane sodium sulfonate on the electrodeposition of nanotwinned copper?/html>[J].Plating & Finishing,2023,(8):1-6.[doi:10.3969/j.issn.1001-3849.2023.08.001]
聚二硫二丙烷磺酸钠对电沉积纳米孪晶铜的影响
- Title:
- The influence of poly-2-sulfur-2-propane sodium sulfonate on the electrodeposition of nanotwinned copper?/html>
- 关键词:
- 纳米孪晶铜; 电沉积; （ 220 ）择优取向
- Keywords:
- nanotwinned copper ; electrodeposition ; 220 -oriented
- 分类号:
- TQ153.2
- 文献标志码:
- A
- 摘要:
- 以聚二硫二丙烷磺酸钠（ SPS ）、明胶蛋白胨（ GP ）、氯离子为添加剂采用直流电镀制备了高度（ 220 ）择优取向的纳米孪晶铜，并探究了其形核机理。结果表明，加入 SPS 会使镀层由（ 111 ）和（ 220 ）取向转变为具有（ 220 ）择优取向的纳米孪晶铜，并且 SPS 浓度会强烈影响镀层的过渡层厚度。 SPS 和 GP 在铜表面竞争性吸附，使镀层的内应力比单一添加剂时更高，镀层通过形成（ 220 ）择优取向孪晶铜释放内应力。纳米孪晶铜的形核和生长受到电流密度和添加剂的共同影响，在合适的过电位下镀层才能通过形成孪晶来释放应变能。在 20 mg/L SPS 、 4 A/dm 2 条件下，孪晶结构最完整，过渡层最薄。
- Abstract:
- ： The highly preferred （ 220 ） -oriented nanotwinned copper （ nt-Cu ） was fabricated by direct current electrodeposition with poly-2-sulfur-2-propane sodium sulfonate （ SPS ）， gelatin peptone （ GP ） and chloride ion. The nucleation mechanism of nt-Cu was investigated. The results show that SPS could change the texture of the Cu films from （ 111 ） and （ 220 ） to highly preferred （ 220 ） . Besides ， the concentration of SPS has strong influence on the thickness of the transition layer. SPS and GP would adsorb on the surface competitively ， which makes the internal stress of the Cu films higher than that of single additive. The Cu films release the internal stresses by the formation of （ 220 ） -oriented nt-Cu. The nucleation and growth of nt-Cu is influenced by current density and additives. Under the appropriate overpotential ， the Cu film could release the strain energy through the formation of twins. The twin structure is the most complete and the transition layer is the thinnest with 20 mg/L SPS and 4 A/dm 2 .
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备注/Memo
收稿日期： 2022-12-21 修回日期： 2023-01-04 作者简介： 张妍嘉（ 1998 —），女，硕士研究生， email ： zyj2081@sjtu.edu.cn * 通信作者： 凌惠琴， email ： hqling@sjtu.edu.cn 基金项目： 国家自然科学基金资助项目（ No.21972091 ）；国家自然科学基金资助项目（ No.62004124 ）；国家自然科学 基 金重大项目（ No.51991374 ）